全文获取类型
收费全文 | 619篇 |
免费 | 10篇 |
国内免费 | 6篇 |
专业分类
化学 | 260篇 |
晶体学 | 5篇 |
力学 | 34篇 |
数学 | 106篇 |
物理学 | 230篇 |
出版年
2022年 | 5篇 |
2021年 | 11篇 |
2019年 | 12篇 |
2018年 | 9篇 |
2017年 | 14篇 |
2016年 | 25篇 |
2015年 | 11篇 |
2014年 | 14篇 |
2013年 | 23篇 |
2012年 | 29篇 |
2011年 | 32篇 |
2010年 | 19篇 |
2009年 | 16篇 |
2008年 | 34篇 |
2007年 | 27篇 |
2006年 | 19篇 |
2005年 | 17篇 |
2004年 | 18篇 |
2003年 | 13篇 |
2002年 | 11篇 |
2001年 | 13篇 |
2000年 | 11篇 |
1999年 | 5篇 |
1998年 | 7篇 |
1997年 | 7篇 |
1996年 | 6篇 |
1994年 | 4篇 |
1993年 | 8篇 |
1992年 | 4篇 |
1991年 | 5篇 |
1990年 | 6篇 |
1989年 | 5篇 |
1988年 | 6篇 |
1987年 | 4篇 |
1986年 | 12篇 |
1985年 | 11篇 |
1984年 | 17篇 |
1983年 | 9篇 |
1982年 | 10篇 |
1981年 | 11篇 |
1980年 | 12篇 |
1979年 | 5篇 |
1978年 | 7篇 |
1977年 | 10篇 |
1976年 | 7篇 |
1975年 | 12篇 |
1974年 | 9篇 |
1973年 | 6篇 |
1970年 | 6篇 |
1966年 | 7篇 |
排序方式: 共有635条查询结果,搜索用时 15 毫秒
1.
S. Ya. Gus'kov M. Yu. Mazur Yu. A. Mikhailov V. B. Rozanov A. V. Rode A. V. Sartori G. V. Sklizkov 《Journal of Russian Laser Research》1990,11(5):392-406
The preheating level of the thermonuclear fuel and of the gas-compressing shell is the main criterion of the target-compression efficiency in experiments on laserdriven thermonuclear fusion. This paper contains the result of investigations of electronic, radiative, and impact preheating in experiments on compression and heating of hlgh-aspect shell targets in the Del'fin-l laser-derived thermonuclear facility. A procedure, based on analysis of the epithermal emission of the plasma, is considered for measuring the target preheating by fast electrons. The radiative and impact preheating of compressing shells in DD gas are estimated. The results of the investigation demonstrate the high degree of adiabaticity of the compression of the thermonuclear fuel in experiments with the Del'fin-l facility.Nuclear Plasma Laboratory of the Lebedev Physics Institute. Translated from Preprint No. 3, Lebedev Physics Institute, Academy of Sciences of the USSR, Moscow, 1990. 相似文献
2.
A nonadiabatic quantum dynamic model has been developed to study the process of electron emission from a low-work-function metal surface. The process is initiated by scattering a highly vibrationally excited NO molecule from a surface composed of a Cs layer covering a Ru crystal. The model addresses the increasing quantum yield of the electron emission as a function of the molecular vibrational excitation and incident kinetic energy. The reaction mechanism is identified as a long-range harpooning electron transfer to a molecular ion which is then accelerated toward the surface. Upon impact, the molecular ion emits its excess electron. 相似文献
3.
P. M. Kochergin I. A. Mazur G. K. Rogul'chenko E. V. Aleksandrova B. E. Mandrichenko 《Chemistry of Heterocyclic Compounds》2001,37(2):224-226
Two novel preparative methods have been developed for the synthesis of 2,3-dihydroimidazo[1,2-a]pyrimidine from 2-aminopyrimidine. These are the reaction with 1,2-dibromoethane and also the reaction with ethylene chloro(bromo)hydrin, subsequent treatment of 1--hydroxyethyl-2-imino-1,2-dihydropyrimidine with thionyl chloride, and cyclization of the intermediate 1--chloroethyl-2-imino-1,2-dihydropyrimidine in the presence of sodium hydroxide. 相似文献
4.
