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1.
The title compound (C2H7NO·C7H4N2O6) has been obtained by the reaction of etha- nolamine with 3,5-dinitrobenzoic acid in deionized water at room temperature. The crystal crystal- lizes in orthorhombic, space group P212121 with a = 6.048(2), b = 9.146(3), c = 21.955(7)(A), C9H11N3O7, Mr = 273.21, Z = 4, V = 1214.3(7)(A)3, Dc = 1.494 g/cm3, F(000) = 568, μ(MoKα) = 0.131 mm-1, R1 = 0.0338 and wR2 = 0.0497. The new organic adduct is composed of one ethanolamine and one 3,5-dinitrobenzoic acid, which are linked up by O-H…O and N-H…O types of hydrogen bonds to form a nine-membered ring and an eleven-membered ring, extending into a one-dimensional network structure. 相似文献
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ZHU Jun ZHANG Yun CHEN Hao CHE Yun-Xia ZHENG Ji-Min ② 《结构化学》2006,25(8):1011-1013
1 INTRODUCTION Nonlinear optics (NLO) is at the forefront of cur- rent researches because of its importance in provi- ding the key functions of frequency shifting, optical modulation, optical switching, optical logic and op- tical memory for the emerging … 相似文献
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The title compound glycin·3,5-dihydroxybenzoic acid (GDB) has been synthesized and characterized by single-crystal X-ray analysis. It crystallizes in orthorhombic, space group Pca21 with a = 25.513(10), b = 4.668(2), c = 9.150(4)(A), Z = 4, V = 1089.8(8)(A)3, C9H13NO7, Mr = 247.20, Dc = 1.507 g/m3, μ(MoKα) = 0.132 mm-1, F(000) = 520, R1 = 0.0322 and wR2 = 0.0611 for 885 observed reflections (I > 2σ(I)). The title compound is a 1:1 molecular complex of glycin and 3,5-dihydroxybenzoic acid, which is linked by O-H…O and N-H…O hydrogen bonds to form a three-dimensional framework. Test of SHG (second harmonic generation) indicates that NLO generation of the crystal is higher than that of KDP. 相似文献
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1 INTRODUCTION Supramolecular chemistry is based on the notion of creating novel structural and functional extended systems using noncovalent interactions between prefabricated molecular or ionic building blocks[1]. More recently, the design of supramolecular architec- tures by self-assembly of small building blocks has become a major research area[2, 3] due to their poten- tial applications in many fields such as selective clathration[4, 5], molecular recognition[6, 7], catalysis[8, 9] a… 相似文献
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A new dysprosium-zinc coordination polymer {[Dy2Zn(dinic)4(H2O)8]·H2O}n 1(H2dinic = 2,5-pyridinedicaboxylic acid) has been synthesized and structurally characterized by X-ray analysis. The complex (C28H30Dy2N4O25Zn, Mr = 1212.94) crystallizes in triclinic, space group P-1 with a = 7.8911(16), b = 9.3177(19), c = 13.029(3)(A), α = 75.29(3), β = 75.04(3), γ =79.00(3)°, V = 887.1(3)(A)3, Z = 1, Dc=2.236 g/cm3,μ(MoKα) = 4.947 mm-1, F(000) = 570, the final R = 0.0345 and wR = 0.0903 for 3644 observed reflections with I> 2σ(I). A two-dimensional supramolecular structure is formed in 1, which was characterized by elemental analysis, IR, TG analysis, and single-crystal X-ray diffraction. 相似文献
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Dielectric Properties of Multilayered Ba0.5Sr0.5TiO3 Thin Films Deposited on ITO-Coated Corning 1737 Glass by rf Magnetron Sputtering 总被引:1,自引:0,他引:1
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A new stacking method via variation ofsubstrate temperature in rfmagnetron sputter is used to fabricate polycrystalline/polycrystalline Ba0.5Sr0.5TiO3 thin films with higher dielectric constant, higher breakdown strength and lower leakage current densities than those prepared by a conventionM deposition method. The improved figure of merit G (ε0εrEb) of the Ba0.5Sr0.5TiO3 thin films implies that they are a feasible insulation layer for thin film electroluminescent devices. 相似文献
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基于啁啾脉冲放大技术的超短脉冲激光系统是提供超快、超强激光的重要途径,具有良好输出波形和高损伤阈值的多层介质膜脉冲宽度压缩光栅是获得高峰值功率脉冲激光的关键. 基于傅里叶谱变换方法和严格模式理论,分析了多层介质膜光栅(MDG)在超短脉冲作用下的光学特性. 结果表明,当MDG的反射带宽小于具有高斯分布的入射脉冲的频谱宽度时,-1级反射脉冲呈非对称高斯分布,其前沿出现振荡,并且-1级反射脉冲能量开始剧烈下降. 讨论了MDG结构参数对其反射带宽的影响. 分析了MDG与超短脉冲作用时的近场光分布,对提高其抗激光损
关键词:
脉冲压缩光栅
傅里叶谱变换
模式理论
损伤阈值 相似文献