排序方式: 共有36条查询结果,搜索用时 15 毫秒
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对50个单元构成的聚N,N-二乙基丙烯酰胺(PDEA)低聚物的水溶液体系进行了分子动力学的研究,分别模拟了300 K时的伸展链、310 K时的伸展链以及紧缩链与水构成的体系,对溶液中PDEA周围溶剂水分子的分布情况以及水分子形成氢键的情况进行了统计,结果表明在PDEA周围的水产生了比本体水更有序的结构,形成了更多的氢键,这种有序结构维持到第二水合层甚至更远.发生相分离后,PDEA与水分子形成的氢键大部分未被破坏,水合层中每个水分子形成的氢键数也没有明显变化,但水合层(形成有序结构的水分子)内水分子数目的减少使得总的氢键数目减少,从而造成体系能量增加及熵增加.同时还研究了聚合物及水分子的自扩散系数,表明PDEA影响周围水分子结构的同时,对水的动力学性质也产生了很大影响. 相似文献
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A novel 2-dimensional cosmic ray position detector based on a CsI(Na) pixel array and an ICCD camera
A novel 2-D cosmic ray position detector has been built and studied. It is integrated from a CsI(Na) crystal pixel array, an optical fiber array, an image intensifier and an ICCD camera. The 2-D positions of one cosmic ray track is determined by the location of a fired CsI(Na) pixel. The scintillation light of these 1.0× 1.0 mm CsI(Na) pixels is delivered to the image intensifier through fibers. The light information is recorded in the ICCD camera in the form of images, from which the 2-D positions can be reconstructed. The background noise and cosmic ray images have been studied. The study shows that the cosmic ray detection efficiency can reach up to 11.4%, while the false accept rate is less than 1%. 相似文献
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吕绮雯 郑阳恒 田彩星 刘福虎 蔡啸 方建 高龙 葛永帅 刘颖彪 孙丽君 孙希磊 牛顺利 王志刚 谢宇广 薛镇 俞伯祥 章爱武 胡涛 吕军光 《物理学报》2012,61(7):72904-072904
本研究采用双层150 mm×150 mm闪烁条阵列定位宇宙线的入射和出射位置. 阵列信号光使用波移光纤吸收传输,在ICCD相机前插入前置像增强器,使信号光延迟大于200 ns, 使ICCD可以由外部高速触发信号控制,有效记录随机触发事例.该宇宙线定位系统可以同时多点密集测量 通用探测器测试平台的时间分辨和闪烁光的渡越时间.该新方法与传统时间分辨测量方法相比提高了30倍以上 的效率.实验结果显示:时间探测器的时间分辨好于200 ps,满足通用探测器测试平台的设计要求. 相似文献
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用循环伏安法对我们新设计、合成的氧化还原型胺羧络合剂——二茂铁甲基亚胺基二乙酸钠(简称FIDA)进行电化学研究.包括温度、溶剂的影响及对Zn2+,Co2+,Cu2+,Ni2+,Ca2+和La2+等金属离子的电化学响应.为这类新型胺羧络合剂的应用提供了有用的信息. 相似文献
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An attenuation length measurement device was constructed using an oscilloscope and LabVIEW for signal acquisition and processing. The performance of the device has been tested in a variety of ways. The test results show that the set-up has a good stability and high precision (sigma/mean reached 0.4 percent). Besides, the accuracy of the measurement system will decrease by about 17 percent if a filter is used. The attenuation length of a gadolinium-loaded liquid scintillator (Gd-LS) was measured as 15.10±0.35 m where Gd-LS was heavily used in the Daya Bay Neutrino Experiment. In addition, one method based on the Beer-Lambert law was proposed to investigate the reliability of the measurement device, the R-square reached 0.9995. Moreover, three purification methods for Linear Alkyl Benzene (LAB) production were compared in the experiment. 相似文献
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The CsI(Tl) crystal modules of the Beijing Spectrometer Ⅲ (BESⅢ) electro-magnetic calorimeter (EMC) were designed and assembled through Monte Carlo simulation and experiments. After the assembly was finished, the performance of each crystal module was tested by cosmic rays. All crystal modules were found to work well before the installation of EMC. 相似文献
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Highly oriented cubic, hollow cubic and spherical nanoparticles of cobalt-iron Prussian blue analogues were synthesized in poly oxyethylene tertoctylphenyl ether (TritonX-100)/n-hexanol/cyclohexane microemulsion. The effects of the water-to-surfactant molar ratio (w), the reactant concentration and the reaction temperature on the morphology of cobalt-iron Prussian blue analogues were studied. The samples were characterized by transmission electron microscopy (TEM), field emission scan electron microscopy (FE-SEM), energy-dispersive X-ray spectroscopy (EDS), X-ray diffraction (XRD) and infrared spectroscopy (IR). 相似文献