Studies on the Intramolecular Inclusion Complexes of Functionalized Calixarenes with CH_3X (X=CN, NO_2)

ＩｎｔｒｏｄｕｃｔｉｏｎＯｎｅｏｆｔｈｅｍｏｓｔａｔｔｒａｃｔｉｖｅｆｅａｔｕｒｅｓｏｆｃａｌｉｘ[4]ａｒｅｎｅｓｉｓｔｈｅｉｒｃｕｐｌｉｋｅｓｔｒｕｃｔｕｒｅ ,ｗｈｉｃｈｗａｓｏｂｓｅｒｖｅｄｂｏｔｈｉｎｓｏｌ ｉｄｓｔａｔｅａｎｄｉｎｓｏｌｕｔｉｏｎ .Ｔｈｅｃａｖｉｔｙｄｅｆｉｎｅｄｂｙｔｈｅｃｏｎｅｃｏｎｆｏｒｍｅｒｏｆｔｈｉｓｍａｃｒｏｃｙｃｌｅｗａｓｅｘｔｅｎｓｉｖｅｌｙｅｍｐｌｏｙｅｄａｓａｂｉｎｄｉｎｇｓｉｔｅｆｏｒｔｈｅｒｅｃｏｇｎｉｔｉｏｎｏｆｎｅｕｔｒａｌｇｕｅｓｔｓｈａｖｉｎ…     

SAPO-34处理方法对吸附性能的影响

以二乙胺为结构导向剂, 在微波条件下合成了SAPO-34分子筛材料, 并分别在空气和氮气氛下1073 K焙烧. 考察了氮气氛下分子筛表面碳改性后对材料表面及水、甲醇和乙醇吸附性能的影响. 结果表明: 碳改性后SAPO-34比表面、孔容下降, 但孔径趋于均一. 与SAPO-34样品相比, 碳改性后SAPO-34吸水量从0.295 g/g降低到0.180 g/g, 甲醇/乙醇的吸附比从1.42提高到2.81.     

葡萄球菌肠毒素B基因的膜片电极支撑双层类脂膜核酸传感器的研究

本研究用膜片电极支撑双层类脂膜(BLMs)核酸传感器,检测葡萄球菌肠毒素B(SEB)基因。BLMs在膜片钳尖端形成后,传感器的检测电流大小和施加的电压成正比。通过在BLMs上固定针对SEB基因特异的直链十二烷烃链(0～273.65μg/L)修饰的单链寡核苷酸(C12-ssDNA)探针与膜片钳系统一同构建成膜片电极支撑BLMs核酸传感器。电流大小与探针的浓度呈正相关,线性回归方程I=5.49 2.94C;相关系数r=0.9962。SEB基因浓度在20～5000μg/L范围时,检测的电流信号与SEB基因浓度的自然对数呈负相关,线性回归方程I=1103.26-103.62lnC,相关系数r=0.9977;同时,核酸传感器有很好的特异性,与不产SEB的金葡菌属、其它食物中毒菌的基因组DNA和空白对照组反应无明显电信号响应。应用原子力显微镜对BLMs表面微观结构、ssDNA固定于BLMs上和BLMs上杂交洗脱后的表面微观结构进行观察。本研究构建的膜片电极支撑BLMs核酸传感器为SEB基因的检测提供了一种快速、灵敏、特异性强的方法。     

1986年哈雷彗星的分裂

1986年3月25日在新西兰John 山天文台拍摄的9张照片,显示出哈雷彗星的彗核分裂成相隔甚远的两个分立彗核。投影在天空切平面上的分离距离约为5×10³km。主核和小伴核都呈现有它们自身的彗发。伴核有一个高达几千公里的突出喷流,而且伴核必定在数天以内即消失不见。结合陈培生等的光电观测结果,看来分裂与一个爆发事件相关。并对有些照片作了数字成像增强处理。     

海啸、地震海啸与海啸地震

简要地介绍了海啸与地震海啸的成因、特点,分析了影响地震海啸的重要因素,阐述了海啸预警的物理基础.以2004年12月26日苏门答腊-安达曼MW9.0特大地震及其激发的印度洋特大海啸为例,说明除了地震的大小、地震机制、震源深度以外,震源破裂过程也是影响地震激发海啸的重要因素.通过对苏门答腊-安达曼特大地震及2005年3月28日苏门答腊北部特大地震进行分析对比,探讨了海啸地震的特征,阐明了进一步深入研究海啸地震的特征及其激发海啸的机制对于预防和减轻海啸灾害的重要意义.     

Traveling waves for nonlinear cellular neural networks with distributed delays

In this paper, we will establish the existence and nonexistence of traveling waves for nonlinear cellular neural networks with finite or infinite distributed delays. The dynamics of each given cell depends on itself and its nearest m left or l right neighborhood cells where delays exist in self-feedback and left or right neighborhood interactions. Our approach is to use Schauder?s fixed point theorem coupled with upper and lower solutions of the integral equation in a suitable Banach space. Further, we obtain the exponential asymptotic behavior in the negative infinity and the existence of traveling waves for the minimal wave speed by the limiting argument. Our results improve and cover some previous works.     

