Synthesis and Structure of Ag_3PSe_4

The title compound Ag3PSe4 was synthesized by the reaction of Ag powder,P2Se5 and Se in a molar ratio of 1:1:1 at 500℃ and structurally characterized by X-ray crystallography.The crystal belongs to orthorhombic,space group Pmn21 with cell parameters:a=7.689(4),b=6.660(3),c=6.379(4)A,V=326.7(3)A^3,Z=2,Dc=6.816g/cm^3,Mr=670.42,F(000)=584,μ=31.302mm^-1,R=0.0606,wR=0.1289 and S=1.012,The 3-D structure can be regarded as constructed from the stacking of puckered Ag-P-Se honeycomb-like sheets along the c direction,in which the Ag,P and Se atoms are bonded to each other to form a chair-like six-membered ring,and the rings then build the sheets by sharing edges.     

两个具有相似（V10）阴离子骨架的化合物的合成和结构表征

本文描述了两个具有相似阴离子骨架的化合物,[Na2(H2O)10(NH4)4][V10O28](1)和[Na2(H2O)10(NH4)4][V9MoO28](2).化合物1的阴离子是一个常见的钒十骨架,而化合物2与化合物1是同晶异质体,化合物2的阴离子是混有一个钼原子的钒十骨架.X-射线晶体结构测定表明,这两个化合物均属于三斜晶系,P1空间群.晶胞参数分别为化合物1a=0.86024(4)nm,b=1.04561(5)nm,c=1.12828(4)nm,α=68.833(1)°,β=87.158(1)°,γ=67.065(1)°;化合物2a=0.86511(3)nm,b=1.04549(5)nm,c=1.12446(5)nm,α=69.071(1)°,β=87.145(1)°,γ=66.982(1)°.     

Synthesis and Crystal Structure of Ag2（admtrz）2（CF3CO2）2（admtrz=4—amino—3,5—dimethyl—1,2,4—triazole）

1 INTRODUCTION Transition metal complexes bridged by 1, 2, 4-triazole group can produce interesting structures and specific properties[1]. Many attempts have been made to synthesize a variety of complexes with paramagnetic centers by using such ligands, and their structures and magnetic properties have been characterized[2]. However, the polynuclear Ag(I) complexes bridged by 1, 2, 4-triazole have been poorly studied[3]. Recently, we have prepared a series of silver(I) triazole complex…     

IIB族金属二硫代氨基甲酸配合物的合成、表征及热稳定性研究

在甲醇溶液中合成了一系列IIB过渡金属Zn(II), Cd(II)的二羟乙基二硫代氨基甲酸[(EtOH)₂dtc]的配合物, 并对配合物M[(EtOH)₂dtc]₂L [M＝Zn (1), Cd (2), L＝2,2'-联吡啶; M＝Zn (3), Cd (4), L＝邻菲啰啉]进行了红外光谱、元素分析、热重分析表征工作. 热重分析表明配合物1～4中DTC配体比中性配体更易失去, 热分解最终产物为相应的氧化物. 对化合物1, 2做了X-ray单晶衍射分析, 1为单斜晶系, P2₁/c空间群, 晶胞参数a＝0.72146(5) nm, b＝2.61720(18) nm, c＝1.59438(11) nm,b＝97.899(2)°, V＝2.9820(4) nm³, Z＝4, m＝1.133 mm^－1, D_c＝1.297 Mg•m^－3; 2为三斜晶系, P-1空间群, 晶胞参数a＝1.0075(2) nm, b＝1.1580(2) nm, c＝1.1777(2) nm, a＝70.92(3)°, b＝85.71(3)°, γ＝81.02(3)°, V＝1.2822(4) nm³, Z＝2, m＝2.118 mm^－1, D_c＝1.630 Mg•m^－3.     

