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排序方式: 共有85条查询结果,搜索用时 18 毫秒
1.
Synthesis and Herbicidal Activity of Novel Sulfonylureas Containing Thiadiazol Moiety 总被引:1,自引:0,他引:1
Thirteen novel sulfonylureas containing thiadiazole moiety were synthesized in a two-step reaction. Their structures were determined using IR, ^1H NMR, HRFTMS, and elemental analysis. Herbicidal activities of these compounds were determined in the green house bio-assay. The results show that four compounds among them exhibit some activity toward four tested herbs. 相似文献
2.
多源单汇网络资源调度路径优化探讨 总被引:1,自引:0,他引:1
在考虑队列长度的前提下 ,论文在分析多源单汇资源传输问题的基础上 ,以两源单汇网络为例 ,在资源到达终点所需时间最短约束下 ,研究、计算了最短传输时间的上下界 ,并提出了相应的算法 .论文的研究内容为进一步研究多源多汇问题建立了基础 ,提供了思路 . 相似文献
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本文对理想流体与线弹性结构的耦联振动问题作理论分析和数值分析.文中证明了耦联振动的固有频率存在并且均为正实数.将流-固耦合系统分析转化为单一结构物在真空中的自由振动分析后,频率方程中不再含有流体变元.使问题得以大大简化.给出了数值解的收敛性证明,以保证解的可靠性.文中还综合里兹法、边界元和有限元方法,提出一种分析转化后结构的混合算法.利用该算法,只需对现有结构分析程序稍作改进,就可分析那些理想流场与结构的耦合问题.一些数例说明了算法的有效性. 相似文献
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ZHOU Yun-yun LI Yu-xin LI Yi-ming YANG Xiao-ping MAO Ming-zhen LI Zheng-ming 《高等学校化学研究》2013,29(2):249-255
Carbohydrates, with broad-spectrum structures and biological functions, are key organic compounds in nature, along with nucleic acids and proteins. As part of our ongoing efforts to develop a new class of pesticides with novel mechanism of action, a series of novel N-glycosyl-1-pyridyl-1H-pyrazole-5-carboxamide was designed and synthesized via the reactions of glycosyl methanamides and pyridyl-pyrazole acid. The compounds were characterized by 1H NMR and 13C NMR. The bioassay results indicate that some of these compounds exhibit moderate insecticidal activities and assessed as potential inhibitors of calcium channels. The modulation of voltage-gated calcium channels by compounds 4a and 5a in the central neurons isolated from the third instar larvae of Spodoptera exigua was studied by whole-cell patch-clamp technique. In addition, compound 5a inhibits the recorded calcium currents reversible on washout. Experimental results also indicate that compound 5a did not release stored calcium from the Endoplasmic Reticulum. The present work demonstrates that N-glycosyl-1-pyridyl-1H-pyrazole-5-carboxamides cannot be used as possible inhibitors of calcium channels for developing novel pesticides. 相似文献
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ZHAO Yu LI Yong-qiang XIONG Li-xia XU Li-ping PENG Li-na LI Fang LI Zheng-ming 《高等学校化学研究》2013,29(1):51-56
In search of environmentally benign insecticides with high activity, low toxicity and low residue, a series of novel anthranilic diamide derivatives containing N-pyridylpyrazole was designed and synthesized. All the compounds were characterized by 1H NMR spectroscopy and elemental analysis. The single crystal structure of compound 8j was determined by X-ray diffraction. The insecticidal activities of the new compounds were evaluated. The results show that some compounds exhibited moderate insecticidal activities against Lepidoptera pests. Among this series of compounds, compounds 8o and 8p showed 100% larvicidal activity against Mythimna separate Walker, Plutella xylostella Linnaeus and Laphygma exigua Hubner at a test concentration of 200 mg/kg, which is equal to the commercial chlorantraniliprole. 相似文献
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Yu Zhao Li-ping Xu Jun Tong Yong-qiang Li Li-xia Xiong Fang Li Li-na Peng Zheng-ming Li 《Molecular diversity》2012,16(4):711-725
In searching for environmentally benign insecticides with high activity, low toxicity and low residue, two series of novel anthranilic diamide containing methyl ether and isopropyl ether group were designed and synthesized. All of the compounds were characterized by 1H NMR spectroscopy, 13C NMR spectroscopy and elemental analysis. The single crystal structure of 19j was determined by X-ray diffraction. The insecticidal activities of the new compounds were evaluated. The results showed that some compounds exhibited excellent insecticidal activities against Lepidoptera pests. Among this series, compound, 18l showed 100?% larvicidal activity against Mythimna separate Walker, Plutella xylostella Linnaeus and Laphygma exigua Hubner at the test concentration, which was equal to the available chlorantraniliprole. 相似文献
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本文研究了面板约束效应对蜂窝芯弹性性能的影响并基于六边形蜂窝芯夹层板的代表性体单元建立了考虑面板约束效应的蜂窝芯位移模式.根据真实蜂窝芯代表性单元与其等效材料的代表性单元在宏观均匀应变作用下的总弹性应变能相等,导出了蜂窝芯材料等效弹性常数的公式,进一步探讨了蜂窝几何参数对其弹性常数的影响规律.通过与现有理论结果、有限元结果和实验数据进行对比证实本文导出的弹性常数公式具有较好的预报精度.结果表明面板约束对蜂窝芯等效弹性常数有显著影响. 相似文献
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