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以高温烧结三聚氰胺制得的CNH化合物为C、N源,与分析纯单质硼粉以一定比例混合,在5.0~5.5 GPa、1 400~1 500 ℃高温高压条件下,经化学反应合成了六角硼碳氮(h-BCN)晶体。用傅立叶变换红外光谱(FTIR)和X射线光电子能谱(XPS)对产物进行了表征,结果表明,得到了含碳量较高的六方结构B0.18C0.66N0.16化合物,成分接近于BC4N,硼、碳、氮是以原子化合的形式存在;XRD分析确定该合成产物具有六角网状结构;SEM测量结果表明,B-C-N晶体具有片状六角形貌,尺寸在1 μm左右。 相似文献
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Anomalous behavior and phase transformation of α-GaOOH nanocrystals under static compression 下载免费PDF全文
The structural compression mechanism and compressibility of gallium oxyhydroxide, α-GaOOH, are investigated by in situ synchrotron radiation x-ray diffraction at pressures up to 31.0 GPa by using the diamond anvil cell technique. Theα-GaOOH sustains its orthorhombic structure when the pressure is lower than 23.8 GPa. The compression is anisotropic under hydrostatic conditions, with the a-axis being most compressible. The compression proceeds mainly by shrinkage of the void channels formed by the coordination GaO_3(OH)_3 octahedra of the crystal structure. Anomaly is found in the compression behavior to occur at 14.6GPa, which is concomitant with the equatorial distortion of the GaO_3(OH)_3 octahedra. A kink occurs at 14.6 GPa in the plot of finite strain f versus normalized stress F, indicating the change in the bulk compression behavior. The fittings of a second order Birch–Murnaghan equation of state to the P–V data in different pressure ranges result in the bulk moduli B_0= 199(1) GPa for P 14.6 GPa and B_0= 167(2) GPa for P 14.6 GPa. As the pressure is increased to about 25.8 GPa, a first-order phase transformation takes place, which is evidenced by the abrupt decrease in the unit cell volume and b and c lattice parameters. 相似文献
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Holographic storage scheme based on digital signal processing 总被引:2,自引:0,他引:2
In this paper, a holographic storage scheme for multimedia data storage and retrieval based on the digital signal processing (DSP) is designed. A communication model for holographic storage system is obtained on the analogy of traditional communication system. Many characteristics of holographic storage are embodied in the communication model. Then some new methods of DSP including two-dimensional (2-D) shifting interleaving, encoding and decoding of modulation-array (MA) code and method of soft-decision, etc. are proposed and employed in the system. From the results of experiments it can be seen that those measures can effectively reduce the influence of noise. A segment of multimedia data, including video and audio data, is retrieved successfully after holographic storage by using those techniques. 相似文献
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针对疲劳载荷造成的不同应力比和频率对船舶与海洋结构中裂纹扩展速率的影响,本文在分析了疲劳裂纹扩展速率几种经验公式的基础上,考虑了不同应力比与不同加载频率的疲劳载荷作用对直线裂纹和弯曲裂纹扩展速率的影响,提出了相应的计算公式;并与经验公式和现有实验数据进行了比较,验证了所提公式的正确性,研究结果可以直接应用于对不同频率、应力比条件下疲劳裂纹扩展速率的预测。结果表明:在同等应力强度因子变化幅值条件下,疲劳裂纹扩展速率随着疲劳载荷应力比和加载频率的增大而增大,在第一阶段增加比较缓慢、在第二和第三阶段增加非常迅速。本文给出的新型Irving公式适用于疲劳载荷作用下线弹性直线、弯曲裂纹扩展的第一、第二、第三阶段,计算结果比原Irving公式的结果更接近实验数据。该新型Irving公式更具有实用性和准确性。 相似文献
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为了得到超硬相的C3N4,利用石墨相C3N4(gC3N4)为实验的初始原料,利用六面顶压机高温高压实验技术,对gC3N4进行了高温高压研究.实验结果表明,在5.2 GPa、600 ℃和5.2 GPa、800 ℃两个压力和温度点,制备的样品经过X射线衍射(XRD)分析,样品仍然为gC3N4,当温度升到1000 ℃时,发现样品发生了变化,经XRD和X光电子能谱(XPS)分析,gC3N4完全分解为石墨. 相似文献
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以三聚氰胺和氧化硼为原料,利用真空热处理和高温高压技术,对BCN化合物的形成及结构进行了研究。在真空条件下,原料经1 100 K热处理得到非晶BCN的前驱物,将前驱物在5.0 GPa、1 500 K条件下高温高压热处理30 min,合成出了单相的六角BCN晶体。采用Materials Studio软件的Reflex模块对样品的X射线衍射图谱进行分析,结果表明,得到的样品为纯的六角相,晶格常数为a=0.250 5 nm,c=0.665 9 nm。对样品进行了透射电镜(TEM)分析,得到了样品的形貌和电子衍射,同样证实了样品为六角BCN晶体,晶粒尺寸约200 nm。对样品进行了XPS表征,确定了样品中存在C—C、C—N、C—B、N—B键,表明B、C、N三元素之间达到了原子级化合,样品的组分含量通过EDX进行标定。 相似文献
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Cubic boron nitride (c-BN) films were deposited on highly-oriented (111) bulk c-BN crystal by using the rf magnetron sputtering method. The growth films are characterized by micro-Raman spectroscopy (μ-RS) and scanning electron microscopy (SEM), The results show that the high crystallization electron transparent c-BN films in thickness of about 10μm are obtained, Island and step growth models are clearly shown. 相似文献