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1.
利用三有机锡氢氧化物和手性配体(4R)-3-[[(2S)-5-氧-2-吡咯烷基]羰基]-4-噻唑烷甲酸(HL)反应合成了3个三有机锡(4R)-3-[[(2S)-5-氧-2-吡咯烷基]羰基]-4-噻唑烷甲酸酯R3SnL[1,R=c-C6H11(a),C6H5(b),C6H5C(CH3)2CH2(c)],通过元素分析、IR、1H NMR和X-射线单晶衍射表征了其结构。化合物1a属正交晶系,P212121空间群;化合物1b属单斜晶系,P21空间群。二者均为由羧基氧和内酰胺羰基氧桥联配位形成的右螺旋链状有机锡配位聚合物,锡原子具有五配位[SnC3O2]畸变三角双锥构型。化合物1a和1b对体外2种人癌细胞Colo205和Bcap37增殖均有强的抑制作用,其活性为1b1a。 相似文献
2.
Zhang ZK Bai ML Guo DZ Hou SM Zhang GM 《Chemical communications (Cambridge, England)》2011,47(29):8439-8441
A novel plasma-electrolysis method is introduced to synthesize high-quality TiO(2) nano/microspheres that exhibited excellent optical absorption covering the range from ultraviolet to infra-red. Both experimental and theoretical results show that the oxygen vacancies in the TiO(2) spheres are primarily responsible for this wide absorption. 相似文献
3.
通常的扩散控制反应理论是以球形对称反应体系为背景的,故用在计算酶与带电底物结合反应速率的最大限度时,不可能较合理地考虑各种影响反应速率的效应。而且,在现有的实验中,已出现了这样的佯谬:一些酶与带电底物结合反应的速率比按通常理论所算得的结合速率的最大限度还要大!因此,重新探讨酶-带电底物反应体系中的各种效应,就显得十分必要。为此,本文在以前工作的基础上,探讨了这种非球形对称快速反应体系的动力学特性。通过计算,给出了方向因子、力程因子与离子强度、反应物所带电荷间的定量关系,从而为酶与带电底物的结合反应提供了新的最大限度。并应用到延胡索酸酶及D-甘油醛-3-磷酸脱氢酶的反应中,解释了通常的扩散控制反应理论所不能解释的现象。此外,还探讨了非平衡定态反应体系中Brφnsted方程成立的条件。 相似文献
4.
The quantum nonthermal radiation and horizon surface gravity of an arbitrarily accelerating black hole with electric charge and magnetic charge 下载免费PDF全文
Using a new tortoise coordinate transformation,we discuss the quantum nonthermal radiation characteristics near an event horizon by studying the Hamilton-Jacobi equation of a scalar particle in curved space-time,and obtain the event horizon surface gravity and the Hawking temperature on that event horizon.The results show that there is a crossing of particle energy near the event horizon.We derive the maximum overlap of the positive and negative energy levels.It is also found that the Hawking temperature of a black hole depends not only on the time,but also on the angle.There is a problem of dimension in the usual tortoise coordinate,so the present results obtained by using a correct-dimension new tortoise coordinate transformation may be more reasonable. 相似文献
5.
We present a new method called the permutation matrix method to perform dense coding using Greenberger--Horne--Zeilinger (GHZ) states. We show that this method makes the study of dense coding systematically and regularly. It also has high potential to be realized physically. 相似文献
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7.
Zhi-Kun Rao Jing Long Cong Li Sui-Shuan Zhang Mei He Ling-Cheng Ou Yong-Tang Zheng Yan-Ping He 《Monatshefte für Chemie / Chemical Monthly》2008,139(8):967-974
Several 2-heteroaryl-, 2-heteroarylcarbonylmethyl-, 2-arylcarbonylmethyl, and 2-arylethyl derivatives of S-dihydro(alkyloxy)benzyloxypyrimidines have been synthesized and the anti-HIV activities of these compounds were tested in
C8166 cell and against RT enzyme. It was found that some of these compounds showed good activity against HIV-1 (EC
50 = 0.014–0.8 μM) with low toxicity (CC
50 value of 222–564 μM) and high selectivity (SI value of 278–37743). The structure-activity relationships (SAR) of these compounds have also been discussed.
