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排序方式: 共有115条查询结果,搜索用时 15 毫秒
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F. Drawert W. Heimann und G. Tsantalis 《Fresenius' Journal of Analytical Chemistry》1967,228(3):170-180
Zusammenfassung Durch Direktinjektion von 5–20 l verschiedener Branntweine wurden auf gaschromatographischen Trennsäulen in Verbindung mit Flammenionisationsdetektoren die Verbindungen Acetaldehyd, Essigsäure-methylester, Essigsäure-äthylester, Methanol, Butanol-2, Propanol-1, 2-Methylpropanol-1, Butanol-1, 2-Methyl-butanol-1, 3-Methyl-butanol-1 und Hexanol-1 aufgetrennt und quantitativ bestimmt. Vergleiche der Analysenzahlen zeigen, daß sich die Branntweingruppen Obstbrände, Weinbrände und Getreidebrände deutlich voneinander abgrenzen und darüber hinaus z.B. zwischen Cognacs und Weinbränden bzw. zwischen schottischen, amerikanischen und kanadischen Whiskies unterschieden werden kann.
Summary By direct injection of 5–20 l of various spirits the following compounds can be separated and determined on gas-chromatographic columns using flame-ionization detectors: acetaldehyde, methyl acetate, ethyl acetate, methanol, butanol-2, propanol-1, 2-methyl-propanol-1, butanol-1, 2-methyl-butanol-1, 3-methyl-butanol-1 and hexanol-1. A comparison of the analytical results reveals distinct differences between spirits from fruit, wine and grain. Moreover, different analytical results are obtained for cognacs and (German) brandies, and for Scotch, American and Canadian whiskies.相似文献
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Outdoor sound propagation is significantly affected by the topography (including ground characteristics) and the state of the atmosphere. The atmosphere on its part is also influenced by the topography. A sound propagation model and a flow model based on a numerical integration of the linearized Euler equations have been developed to take these interactions into account. The output of the flow model enables the calculation of the sound propagation in a three-dimensionally inhomogeneous atmosphere. Rigid, partly reflective, or fully absorptive ground can be considered. The linearized Eulerian (LE) sound propagation model has been validated by means of four different scenarios. Calculations of sound fields above rigid and grass-covered ground including a homogeneous atmosphere deviate from analytic solutions by < or = 1 dB in most parts of the computed domain. Calculations of sound propagation including wind and temperature gradients above rigid ground agree well with measured scale model data. Calculations of sound propagation over a screen including ground of finite impedance show little deviations to measured scale model data which are probably caused by an insufficient representation of the complex ground impedance. Further calculations included the effect of wind on shading by a screen. The results agree well with the measured scale model data. 相似文献
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A novel 2:1 (permethylated-beta-cyclodextrin)-fullerene conjugate has been synthesised; highly soluble in cold water with formation of aggregates, it displays a negative solubility coefficient and has a partition coefficient between octanol and water (Log P = 1.58) in the suitable range for biological studies. 相似文献
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F.J. Himpsel K. Christmann P. Heimann D.E. Eastman Peter J. Feibelman 《Surface science》1982,115(3):L159-L164
We have studied carbon-induced two-dimensional energy bands on Ru(0001) using angleresolved photoelectron spectroscopy and have compared them with ab initio calculations. We find a nearly parabolic band (bottom at EF ?9.8 eV at k∥ = 0, effective mass ~ 1.5 me) which we assign to the C 2pz valence states of a graphitic carbon overlayer. Compared to graphite, these states are bound more tightly by 2.3 eV. 相似文献
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Band-selective measurements of electron dynamics in VO2 using femtosecond near-edge x-ray absorption
Cavalleri A Rini M Chong HH Fourmaux S Glover TE Heimann PA Kieffer JC Schoenlein RW 《Physical review letters》2005,95(6):067405
We report on the first demonstration of femtosecond x-ray absorption spectroscopy, made uniquely possible by the use of broadly tunable bending-magnet radiation from "laser-sliced" electron bunches within a synchrotron storage ring. We measure the femtosecond electronic rearrangements that occur during the photoinduced insulator-metal phase transition in VO2. Symmetry- and element-specific x-ray absorption from V2p and O1s core levels (near 500 eV) separately measures the filling dynamics of differently hybridized V3d-O2p electronic bands near the Fermi level. 相似文献
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Saes M Bressler C Abela R Grolimund D Johnson SL Heimann PA Chergui M 《Physical review letters》2003,90(4):047403
Accurate determination of the transient electronic structures, which drive photochemical reactions, is crucial in chemistry and biology. We report the detection of transient chemical changes on the picosecond time scale by x-ray-absorption near-edge structure of photoexcited aqueous [Ru(bpy)(3)](2+). Upon ultrashort laser pulse excitation a charge transfer excited state having a 300 ns lifetime is formed. We detect the change of oxidation state of the central Ru atom at its L3 and L2 edges, at a temporal resolution of 100 ps with the zero of time unambiguously determined. 相似文献