纳米SiO_2/聚丙烯酸酯复合乳液的制备与表征

根据核壳乳液聚合理论,以经过硅烷偶联剂表面改性的纳米SiO2为种子,采用适当的乳液聚合工艺,制备了纳米SiO2/聚丙烯酸酯复合乳液,并表征了其性能.结果表明,纳米SiO2经过改性后,硅烷偶联剂接枝在其表面;以其为种子制备的复合乳液具有核壳结构,其热稳定性有所提高.     

WCS Coefficients in Orlicz Sequence Spaces

We introduce some practical calculation of the weakly convergent sequence coefficients of Orlicz sequence spaces equipped with Luxemburg norm and Orlicz norm. For the N-function (u) of which the index function is monotonuous, the exact value WCS(l⁽⁾) of Orlicz sequence space l⁽⁾ with Luxemburg norm is available, i.e. WCS(l⁽⁾) = or WCS(l) of l with Orlicz norm has the exact value or estimation

Reconstruction of Solid Electrolyte Interphase with SrI2 Reactivates Dead Li for Durable Anode-Free Li-Metal Batteries

Without excess Li, anode-free Li-metal batteries (AFLMBs) have been proposed as the most likely solution to realizing highly-safe and cost-effective Li-metal batteries. Nevertheless, short cyclic life puzzles conventional AFLMBs due to anodic dead Li accumulation with a local current concentration induced by irreversible electrolyte depletion, insufficient active Li reservoir and slow Li⁺ transfer at the solid electrolyte interphase (SEI). Herein, SrI₂ is introduced into carbon paper (CP) current collector to effectively suppress dead Li through synergistic mechanisms including reversible I⁻/I₃⁻ redox reaction to reactivate dead Li, dielectric SEI surface with SrF₂ and LiF to prevent electrolyte decomposition and highly ionic conductive (3.488 mS cm⁻¹) inner layer of SEI with abundant LiI to enable efficient Li⁺ transfer inside. With the SrI₂-modified current collector, the NCM532/CP cell delivers unprecedented cyclic performances with a capacity of 129.2 mAh g⁻¹ after 200 cycles.     

H2FCS单分子分解反应的直接动力学研究

采用量子化学QCISD(T)/6-311++G(d,p)//B3LYP/6-311+G(d,p)方法研究了H2FCS单分子分解反应的微观动力学性质, 构建了反应势能剖面. 利用经典过渡态理论(TST)与变分过渡态理论(CVT)并结合小曲率隧道效应模型(SCT), 分别计算了在200～3000 K温度范围内的速率常数kTST、kCVT和kCVT/SCT. 计算结果表明, H2FCS可经过不同的反应通道生成10种小分子产物, 脱H反应和HF消去反应为标题反应的主反应通道, 其中HF消去反应产物HCS可由两条反应通道生成. 在200~3000 K温度区间内得到三条反应通道的表观反应速率常数三参数表达式分别为 , 和 . 速率常数计算结果显示, 量子力学隧道效应在低温区间对反应速率常数的影响显著, 而变分效应在计算温度范围内可以忽略.     

A study on the complexity of a business cycle model with great excitements in non-resonant condition

Based on the researches of Szydlowski and Krawiec, we studied the inherent complexity of a chaotic business cycle with great excitements in non-resonant condition. First, we got the first-order and second-order approximate solutions of the system by using multiple scale method. Then deduced the formulation reflecting the complex relations between vibration, phase, bifurcation parameter μ and excite frequency Ω of first-order solution. As the great excitement F varied, the global changes of the system solutions were analyzed. We also explored the different paths leading the systems with different parameter combinations into catastrophe region, fuzzy region or chaos region. Finally, we discussed the evolution trends of business cycle models under the above-mentioned conditions. Hence, this paper has some theoretical and practical significance.     

