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排序方式: 共有566条查询结果,搜索用时 15 毫秒
1.
Palladium-containing zeolites catalyze the cycloisomerization of diethyl diallylmalonate to dimethylcyclopentenes. When the reaction is carried out in toluene, the performance of the palladium catalyst depends on the pore size of the zeolites. At 60 °C, palladium adsorbed on large pore size Beta zeolite (pore size ∼7.4 Å) is more active than medium pore size ZSM-5 (pore size ∼5.4 Å). This lower activity of ZSM-5 compared to Beta is attributable to the restricted diffusion of reagent and products through the ZSM-5 channels as compared to Beta zeolite. However, due to the gas-like diffusion characteristic of the supercritical state, the activity of ZSM-5 increases and becomes identical to that of Beta zeolite using supercritical CO2 as medium. 相似文献
2.
Alvaro Carrillo Ravi S. Kane 《Journal of polymer science. Part A, Polymer chemistry》2004,42(13):3352-3359
This article describes the formation and characterization of self‐assembled nanoparticles of controlled sizes based on amphiphilic block copolymers synthesized by ring‐opening metathesis polymerization. We synthesized a novel hydrophobic derivative of norbornene; this monomer could be polymerized using Grubbs' catalyst [Cl2Ru(CHPh)(PCy3)2] forming polymers of controlled molecular weight. We synthesized amphiphilic block copolymers of controlled composition and showed that they assemble into nanoparticles of controlled size. The nanoparticles were characterized using dynamic light scattering and transmission electron microscopy. Tuning the composition of the block copolymer enables the tuning of the diameters of the nanoparticles in the 30‐ to 80‐nm range. © 2004 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 42: 3352–3359, 2004 相似文献
3.
Alvaro P. Raposo Hans J. Weber David E. Alvarez-Castillo Mariana Kirchbach 《Central European Journal of Physics》2007,5(3):253-284
We briefly review the five possible real polynomial solutions of hypergeometric differential equations. Three of them are
the well known classical orthogonal polynomials, but the other two are different with respect to their orthogonality properties.
We then focus on the family of polynomials which exhibits a finite orthogonality. This family, to be referred to as the Romanovski
polynomials, is required in exact solutions of several physics problems ranging from quantum mechanics and quark physics to
random matrix theory. It appears timely to draw attention to it by the present study. Our survey also includes several new
observations on the orthogonality properties of the Romanovski polynomials and new developments from their Rodrigues formula. 相似文献
4.
We present a modification of the Cyclic Subgradient Projection (CSP) method by Censor and Lent, which solves the convex feasibility problem in a finite number of steps when a Slater type condition holds, while preserving its row-action properties. A linear rate of convergence for the CSP method is established assuming the same hypothesis.Research partially supported by CNPq, under Grant No. 301699/81. 相似文献
5.
Alvaro M Corma A Das D Fornés V García H 《Chemical communications (Cambridge, England)》2004,(8):956-957
Preparation of hybrid organic-inorganic MCM-41 and SBA-15 silicas functionalized with perfluoroalkylsulfonic acid groups has been achieved in a single step by reacting the mesoporous silicas with 1,2,2-trifluoro-2-hydroxy-1-trifluoromethylethane sulfonic acid beta-sultone; the catalysts showed higher activity than commercial Nafion-silica composite for the esterification of long chain fatty acids with ethanol. 相似文献
6.
Pyrazol-l'-ylpyridines undergo electrophilic substitution reactions (bromination, chlorination, and nitration) preferentially in the pyrazole ring. There is some evidence of the mutual influence of the pyrazole and the pyridine ring on the reactivity of the system. Some modifications of the substituents were also carried out. A dihydro derivative of a new ring system, pyrazolo[1′,2′-a]pyrido[2,1-c][l,2,4]triazine was also obtained. 相似文献
7.
Alvaro M Formentín P García H Palomares E Sabater MJ 《The Journal of organic chemistry》2002,67(15):5184-5189
Three N-alkylpyridinium photosensitizers having chiral alkyl groups have been prepared by reacting 2,4,6-triphenylpyrylium tetrafluoroborate ion with (1R,2S)-(-)-norephedrine, (S)-(+)-2-(aminomethyl)pyrrolidine, and (R)-(-)-1-cyclohexylethylamine. Laser flash photolysis allows detection of the corresponding triplet excited states that are quenched by hydrogen atom donors and electron donors. Asymmetric quenching of the chiral triplet excited state was observed using enantiomerically pure 1,2-diamino cyclohexane as quencher. Low enantiomeric excess values (up to 7%) were measured for the photochemical cyclization of 5-methyl-4-hexenoic acid to its corresponding gamma-lactone using these chiral N-alkylpyridinium as photosensitizers. 相似文献
8.
The complexation equilibria between Ni(II) and Zn(II) metal ions with 3-(1-naphthyl)-2-mercaptopropenoic acid (H2NMP) were studied by glass electrode potentiometry, at 25 °C and 1.0 mol·dm–3 in NaClO4 as constant ionic medium in 50% (v/v) water-ethanol solutions. Formation constants for the complexes Ni(NMP), Ni(NMP)
2
2–
, Zn(NMP) and Zn(NMP)
2
2–
, refined by the MINIGLASS program, are reported. 相似文献
9.
M. Angeles Díaz-Díez Fernando J. García-Barros Francisco J. Higes-Rolando Alvaro Bernalte-García Cristóbal Valenzuela-Calahorro 《Transition Metal Chemistry》1995,20(4):402-405
Summary Complexes of CuII with 2-(benzylamino)-2-deoxy-d-glycero-d-talo heptonic acid (BnMa) and 2-(benzylamino)-2-deoxy-d-glycero-l-gluco heptonic acid (BnGa) were prepared and characterized by elemental analysis, thermal data, i.r., electronic and e.s.r. spectra, magnetic susceptibility measurements, and X-ray powder diffraction. The metal:ligand stoichiometry of these complexes is 12 and coordination around CuII seems to be octahedral, with the ligands bound through the N atom of the amino group and O atoms of the bridging carboxylate group. 相似文献
10.
The framework of the paper is that of the full Fock space
and the Banach algebraF
which can be viewed as non-commutative analogues of the Hardy spacesH
2 andH
respectively.An inner-outer factorization for any element in
as well as characterization of invertible elements inF
are obtained. We also give a complete characterization of invariant subspaces for the left creation operatorsS
1
,..., S
n
of
. This enables us to show that every weakly (strongly) closed unital subalgebra of {(S
1
,..., S
n
) F
} is reflexive, extending in this way the classical result of Sarason [S]. Some properties of inner and outer functions and many examples are also considered.The first author was supported in part by NSF DMS 93-21369 1991Mathematics Subject Classification. Primary 47D25, Secondary 32A35, 47A67. 相似文献