First two authors contributed equally to this work
Correspondence: Yan-Ping He, Key Laboratory of Medicinal Chemistry for Natural Resource Ministry of Education, School of Chemical
Science and Technology, Yunnan University, Kunming 650091, People’s Republic of China; Yong-Tang Zheng, Laboratory of Molecular
Immunopharmacology, Key Laboratory of Animal Models and Human Disease Mechanisms, Chinese Academy of Sciences, Kunming Institute
of Zoology, Kunming, Yunnan 650223, People’s Republic of China. 相似文献
8.
Zhi-Kun Su Jia-Ning Xie Na Li Chuan-Yun Zhu Ding-An Han 《International Journal of Theoretical Physics》2014,53(2):409-418
Recently a quantum teleportation scheme has been analyzed by Wangner et al. (J. Opt. Soc. Am. B 27:A73–A80, 2010) which is based on spatially and temporarily resolved collective spontaneous emission. We study a similar model, which has the two atoms trapped in a resonant cavity instead of in the free vacuum space. It is found that the quantum channel experiences entanglement of sudden death (ESD), yet every time this channel can recover after an interval of time. Surprisingly, we demonstrate there exits another channel to assist the initial channel to complete the teleportation, and the fidelity can be well beyond the classical limit of 2/3, with the increase of dipole-dipole interaction. 相似文献
9.
三唑并噻二唑衍生物的合成及抑菌活性 总被引:1,自引:0,他引:1
为了寻找高活性农药先导化合物,考虑到三唑并噻二唑衍生物具有广泛的生物活性,本文利用活性亚结构拼接原理,将活性基团分别引入1,2,4-均三唑并[3,4-b]-1,3,4-噻二唑杂环的3位和6位,合成了未见文献报道的3,6-二取代均三唑并[3,4-b]-1,3,4-噻二唑类化合物11个,并用IR、1HNMR及元素分析测试技术对其进行了结构表征。抑菌活性生物测定结果表明,合成的大部分化合物对黄瓜灰霉病菌(Botrytis cinerea)均有较好的生长抑制作用,其中,化合物5ae、5ag和5bd的抑制率达到70%;化合物5ad、5cd、5ce的抑制率大于60%;5bd对水稻纹枯病菌(Pellicularia sasakii)抑制率大于60%,化合物5cg对西瓜炭疽病菌(Colletotrichum lagenarium)的抑制率为69%。 相似文献
10.
Nai-Xing Wang Lei Wang Wei Jiang Yue-Zhen Ren Zhi-Kun Si Xun-Xing Qiu Gao-Ying Du Ping Qi 《Analytical and bioanalytical chemistry》1998,361(8):821-824
Norfloxacin (NFX) is proposed as reagent for the derivative spectrophotometric determination of neodymium, holmium and erbium
in mixed rare earths. The absorption spectra of 4f electron transitions of the systems of neodymium, holmium and erbium complexes
with norfloxacin in presence of cetylpyridinium chloride were studied by normal and derivative spectra. The absorption bands
found normally at 575 nm for neodymium, 450 nm for holmium and 523 nm for erbium were enhanced markedly. Using the second
derivative spectrum, Beer’s Law is obeyed from 5.0 × 10–5∼ 2.5 × 10–4 mol dm–3 for neodymium, holmium and erbium. The relative standard deviations are 1.0, 1.4 and 1.1% for 6.9 × 10–5 mol dm–3 of neodymium, 6.1 × 10–5 mol dm–3 of holmium and 6.0 × 10–5 mol dm–3 of erbium, respectively. A method for the direct determination of neodymium, holmium and erbium in mixtures of rare earth
elements with good accuracy and selectivity, is described.
Received: 18 December 1997 / Revised: 23 February 1998 / Accepted: 26 February 1998 相似文献