L. Margulies N. Friedman M. Sheves Y. Mazur M.E. Lippitsch M. Riegler F.R. Aussenegg 《Tetrahedron》1985,41(1):191-195
Linear dichroism spectra of several retinoids and related polyenes incorporated in stretched polyethylene films were determined. It is suggested that the retinoids are oriented with the plane of the ring parallel to the stretching direction of the film, the long polyene chain being displaced from that direction. 相似文献
5.
Rahimipour S Litichever-Coslovsky N Alaluf M Freeman D Ehrenberg B Weiner L Mazur Y Fridkin M Koch Y 《Photochemistry and photobiology》2005,81(2):250-258
A combination of light, oxygen and a photosensitizer is used to induce death of cancer cells by photodynamic therapy. In this study, we have synthesized several new methyl helianthrone derivatives and compared their phototoxicity with that of hypericin. In contrast to hypericin, methyl helianthrones are soluble in aqueous solutions and have a broad range of light absorbance, which allows the use of polychromatic light. Structural modifications of methyl helianthrone demonstrated that substitution of hydrogen atoms of methyl helianthrone at Positions 2 and 5 with Br atoms or methylation of its phenolic hydroxyls, significantly increases the corresponding singlet oxygen quantum yield and their phototoxicity toward alphaT3-1, M2R and LNCaP cells. The phototoxicity of some of these compounds was similar to that of hypericin. Methyl helianthrones, like hypericin, accumulated mainly in the perinuclear region as evident by confocal microscopy. Irradiation of cells pretreated with methyl helianthrone derivatives generates intracellular reactive oxygen species and lipid free radicals, as shown by a fluorescentic probe and electron paramagnetic resonance methods, respectively. The phototoxicity of these methyl helianthrones as well as their ability to oxidize membrane lipids were significantly decreased on addition of specific Type-II inhibitors, suggesting the involvement of singlet oxygen as the main oxidant. 相似文献
6.
Dan Veierov Tuvia Bercovici Ernst Fischer Yehuda Mazur Amnon Yogev 《Helvetica chimica acta》1975,58(4):1240-1243
Enol-esters 1a-1e undergo clean Photo-Fries-rearrangements without side reactions. With anthroyl derivatives the reaction is observed only at 254 nm, not at 366 nm. 相似文献
7.
Time resolved chemiluminescence spectra of pure tetramethyldioxetane are obtained for the first time using pulsed infrared laser excitation. The only major product, acetone, is shown to be formed by at least two pathways: a unimolecular, collision free, decomposition and a collision induced mechanism. Spectral and temporal behaviour indicate that neither singlet nor triplet acetone are the primary products. Other possibilities are discussed. 相似文献
8.
We consider Albrecht's theory for Raman scattering of fundamentals in the far and pre-resonance regions. Destructive interferences inherent to the A and B terms augment the conventionally suppressed C term dramatically. Raman excitation profiles for the ν1(a1g) and ν6(e2g fundamentals in benzene can be well fitted with theoretical C-term profiles involving the 1E1u(π-π*) state at 1800 A. 相似文献
9.
10.
K. I. Dikovskaya I. V. Turovskii T. V. Mazur Ya. F. Freimanis 《Chemistry of Heterocyclic Compounds》1993,29(8):878-882
A study was made of the condensation of bicyclic -lactone I with furylacrolein and furylpropionic aldehyde. Significant differences were observed in the reactivity of the aldols obtained, and in the stereochemical trend of their dehydration reaction.For Communication 35, see [1].Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 8, pp. 1035–1039, August, 1993. 相似文献