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JPC – Journal of Planar Chromatography – Modern TLC - In this work we have studied the separation of a mixture of the sulfonylurea herbicides (metsulfuron-methyl, chlorsulfuron,... 相似文献
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本文提出平行催化体系的对位叠式循环方波伏安法,并对共作了系统的研究,推导了这一方法的催化电流理论方程,并用验验证这理论的正确性,得到其各脉冲电流皆为同方向,对位叠式循环催化电流相当于将电流叠加4次,而波形不受方波幅度大小的影响,因而灵敏度和分辨率有较大提高,优于其它方波伏安法。 相似文献
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Jia Sun Peicheng Zhang Qi Wei Hang Xun Feng Tang Yongde Yue Li Li Xuefeng Guo Rong Zhang 《Tetrahedron letters》2014
Amarusine A (1), a new polyketide derivative possessing an unusual dioxaspiro[4.4]nonane derivative with a butyrolactone ring, was isolated from the leaves of Pleioblastus amarus. The structure and absolute stereochemistry of compound 1 were rigorously determined using UV, IR, HRESIMS, and 1D and 2D NMR techniques and by comparing experimental and calculated electronic circular dichroism (ECD) spectra. Amarusine A (1) exhibits a good antioxidant activity for scavenging the DPPH radical. A possible biosynthetic pathway was postulated. 相似文献
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采用涂覆法在镁锂合金表面制备了含双-[3-(三乙氧基硅)丙基]四硫化物(KH-69硅烷)改性纳米ZrO2的环氧树脂涂层. 通过傅里叶变换红外光谱(FTIR)、 扫描电子显微镜(SEM)和电化学阻抗谱(EIS)等手段表征了该涂层. 考察了KH-69硅烷改性纳米ZrO2浓度对环氧树脂涂层耐蚀性能的影响. 结果表明, KH-69硅烷改性纳米ZrO2能显著提高镁锂合金表面环氧树脂涂层的耐腐蚀性能, 其中1.0%(质量分数) KH-69硅烷改性纳米ZrO2环氧树脂涂层具有较好的耐蚀性能. 在NaCl溶液中浸渍528 h后的低频阻抗值为1.6×109 Ω·cm2, 相比在NaCl溶液中浸渍240 h的纯环氧树脂涂层提高约5个数量级. 相似文献
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Yingcai Wang Mei Li Milin Zhang Wei Han Tao Jiang Yongde Yan 《Journal of Solid State Electrochemistry》2018,22(12):3689-3702
Cyclic voltammogram and square wave voltammograms indicated that Cu (II) ion being reduced to Cu(0) was a two-electron process: Cu(II)?+?e??→?Cu(I) and Cu(I)?+?e??→?Cu(0). The diffusion activation energy for Cu (I) ions was calculated as 42.85 kJ mol?1. The equilibrium potential and apparent standard potential for Cu (I)/Cu(0) redox couple was measured by open circuit chronopotentiometry at a temperature of 773–923 K. Three reduction peaks, corresponding to the formation of PrxCuy intermetallic compounds, were detected from cyclic voltammogram and square wave voltammogram obtained by co-reduction of Pr (III) and Cu (II) or electrodeposition of Pr (III) on Cu electrode. Furthermore, potentiostatic electrolysis was performed to extract the element Pr on Cu electrode, and the electrolytic products were analyzed by scanning electron microscopy equipped with energy dispersive spectrometry. Meanwhile, the highest extraction efficiency of Pr (III) ions could reach about 99.81% at ??2.20 V for 22 h at 823 K. 相似文献
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High-performance thin-layer chromatographic analysis of selected organophosphorous pesticide residues in tea 总被引:1,自引:0,他引:1
The separation of 9 organophosphates (monocrotophos, quinalphos, triazophos, parathion-methyl, isofenphos-methyl, temephos, parathion, phoxim-ethyl, and chlorpyrifos) by high-performance thin-layer chromatography (HPTLC) with automated multiple development was studied. The HPTLC method was developed and validated for analysis of residues of phoxim-ethyl and chlorpyrifos in tea. The sample was extracted with acetonitrile and cleaned up by ENVI-CARB solid-phase extraction. The extract was directly applied as bands to glass-backed silica gel 60F254 HPTLC plates. The plates were developed with dichloromethane-hexane (1 + 1, v/v) in a glass twin-trough chamber. Evaluation of the developed HPTLC plates was performed densitometrically. The results indicated that the detection limits of phoxim and chlorpyrifos were 5.0 x 10(-9) and 1.0 x 10(-8) g, respectively. Recoveries of the pesticides from tea by this analytical method were 90.7-105.5%, and relative standard deviations were 7.3-13.5%. The precision and accuracy of the method were generally satisfactory for analysis of pesticide residues in tea. 相似文献
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Pengbo Cui Linjie Zhao Dr. Yongde Long Prof. Liming Dai Prof. Chuangang Hu 《Angewandte Chemie (International ed. in English)》2023,62(14):e202218269
Oxygen reduction reaction (ORR) is vital for clean and renewable energy technologies, which require no fossil fuel but catalysts. Platinum (Pt) is the best-known catalyst for ORR. However, its high cost and scarcity have severely hindered renewable energy devices (e.g., fuel cells) for large-scale applications. Recent breakthroughs in carbon-based metal-free electrochemical catalysts (C-MFECs) show great potential for earth-abundant carbon materials as low-cost metal-free electrocatalysts towards ORR in acidic media. This article provides a focused, but critical review on C-MFECs for ORR in acidic media with an emphasis on advances in the structure design and synthesis, fundamental understanding of the structure-property relationship and electrocatalytic mechanisms, and their applications in proton exchange membrane fuel cells. Current challenges and future perspectives in this emerging field are also discussed. 相似文献