混凝土动态劈裂拉伸试验的数值模拟

采用LS-DYNA有限元编码程序，对混凝土的动态劈裂拉伸试验进行了数值模拟，给出了混凝土试样在不同类型加载情况下应力分布之间的差异，证实了动态劈裂拉伸试验的有效性，提出了改进试验方法的若干结论．     

刚性块轴向撞击杆的弹塑性动力屈曲

用特征线法分析了刚性块轴向撞击弹塑性直杆时应力波传播的全过程,得到了杆冲击端与固定端应力的变化规律及刚性块与杆首次分离的时间.基于能量原理,考虑了弹塑性应力波的传播与反射,建立了弹塑性杆在刚性块轴向撞击下的横向扰动方程,给出了问题的级数解,由解的稳定性得到了发生屈曲时的临界条件;通过数值计算和分析,给出了临界速度与冲击质量、线性强化模量及临界时间间的关系.     

基于重构相空间的结构损伤识别方法

介绍了混沌理论中相空间重构技术,应用到结构损伤检测与健康监测中.以单自由度弹簧振子为例分析了基于相空间拓扑结构变化的损伤检测方法的可行性,结果表明,当弹簧的刚度降低,相空间拓扑结构发生明显变化,表明该检测方法是可行的.利用相空间重构技术,直接将结构动态响应以相空间的形式展开,根据损伤前后相空间拓扑结构的变化,提出了新的损伤因子.为了验证该方法的可行性与可靠性,进行了圆拱结构动态实验并进行损伤识别.实验结果表明,该方法能够成功地识别出圆拱结构的损伤位置及损伤程度,且灵敏度较之常用的动力指纹方法有了很大的提高.该方法只需单个测点就能计算出该点损伤因子的值,可作为结构整体参量来监测结构是否存在损伤以及结构健康状况.     

超声探头的响应特性及暂态回波模型

建立检测系统的数学模型,可以更好地理解超声检测的物理本质。分析了超声波从产生、介质中传播、缺陷耦合以及接收的全过程,将缺陷回波表示为探头响应函数与缺陷响应的时域卷积。利用空间脉冲响应和基尔霍夫近似建立了超声波与平面型缺陷的耦合模型,用大平面试块底面回波和大平面响应进行反卷积求得了探头的响应函数,并详细分析了探头在不同偏置位置时不同大小缺陷响应的特点,发现缺陷回波由直达回波和边缘回波组成,直达回波和边缘回波极性相反,且直达回波的幅值远远大于边缘回波。     

Reversal current observed in micro-and submicro-channel flow under non-continuous DC electric field

In practical applications of biochips and bio-sensors, electrokinetic mechanisms are commonly employed to manipulate and analyze the characteristics of single bio-molecules. To accurately and flexibly control the movement of single molecule within micro-/submicro-fluidic channels, the characteristics of current signals at the initial stage of the flow are systematically studied based on a three-electrode system. The current response of micro-/submicro-fluidic channels filled with different electrolyte solutions in non-continuous external electric field are investigated. It is found, there always exists a current reversal phenomenon, which is an inherent property of the current signals in micro/submicro-fluidics Each solution has an individual critical voltage under which the steady current value is equal to zero The interaction between the steady current and external applied voltage follows an exponential function. All these results can be attributed to the overpotentials of the electric double layer on the electrodes. These results are helpful for the design and fabrication of functional micro/nano-scale fluidic sensors and biochips.     

静电纺丝纳米纤维薄膜的应用进展

静电纺丝是一种简单而高效制备高分子微纳米纤维的技术,由于设备和实验成本低、纤维产率高、制备出的纤维比表面积比较大、适用性广泛等独特的优势,近些年来备受关注。静电纺丝的应用是静电纺丝研究的最基本动力和终极目标,因此成为研究者一直努力的方向。为了研究静电纺丝应用的研究现状和主要发展方向,本文综述了静电纺丝纳米纤维薄膜几个主要的应用领域,包括组织工程、药物缓释、纳米传感器、能源应用、生物芯片和催化剂负载等,并展望了未来可能的发展方向。