The structure of 1-phenyl-3-benzoylamino-4-benzoylpyrazol-2-in-5-one

Crystal and molecular structure of 1-phenyl-3-benzoylamino-4-benzoylpyrazol-2-in-5-one as a product of the benzoylation of 1-phenyl-3-benzoylaminopyrazol-2-in-5-one was characterised by X-ray single crystal diffraction. It is shown that 1-phenyl-3-benzoylamino-4-benzoylpyrazol-2-in-5-one exists in the solid phase in an NH-tautomeric form, which is stabilised by two intramolecular hydrogen bonds and one intermolecular bond with the solvate dioxane molecule, the latter being used as a solvent for recrystallisation.     

Electrochemical Generation of Pyrazolyl-Pyridyl N-Heterocyclic Carbene Complexes of Nickel

Russian Journal of Electrochemistry - By methods of cyclic voltammetry and preparative electrolysis, the electrochemical properties of sterically hindered imidazolium salt...     

Phosphine-Catalyzed Reactions of Imides and Hydrophosphoryl Compounds Addition to Divinyl Sulfone

Russian Journal of General Chemistry - An efficient method for the phosphine-catalyzed bisaddition of P(O)H compounds and cyclic imides to divinyl sulfone has been developed. The reaction proceeds...     

Small-Angle Neutron Scattering at the Pulsed Reactor IBR-2: Current Status and Prospects

Crystallography Reports - Neutron diffraction studies on the small-angle neutron spectrometer YuMO (Joint Institute for Nuclear Research, Dubna), based on the IBR-2 pulsed reactor, have been...     

Superconductivity on the localization threshold and magnetic-field-tuned superconductor-insulator transition in TiN films

Temperature-and magnetic-field-dependent measurements of the resistance of ultrathin superconducting TiN films are presented. The analysis of the temperature dependence of the zero-field resistance indicates an underlying insulating behavior, when the contribution of Aslamazov-Larkin fluctuations is taken into account. This demonstrates the possibility of the coexistence of the superconducting and insulating phases and of a direct transition from the one to the other. The scaling behavior of magnetic field data is in accordance with a superconductor-insulator transition (SIT) driven by quantum phase fluctuations in two-dimensional superconductor. The temperature dependence of the isomagnetic resistance data on the high-field side of the SIT has been analyzed, and the presence of an insulating phase is confirmed. A transition from the insulating to a metallic phase is found at high magnetic fields, where the zero-temperature asymptotic value of the resistance is equal to h/e².     

Photoelectron spectrum and quantum-chemical analysis of structure of bis(N-methoxydiazene-N-oxido)methane

A. E. Arbuzov Institute of Organic and Physical Chemistry, Kazan' Branch, Academy of Sciences of the USSR. Translated from Zhurnal Strukturnoi Khimii, Vol. 30, No. 2, pp. 74–79, March–April, 1989.     

Calculated characteristics of the anode region of a longitudinal discharge including diffusion

Translated from Zhurnal Prikladnoi Mekhaniki i Tekhnicheskoi Fiziki, No. 5, pp. 3–5, September–October, 1990.