排序方式: 共有48条查询结果,搜索用时 31 毫秒
1.
通过将水合物的分解过程看作是无固态产物层生成的气固反应过程, 结合粒径缩小的收缩核反应模型和分形理论, 建立了多孔介质中水合物降压分解的分数维动力学模型, 提出了基于水合物分解实验数据计算多孔介质分形维数的方法. 分别利用前人的甲烷水合物和CO2水合物降压分解实验数据, 对上述分数维动力学模型进行了验证. 计算结果表明, 用提出的方法所计算得到的多孔介质分形维数与前人的测定结果基本符合; 对甲烷水合物和CO2水合物的降压分解过程, 提出的分数维动力学分解模型得出了和实验结果基本一致的预测, 绝对平均误差(AAD)小于10%. 相似文献
2.
Yuguo Li Ruiqin Peng Xianwu Xiu Xuelei Zheng Xiaosen Zhang Guannan Zhai 《Superlattices and Microstructures》2011,50(5):511-516
Tin oxide (SnO2) nanoparticles were fabricated by evaporation of Sn powers at 1000 °C in air pressure. The as-deposited SnO2 particles were single crystal structure, which were mostly spherical shape, the diameter of particles was ranging from 200 to 600 nm. The photoluminescence (PL) spectrum showed that a sharp emission peak at around 393 nm with the excitation wavelength at 325 nm, which suggested possible applications in nanoscaled optoelectronic devices. It was also found that the holding time affects the morphology of the products. The formation mechanism of SnO2 particles was discussed. 相似文献
3.
In this paper we investigate the global existence and energy decay rate for the solution of a coupled hyperbolic system. The semi-explicit energy decay rate is established by using piecewise multiplier techniques and weighted integral inequality. We extend the energy decay result in Alabau-Boussouira [F. Alabau-Boussouira, Convexity and weighted integral inequalities for energy decay rates of nonlinear dissipative hyperbolic systems, Appl. Math. Optim. 51 (2005) 61-105] for a single equation to the coupled hyperbolic system. 相似文献
4.
Non-Hermitian Weyl semimetals: Non-Hermitian skin effect and non-Bloch bulk-boundary correspondence
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We investigate novel features of three-dimensional non-Hermitian Weyl semimetals,paying special attention to the unconventional bulk-boundary correspondence.We use the non-Bloch Chern numbers as the tool to obtain the topological phase diagram,which is also confirmed by the energy spectra from our numerical results.It is shown that,in sharp contrast to Hermitian systems,the conventional(Bloch)bulk-boundary correspondence breaks down in non-Hermitian topological semimetals,which is caused by the non-Hermitian skin effect.We establish the non-Bloch bulk-boundary correspondence for non-Hermitian Weyl semimetals:the topological edge modes are determined by the non-Bloch Chern number of the bulk bands.Moreover,these topological edge modes can manifest as the unidirectional edge motion,and their signatures are consistent with the non-Bloch bulk-boundary correspondence.Our work establishes the non-Bloch bulk-boundary correspondence for non-Hermitian topological semimetals. 相似文献
5.
实验获得了激光照射红细胞悬液的荧光光谱,并分别监测不同荧光峰值波长处强度随时间的衰变过程,测试了其相应的荧光寿命。结果表明,在波长为407nm的激光照射下,红细胞悬液向外发射中心波长分别位于596,628,692nm的荧光光谱,各荧光峰对应衰变过程的平均荧光寿命分别为1.97,13.31,14.58ns。利用荧光强度和吸收率的加和性表示了混合物的总吸收率和总荧光发射强度,通过理论计算获得了红细胞悬液中锌卟啉、原卟啉和其他游离物参与荧光发射的相对含量和相对强度在不同荧光峰位的变化关系,进一步解释了不同峰位处荧光发射强度和平均荧光寿命的变化原因。 相似文献
6.
结合改进的基础度量理论(modified fundamental measure theory, MFMT)和密度泛函理论(Density functional theory, DFT), 研究了二缔合Lennard-Jones(LJ)流体在纳米缝隙中的相行为. 根据平衡时两相温度、化学势及巨势相等的原则, 计算了二缔合LJ流体在纳米缝隙中的相平衡. 阐明了缔合能量和缝隙宽度对平衡时分子和单体密度分布、吸附-脱吸等温线及汽液共存等热力学性质的影响. 相似文献
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8.
氢化物发生—电感耦合等离子体原子发射光谱法测定环境样品中痕量铅 总被引:4,自引:0,他引:4
提出了以重铬酸钾-铁氰经钾为氧化剂的铅氢化物发生氧化还原体系。采用连续氢化物发生器,对电感耦合等离子体原子发射光谱法,测定痕量铅的条件进行了研究。选定条件下,以02%硫氰酸钾-0.45草酸为干扰抑制剂,测得铅的检出限为0.09μg/L,相对标准偏差为0.49%。对环境标准物质进行分析,结果令人满意。 相似文献
9.
In this paper, we are concerned with the existence and uniqueness of the local solution to the generalized Riemann problem
for first order quasi-linear hyperbolic systems of conservation laws in the presence of the shock wave with large amplitude
and the centered wave. Apart from some exceptions, we prove the problem admits a unique piecewise smooth solution u=u(t,x), and this solution has a structure similar to the similarity solution u=u(x/t) of the corresponding Riemann problem in the neighborhood of the origin, provided that the coefficients of the system and
the initial conditions are sufficiently smooth. The application of our results in rich system is also given. 相似文献
10.
针对乙醇水溶液荧光发射的四个特征参量进行了研究,得出了该溶液发射荧光光子的时域和频域特征参量。发射光谱和激发光谱表明乙醇水溶液中含有三个结构不同的发光物质,其发射峰分别位于290 nm,305 nm和330 nm处,与其相对应的最佳吸收峰为265 nm,280 nm和236 nm。荧光强度随溶液中乙醇与水体积混合比的变化规律也证实了三种不同发光结构的存在。在荧光光谱峰值波长处分别监测其荧光强度随时间的衰变过程,将获得的荧光衰减动力学曲线采用指数方法拟合并进行解卷积处理,测试的荧光寿命分别对应8 ns,12 ns,25 ns。结合乙醇水溶液荧光发射的四个特征参量可以看出:乙醇分子和水分子发生团簇作用形成了三个新的分子结构从而可发射具有不同能量的荧光光子。该研究结果能为乙醇水分子的团簇结构研究提供参考。 相似文献