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1.
Weihan Li Zongquan Wu Anqiu Zhang Marke E. Leland Jae-Young Park Frank W. Harris 《Journal of Macromolecular Science: Physics》2013,52(3):315-333
A high-performance aromatic polyimide fiber has been spun from a high molecular weight polyimide synthesized from 3,3′,4,4′-biphenyltetracarboxylic dianhydride (BPDA) and 2,2′-dimethyl-4,4′-diaminobiphenyl (DMB). The fiber exhibits not only excellent tensile properties and high temperature resistance but also a high compressive strength of 655 MPa. Morphological observations of BPDA-DMB fibers indicate that the fiber shows a skin-core structure and microfibrillar textures. A banded texture can also be found with a spacing of about 2μm, which may be introduced by the liquid crystalline behavior that appears during processing. Compressed BPDADMB fibers form kink and microkink bands over different size scales. The detailed formation mechanism of these banded textures is discussed. The structure parameter changes during compression-including crystal unit cell parameters, apparent crystallinity, crystal and overall orientation, and apparent crystallite sizes-are monitored. It is found that after restretching, the crystal and overall orientation is almost fully recovered while the apparent crystallinity is not recoverable. The structural changes during compression are critically associated with the loss of macroscopic mechanical property in the fibers. 相似文献
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Kaloper N 《Physical review letters》2005,94(18):181601
We construct exact gravitational field solutions for a relativistic particle localized on a tensional brane in brane-induced gravity. They are a generalization of gravitational shock waves in 4D de Sitter space. We provide the metrics for both the normal branch and the self-inflating branch Dvali-Gabadadze-Porrati brane worlds, and compare them to the 4D Einstein gravity solution and to the case when gravity resides only in the 5D bulk, without any brane-localized curvature terms. At short distances the wave profile looks the same as in four dimensions. The corrections appear only far from the source, where they differ from the long distance corrections in 4D de Sitter space. We also discover a new nonperturbative channel for energy emission into the bulk from the self-inflating [corrected] branch, when gravity is modified at the de Sitter radius. 相似文献
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Poul W. Marke 《Mathematische Annalen》1937,114(1):29-56
Ohne Zusammenfassung 相似文献
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We show that for every there exists C > 0 such that if then asymptotically almost surely the random graph contains the kth power of a Hamilton cycle. This determines the threshold for appearance of the square of a Hamilton cycle up to the logarithmic factor, improving a result of Kühn and Osthus. Moreover, our proof provides a randomized quasi‐polynomial algorithm for finding such powers of cycles. Using similar ideas, we also give a randomized quasi‐polynomial algorithm for finding a tight Hamilton cycle in the random k‐uniform hypergraph for . The proofs are based on the absorbing method and follow the strategy of Kühn and Osthus, and Allen et al. The new ingredient is a general Connecting Lemma which allows us to connect tuples of vertices using arbitrary structures at a nearly optimal value of p. Both the Connecting Lemma and its proof, which is based on Janson's inequality and a greedy embedding strategy, might be of independent interest. 相似文献
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Nemanja Trišović Nebojša Banjac Nataša Valentić Gordana Ušćumlić 《Journal of solution chemistry》2009,38(2):199-208
The absorption spectra of nine compounds structurally related to phenytoin (5,5-diphenylhydantoin) were recorded in twelve
solvents over the range of 200 to 400 nm. The effects of solvent dipolarity/polarizability and solvent/solute hydrogen bonding
interactions were analyzed by means of the linear solvation energy relationship (LSER) concept proposed by Kamlet and Taft.
The lipophilic activity of the investigated hydantoins was estimated by calculation of their log 10
P values. The calculated values of log 10
P were correlated with the ratio of the contributions of specific and non-specific solute/solvent interactions. The correlation
equations were combined with the corresponding ED50 values to generate new equations that demonstrate exact relationship between solute/solvent interactions and the structure-activity
parameters. 相似文献
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Izabela Spaleniak Simon Gross Nemanja Jovanovic Robert J. Williams Jon S. Lawrence Michael J. Ireland Michael J. Withford 《Laser \u0026amp; Photonics Reviews》2014,8(1):L1-L5
The first demonstration of narrowband spectral filtering of multimode light on a 3D integrated photonic chip using photonic lanterns and waveguide Bragg gratings is reported. The photonic lanterns with multi‐notch waveguide Bragg gratings were fabricated using the femtosecond direct‐write technique in boro‐aluminosilicate glass (Corning, Eagle 2000). Transmission dips of up to 5 dB were measured in both photonic lanterns and reference single‐mode waveguides with 10.4‐mm‐long gratings. The result demonstrates efficient and symmetrical performance of each of the gratings in the photonic lantern. Such devices will be beneficial to space‐division multiplexed communication systems as well as for units for astronomical instrumentation for suppression of the atmospheric telluric emission from OH lines. 相似文献
8.
Milo S. Jovanovi Nemanja Krgovi Katarina avikin Jelena
ivkovi 《Molecules (Basel, Switzerland)》2022,27(21)
The residue after sieving (“dust”) from the willow gentian underground parts is an unexploited herbal tea by-product, although it contains valuable bioactive compounds. Cyclodextrins as efficient green co-solvents, cage molecules, and multifunctional excipients could improve the extraction and contribute to the added value of the resulting extracts. The objective of this study was to determine the optimal conditions for the extraction of gentiopicroside, isogentisin, and total phenolics (TPC) from willow gentian “dust” using ultrasound-assisted water extraction coupled with hydroxypropyl-β-cyclodextrin (HPβCD). The influence of extraction temperature (X1: 20–80 °C), time (X2: 20–50 min), and HPβCD concentration (X3: 2–4% w/v) was analyzed employing the response surface methodology (RSM). The optimal extraction conditions for simultaneously maximizing the extraction yield of all monitored responses were X1: 74.89 °C, X2: 32.57 min, and X3: 3.01% w/v. The experimentally obtained response values under these conditions (46.96 mg/g DW for gentiopicroside, 0.51 mg/g DW for isogentisin, and 12.99 mg GAE/g DW for TPC) were in close agreement with those predicted, thus confirming the suitability and good predictive accuracy of the developed RSM models. Overall, the developed extraction system could be an applicable alternative strategy to improve the extraction of bioactive compounds from the underutilized “dust” of willow gentian underground parts. 相似文献
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