全文获取类型
收费全文 | 220篇 |
免费 | 4篇 |
国内免费 | 1篇 |
专业分类
化学 | 120篇 |
晶体学 | 2篇 |
力学 | 11篇 |
数学 | 51篇 |
物理学 | 41篇 |
出版年
2022年 | 2篇 |
2020年 | 6篇 |
2018年 | 6篇 |
2017年 | 4篇 |
2016年 | 4篇 |
2015年 | 8篇 |
2014年 | 5篇 |
2013年 | 5篇 |
2012年 | 11篇 |
2011年 | 8篇 |
2010年 | 6篇 |
2009年 | 4篇 |
2008年 | 4篇 |
2007年 | 13篇 |
2006年 | 8篇 |
2005年 | 7篇 |
2004年 | 12篇 |
2003年 | 2篇 |
2002年 | 8篇 |
2001年 | 6篇 |
2000年 | 5篇 |
1999年 | 6篇 |
1998年 | 2篇 |
1997年 | 3篇 |
1996年 | 2篇 |
1995年 | 4篇 |
1994年 | 3篇 |
1993年 | 2篇 |
1992年 | 4篇 |
1989年 | 2篇 |
1984年 | 4篇 |
1982年 | 4篇 |
1981年 | 4篇 |
1980年 | 4篇 |
1978年 | 8篇 |
1976年 | 2篇 |
1972年 | 2篇 |
1932年 | 3篇 |
1931年 | 1篇 |
1930年 | 2篇 |
1929年 | 2篇 |
1927年 | 1篇 |
1925年 | 1篇 |
1924年 | 3篇 |
1921年 | 1篇 |
1918年 | 2篇 |
1912年 | 2篇 |
1899年 | 2篇 |
1898年 | 2篇 |
1897年 | 2篇 |
排序方式: 共有225条查询结果,搜索用时 15 毫秒
1.
2.
Capillary reversed-phase high-performance liquid chromatography (RP-HPLC) utilizing monolithic poly(styrene-divinylbenzene) columns was optimized for the coupling to electrospray ionization mass spectrometry (ESI-MS) by the application of various temperatures and mobile phase additives during peptide and protein analysis. Peak widths at half height improved significantly upon increasing the temperature and ranged from 2.0 to 5.4 s for peptide and protein separations at 70 degrees. Selectivity of peptide elution was significantly modulated by temperature, whereas the effect on proteins was only minor. A comparison of 0.10% formic acid (FA), 0.050% trifluoroacetic acid (TFA), and 0.050% heptafluorobutyric acid (HFBA) as mobile phase additives revealed that highest chromatographic efficiency but poorest mass spectrometric detectabilities were achieved with HFBA. Clusters of HFBA, water, and acetonitrile were observed in the mass spectra at m/z values >500. Although the signal-to-noise ratios for the individual peptides diverged considerably both in the selected ion chromatograms and extracted mass spectra, the average mass spectrometric detectabilities varied only by a factor of less than 1.7 measured with the different additives. Limits of detection for peptides with 500 nl sample volumes injected onto a 60 mm x 0.20 mm monolithic column were in the 0.2-13 fmol range. In the analysis of hydrophobic membrane proteins, HFBA enabled highest separation selectivity at the cost of lower mass spectral quality. The use of 0.050% TFA as mobile phase additive turned out to be the best compromise between chromatographic and mass spectrometric performance in the analysis of peptides and proteins by RP-HPLC-ESI-MS using monolithic separation columns. 相似文献
3.
4.
5.
We prove the existence of fast traveling pulse solutions in excitable media with non-local coupling. Existence results had been known, until now, in the case of local, diffusive coupling and in the case of a discrete medium, with finite-range, non-local coupling. Our approach replaces methods from geometric singular perturbation theory, that had been crucial in previous existence proofs, by a PDE oriented approach, relying on exponential weights, Fredholm theory, and commutator estimates. 相似文献
6.
Ortal Haik Francis Susai Amalraj Daniel Hirshberg Luba Burlaka Michael Talianker Boris Markovsky Ella Zinigrad Doron Aurbach Jordan K. Lampert Ji-Yong Shin Martin Schulz-Dobrick Arnd Garsuch 《Journal of Solid State Electrochemistry》2014,18(8):2333-2342
Thermodynamic instability of positive electrodes (cathodes) in Li-ion batteries in humid air and battery solutions results in capacity fading and batteries degradation, especially at elevated temperatures. In this work, we studied thermal interactions between cathode materials Li2MnO3, xLi2MnO3 .(1???x)Li(MnNiCo)O2,LiNi0.33Mn0.33Co0.33O2, LiNi0.4Mn0.4Co0.2O2, LiNi0.8Co0.15Al0.05O2 LiMn1.5Ni0.5O4, LiMn(or Fe)PO4, and battery solutions containing ethylene carbonate (EC) or propylene carbonate (PC), dimethyl carbonate (DMC) or ethylmethyl carbonate (EMC) and LiPF6 salt in the temperature range of 40–400 °C. It was found that these materials are stable chemically and well performing in LiPF6-based solutions up to 60 °C. The thermal decomposition of the electrolyte solutions starts >180 °C. The macro-structural transformations of cathode materials upon exothermic reactions were studied by transmission electron microscopy (TEM), X-ray difraction (XRD) and Raman spectroscopy. Differential scanning calorimetry (DSC) studies have shown that the exothermic reactions in the temperature range of 60–140 °C lead to partial decomposition of both the cathode material and electrolyte solution. The systems thus formed consisted of partially decomposed solutions and partially chemically delithiated cathode materials covered by reactions products. Thermal reactions terminate and this system reaches equilibrium at about 120 °C. It remains stable up to the beginning of the solution decomposition at about 180 °C. The increased content of surface Li2CO3 is found to significantly affect the thermal processes at high temperature range due to extensive exothermic decomposition at low temperatures. 相似文献
7.
Dr. Peter Thumbs M. Sc. Timm T. Ensfelder M. Sc. Markus Hillmeier Dr. Mirko Wagner M. Sc. Matthias Heiss M. Sc. Constanze Scheel M. Sc. Alexander Schön Dr. Markus Müller Prof. Dr. Stylianos Michalakis Dr. Stefanie Kellner Prof. Dr. Thomas Carell 《Angewandte Chemie (Weinheim an der Bergstrasse, Germany)》2020,132(30):12451-12455
8.
9.
The spatiotemporal superstructure of meandering and drifting spiral waves is explained analytically. It is also demonstrated that the Hopf eigenmode that causes the transition to meandering waves is weakly exponentially localized at onset but grows exponentially slightly before onset. 相似文献
10.
We have demonstrated experimentally that polar molecules revolve around the inner electrode of a charged cylindrical capacitor in helical trajectories that result from a superposition of a translational motion along and an orbital motion around the cylinder axis. In this way molecular beams can be guided over any given distance. The results have been obtained for nozzle beams of NaCl, NaBr, and NaI seeded in Kr. The capacitor bent into a toroid may be used as a storage ring for polar molecules in high field seeking rotational states. 相似文献