全文获取类型
收费全文 | 68篇 |
免费 | 1篇 |
专业分类
化学 | 65篇 |
力学 | 1篇 |
物理学 | 3篇 |
出版年
2023年 | 3篇 |
2020年 | 2篇 |
2019年 | 2篇 |
2016年 | 1篇 |
2014年 | 1篇 |
2012年 | 3篇 |
2011年 | 1篇 |
2010年 | 2篇 |
2008年 | 4篇 |
2007年 | 5篇 |
2005年 | 2篇 |
2004年 | 1篇 |
2003年 | 4篇 |
2002年 | 5篇 |
2001年 | 2篇 |
2000年 | 5篇 |
1999年 | 2篇 |
1998年 | 2篇 |
1997年 | 2篇 |
1996年 | 4篇 |
1995年 | 1篇 |
1994年 | 1篇 |
1992年 | 2篇 |
1991年 | 1篇 |
1990年 | 3篇 |
1989年 | 3篇 |
1988年 | 1篇 |
1987年 | 1篇 |
1986年 | 2篇 |
1975年 | 1篇 |
排序方式: 共有69条查询结果,搜索用时 15 毫秒
1.
Deep blue-violet single crystals of hitherto unknown chromous orthophosphate have been obtained reducing CrPO4 by elemental Cr at temperatures above 1050°C in evacuated silica ampoules (NH4I or I2 as mineraliser). The complex structure of Cr3(PO4)2 (P212121, Z = 8, a = 8.4849(10) Å, b = 10.3317(10) Å, c = 14.206(2) Å) contains six crystallographically independent Cr2+ per unit cell. Five of them are coordinated by four oxygen atoms which form a distorted (roof shaped) square plane as first coordination sphere at interatomic distances 1.96 Å ? d(Cr? O) ? 2.15 Å. Their coordination is completed by additional oxygen atoms (2 or 3) at distances 2.32 Å ? d(Cr? O) ? 3.21 Å. The sixth Cr2+ shows six-fold octahedral coordination with strong radial distortion (d(Cr? O): 1.97, 2.04, 2.15, 2.28, 2.29, 2.53 Å). The four different [PO4] groups exhibit only minor deviations from ideal tetrahedral geometry (1.51 Å ? d(P? O) ? 1.57 Å, 104.3° ? ∠(O? P? O) ? 114.4°). An unusually low magnetic moment μexp = 4.28(2) μB (θP = ?54.8(5) K) has been observed for Cr2+. 相似文献
2.
New Metal Oxides with Doubles of Tetrahedra as Building Units: Rb6[Tl2O6] and Cs6[In2O6] We prepared the hitherto unknown Rb6[Tl2O6] and Cs6[In2O6] by heating mixtures of Tl2O3 and RbO0.60 (Rb:Tl = 3.5:1) as well as In2O3 and CsO0.53 (Cs:In = 3.5:1) as single crystals [closed Ag-cylinder, 650°C, 14 d]. The single crystals of Rb6[Tl2O6] are yellow, those of Cs6[In2O6] pale yellow, all transparent and rude. The new type of structure was elucidated by 4-circle-diffractometer (PW 1100) data. Rb6[Tl2O6]: P21/a; a = 1145,7(3), b = 713,3(1), c = 783,9(2) pm, β = 93,73° (2), Z = 2; Ag–Kα, 2100 out of 2531 I0(hkl), R = 9,6% and Rw = 8,9%. Cs6[In2O6]: P21/a; a = 1178,5(4), b = 730,7(2), c = 816,3(2) pm, β = 95,38° (3), Z = 2; Mo–Kα, 1584 out of 2032 I0(hkl), R = 9,25%, and Rw = 8,44%. The Madelung Part of Lattice Energy, MAPLE, is calculated and discussed. 相似文献
3.
Robert Glaum 《无机化学与普通化学杂志》1992,616(10):46-52
Contributions on the Thermal Behaviour of Anhydrous Phosphates. IX. Synthesis and Crystal Structure of Cr6(P2O7)4. A Pyrophosphate Containing Di- and Trivalent Chromium Cr6(P2O7)4 (Cr22+Cr43+(P2O7)4) can be obtained reducing CrPO4 by phosphorus (950°C, 48 h, 100 mg iodine as mineralizer). By means of chemical transport reactions (transport agent iodine; 1050 → 950°C) the compound has been separated from its neighbour phases (Cr2P2O7, CrP3O9) and crystallized (greenish, transparent crystals; edge length up to 0.3 mm). The crystal structure of Cr6(P2O7)4 (Spcgrp.: P-1; z = 1; a = 4.7128(8) Å, b = 12.667(3) Å, c = 7.843(2) Å, α = 89.65(2)°, β = 92.02(2)°, γ = 90.37(2) has been solved and refined from single crystal data (2713 unique reflections, 194 parameter, R = 0.035). Cr2+ is surrounded by six oxygen atoms which occupy the corners of an elongated octahedron (4 × dCr? O ≈? 2.04 Å; 2 × dCr? O ≈? 2.62 Å). The Cr3+ ions are also coordinated octahedraly (1.930 Å ≤ dCr? O ≤ 2.061 Å). The crystallographically independent pyrophosphate groups show nearly eclipsed conformation. The bridging angles (P? O? P) are 136.5° and 138.9° respectively. 相似文献
4.
Zum chemischen Transport von Chrom- und Manganmonophosphid mit Iod. Experimente und Modellrechnungen
On the Chemical Vapour Transport of Chromium and Manganese Monophosphide. Experimental Results and Thermochemical Calculations Using iodine as transport agent well shaped crystals of a volume up to V ≈︁ 50 mm3 (CrP) or an edgelength of approximately 1 ≈︁ 10 mm (MnP) can be grown. CrP has been deposited at the lower temperature of a temperature gradient (1050 → 950°C). At a density of the transport agent higher than D = 26 · 10−6 [mol I2/cm3] CrP and CrI2,1 coexist in the deposition region at the lower temperature. The determined composition of the condensed phases under equilibrium conditions are in accordance with thermochemical calculations assuming the heat of formation of CrP to be ΔFH= −25.5 ± 2 [kcal/mol]. Furthermore these calculations show that the solution of CrP in the gas phase leads to CrI2,g, Cr2I4,g, P2,g and P4,g, while I2,g, HIg, PI3,g and P2I4,g have to be considered as transport agents. The migration of MnP (1000 → 1100°C) results from an exothermic reaction. MnPs exists besides MnI2,1 in the source region. Thermochemical calculations are in good agreement with the experimental results and suggest the following heterogenous equilibrium to be responsible for the observed behaviour: . 相似文献
5.
Background
A clear picture of the mechanisms controlling glutamate receptor expression, localization, and stability remains elusive, possibly due to an incomplete understanding of the proteins involved. We screened transposon mutants generated by the ongoing Drosophila Gene Disruption Project in an effort to identify the different types of genes required for glutamate receptor cluster development. 相似文献6.
7.
8.
9.
10.