混合驱动水下滑翔机水动力参数辨识

与传统水下滑翔机相比,混合驱动水下滑翔机可以分别利用头部的浮力驱动单元和机身尾部的螺旋桨推进单元进行驱动从而实现不同形式的运动,具备低功耗、长航程、良好机动性等特点,具有广泛的应用前景. 准确的动力学模型以及精确的水动力参数是实现混合驱动水下滑翔机控制系统设计以及精确导航的基础. 在混合驱动水下滑翔机动力学模型已知的前提下获得准确的水动力参数是本文主要研究的问题. 本文以天津大学研制的混合驱动水下滑翔机“海燕” 作为研究对象,提出一种在有限航行参数条件下,基于大数据统计分析的计算流体力学(computational fluid dynamics, CFD) 和参数辨识相结合来获取混合驱动水下滑翔机的水动力参数的方法. 即首先建立滑翔机的动力学模型,推导出稳态数据与所求水动力参数的关系;然后采用CFD 的方法得到其升力系数,根据大量稳态纯滑翔实验数据,结合大数据统计分析,辨识出其剩余水动力参数;最后,根据混合驱动模式下的实验数据辨识出与螺旋桨相关的参数,从而得到其整套的水动力参数. 该方法不仅结合了CFD 方法具有获取复杂外形结构航行水动力的特点,而且可以有效利用大量现场实验数据,因而能够更加准确地辨识其实际运动. 通过运动仿真与试验对比,验证了该辨识方法的正确性和有效性,对滑翔机的研究具有指导意义.      

In Situ Preparation of CsPbBr3@CsPb2Br5 Composite Assisted with Water as a Highly Efficient and Stable Catalyst for Photothermal CO2 Hydrogenation

Lead halide perovskite has triggered a lot of research due to its superior optical properties. However, halide perovskite materials have poor environmental stabilities and are easily affected by external factors such as water and heat, resulting in structural decomposition and performance failure. Contrary to this commonplace concept, it is found that CsPbBr₃ (CPB) can convert to CsPb₂Br₅ (CP2B5) partially when meeting a small amount of water, and the CsPbBr₃@CsPb₂Br₅ (CPB@CP2B5) composite is synthesized by an in situ method accordingly. The CPB@CP2B5 composite shows an enhanced catalytic performance compared with pure CPB, as well as a dramatically synergistic effect of photo and thermal for catalytic CO₂ hydrogenation. The CO production rate of CPB@CP2B5 is determined as 69 μmol g⁻¹ h⁻¹ under light irradiation at 200 °C, which is 156.8 and 43.4 times higher than that under pure photo (0.44 μmol g⁻¹ h ⁻¹) and pure thermal (1.59 μmol g⁻¹ h ⁻¹) condition, respectively. Meanwhile, the CPB@CP2B5 sample is also stable, which shows no significant decline in the catalytic activity during 8 cycles of repeated experiments. The probable mechanism is explored by utilizing a series of in situ characterizations.     

CHARACTERISTICS OF CLAY MINERALS IN ASIAN DUST AND THEIR ENVIRONMENTAL SIGNIFICANCE

The objectives of this research were to characterise the clay minerals composition of soil-derived dust in Northern China and to set up a mineralogical signature to trace their origin. Mineral composition of aerosol particles was investigated at Aksu, Dunhuang, Yulin, Tongliao and Changwu during an intensive field campaign period of ACE-Asia. The results show that the kaolinite （K） to chlorite （C） ratio is sensitive to the regional origin of Asian dust. Western source areas （represented by Aksu） displayed the lowest K/C ratio of 0.3 （average）, while it was found to increase up to 0.70 （average） upon moving towards northern source areas （represented by Yulin）. By studying transported dust in a deposition area representative of the Chinese Loess Plateau, the usefulness of the K/C ratio, when associated with back air-mass trajectories, was found to lie in revealing the origin of the dust. Comparison of the mineralogical data between Asian dust and Sahara dust, shows that the K/C ratio is also an effective signature to identify the source areas on a hemisphere scale.     

Moore机器的若干应用

本文利用Ｇ．Ｍ．Ｒｅｅｄ构造的Ｍｏｏｒｅ机器证明了：（１）Ｍｏｏｒｅ空间中的弱Ｌｉｎｄｅｌｏｆ住严格介于ＣＣＣ与ＤＣＣＣ之间．（２）强星可遮的Ｍｏｏｒｓ空间不必是星仿紧的．     

Significantly enhanced photocatalytic activity of TiO2/TiC coatings under visible light

Journal of Solid State Electrochemistry - Rutile TiO2 forms on TiC coatings (TiO2/TiC coatings) during carbon-embedding heat treatment (cHT) for TiC coatings. The photocatalytic activity of...