Properties of traveling waves for integrodifference equations with nonmonotone growth functions

In this paper, we will establish some new properties of traveling waves for integrodifference equations with the nonmonotone growth functions. More precisely, for c ≥ c _*, we show that either \({\lim\limits_{\xi\rightarrow+\infty} \phi(\xi)=u*}\) or \({0 < \liminf\limits_{\xi \rightarrow + \infty} \phi(\xi) < u* < \limsup \limits_{\xi\rightarrow+\infty}\phi(\xi)\leq b,}\) that is, the wave converges to the positive equilibrium or oscillates about it at +∞. Sufficient conditions can assure that both results will arise. We can also obtain that any traveling wave with wave speed c > c* possesses exponential decay at ?∞. These results can be well applied to three types of growth functions arising from population biology. By choosing suitable parameter numbers, we can obtain the existence of oscillating waves. Our analytic results are consistent with some numerical simulations in Kot (J Math Biol 30:413–436, 1992), Li et al. (J Math Biol 58:323–338, 2009) and complement some known ones.     

线型脲醛树脂的半结晶模板化作用

酸性条件下硅溶胶体系中尿素和甲醛聚合反应会产生脲醛树脂-氧化硅杂化沉淀. 沉淀的质量随有机组分比例的增加而增加, 当尿素和甲醛物质的量比≥1.0时生成沉淀的量为恒定最大值. 红外分析表明杂化材料在3348, 1635, 1572和784 cm^－1处产生了可被归结为线型结构(—[NHCONHCH₂]_n—)的特征吸收. XRD分析表明这种线型分子可形成氢键(C＝O…H—N)导向型的半结晶. 微分热重和XRD结果证明结晶物种在290 ℃完全分解. SEM表征显示半结晶杂化沉淀以三维网络结构为特征, 具有层状结晶的各向异性, 其初级粒子即使在室温下干燥也容易开裂. 随着反应时间的延长、酸性的增加或无机组分量的相对增加杂化粒子变得更加致密. 液氮吸附结果证明沉淀焙烧后所得氧化硅材料的结构具有层状孔结构性质, 其比表面积、孔尺寸和孔体积可以达到510 m²/g, 14.3 nm和1.68 cm³/g. 改变反应体系的酸性和反应组分配比等条件可以方便地控制杂化材料的结构.     

Efficient Detection of Environmental Estrogens Bisphenol A and Estradiol By Sensing System Based on AuNP-AuNP-UCNP Triple Structure

A sensing system based on AuNP-AuNP-UCNP triple structure for efficient detection of dual targets bisphenol A and estradiol was constructed. In the preparation of triple structure, the gold nanoparticles (AuNPs) and upconversion nanoparticles (NaYF₄: Yb, Er, Gd, UCNPs) were synthesized and surface modified. Then, the two nanoparticles and their aptamers were connected to form two kinds of optical fluorescent probes. A nucleic acid sequence that matches with two aptamers was designed, rendering the probes to get close based on the principle of complementary base pairing. On the basis of this, a sensing system with triple structure was prepared, and its connecting effect was characterized by TEM. With this system, dual targets of bisphenol A and estradiol were detected efficiently and conveniently through quantitatively determination by fluorescence and UV spectrophotometer. At the reaction temperature 30 °C and pH 7.8, this method exhibited good linear range for determination of bisphenol A and estradiol from 2 ng mL^–1 to 200 ng mL^–1 and from 10 ng mL^–1 to 150 ng mL^–1, with the limits of detection of 0.2 ng mL^–1 and 0.5 ng mL^–1, respectively. This sensing system with triple structure owned better specificity to structural and functional analogues, showed good repeatability and stability. What's more, this sensing system could be applied to actual water detection, with the recoveries of 86.1%–107.4%, and the relative standard deviation below 6.8%. This method shows promising applications in other environmental estrogens in water sample.     

5,11,17,23-四叔丁基-25,26,27,28-四[3-(甲氧基羰基)苄氧基]杯[4]芳烃包合性能的研究

杯芳烃是继冠醚和环糊精后的第三代主体化合物 .这类主体分子不仅可以识别和络合阳离子 ,而且还具有包合中性有机分子的性能 [1～ 5] .杯 [4]芳烃类包合物的晶体结构测定表明 ,它们可分为分子内和分子间包合两种类型 [3 ,5] ,前者是客体分子被包合在主体分子的空穴内 ,后者是客体分子被包合在主体分子之间 .对叔丁基杯 [4]芳烃的下沿酚氧基与上沿均可进行化学修饰得到不同的杯 [4]芳烃衍生物 .最早报道的对叔丁基杯 [4]芳烃及其衍生物的分子内包合物是与甲苯或乙腈的 1∶ 1包合物 [4 ,5] ,客体分子依靠 CH3 -π的作用被包结在主体分子内[6]…