Highly Enantioselective Phenylacetylene Addition to Benzaldehyde Catalyzed by Chiral Tridentate Ligand

Development of new or improved methods for the asymmetric preparation of chiral propargylic alcohols has gained considerable significance during the past years because they are useful building blocks for the synthesis of many biologically active compounds and natural products.[1] A series of chiral tridentate ligands were conveniently synthesized from amino acids with good yields (Scheme 1).[2] A preliminary study of the enantioselective alkynylation of benzaldehyde catalyzed by this chiral tridentate ligand was carried out and up to 83% ee of chiral propargyl alcohols was obtained (Table 1 ). A further investigation of the tridentate ligand is currently underway.     

纳米金标记抗体增强SPR检测大肠杆菌O157∶H7

将金纳米粒子(AuNPs)标记的大肠杆菌O157∶H7(E.coli O157∶H7)的多克隆抗体(PAb)作为二抗,采用氨基偶联法将PAb固定在传感器表面作为一抗,通过三明治方法用双通道表面等离子体子共振(SPR)传感器对E.coli O157∶H7进行检测,并与SPR直接法检测进行了比较.结果表明,直接法的检出限为103cfu/mL,线性范围为103～109cfu/mL;AuNPs增强三明治法的检出限为10 cfu/mL,线性范围为10～1010cfu/mL,灵敏度比直接法提高了100倍,且具有更宽的检测范围.本方法不仅检测时间短,而且具有良好的选择性和重现性.     

自组装和共缩聚法制备磺酸基修饰的硅柱磷酸锆

以十六胺插层磷酸锆为原料, 利用十二烷基二甲基苄基氯化铵为导向模板剂, 通过正硅酸乙酯和巯丙基三甲氧基硅烷的层间共水解缩聚, 并结合双氧水对巯丙基的熏蒸氧化, 制备了磺酸基修饰的硅柱磷酸锆材料。通过XRD、SEM、N2吸附-脱附和FT-IR等方法对柱撑材料进行了结构表征。结果表明, 通过调变预撑剂和模板剂中的碳链长度可以优化材料的柱撑结构和孔结构, 磺酸基修饰的材料孔径分布在2.17 nm左右, 比表面积可达163 m²·g^-1, 且保留有规整有序的柱撑磷酸锆层板结构。磺酸基的修饰则成功调变了材料的酸位性质, Brönsted酸量最高可达2.71 mmol·g^-1, 总酸量可达5.20 mmol·g^-1。利用柠檬酸与正丁醇的酯化反应为探针反应, 由于磺酸基修饰的硅柱磷酸锆材料具有独特的空间反应效应和较为丰富的Brönsted酸位, 酯化反应转化率最高可达95.74%。     

酰基吡唑啉酮缩邻苯二胺希土配合物的合成、表征及生物活性

酰基吡唑啉酮缩二胺是近年开发的双席夫碱试剂,对希土离子具有较高的萃取性能,并表现出一定的抗菌、抗病毒生物活性。由于这类试剂含有活性的羟基和亚胺基官能团,适于同各种金属离子配位。最近我们研究了酰基吡唑啉酮缩乙二胺配合物,发现它们具有一定的传递电子作用、光致发光作用和较强的抗菌生物活性。但缩芳香二胺双席夫碱配合物的研究较少,为进一步拓宽酰基吡唑啉酮类配合物的研究领域,本文合成了11种未见报道的希土元素与N,N'-双[1－苯基－3－甲基－5－氧－4－吡唑啉基）α-呋喃次甲基]邻苯二亚胺（（HPMαFP）2Pen)的配合物。研究了配合物的结构,一般性质和抗菌活性。     

长寿命高镍无钴锂离子正极材料的制备

通过调整不同配锂量、不同焙烧温度以及包覆改性对高镍无钴二元材料性能的影响因素进行了研究。对不同原样和其改性后的材料进行了X射线粉末衍射(XRD)分析和首次充放电性能和倍率性能、循环性能等电化学性能测试。其中过锂量(质量分数)为5%,焙烧温度为820℃的材料性能优异,其首次放电比容量为171.6 mAh·g^-1,1C和3C的放电比容量分别为147.8、129.8 mAh·g^-1。对材料进行锰化合物(质量分数1.0%)包覆处理后,材料的残碱量下降明显,加工性能优异,倍率性能得到明显改善,1C和3C的放电比容量分别提升为156.5、141.8 mAh·g^-1。2Ah软包电池常温循环830周容量保持率为80%,高温循环345周容量保持率为80%。     

The unique carrier mobility of Janus MoSSe/GaN heterostructures

Heterostructure is an effective approach in modulating the physical and chemical behavior of materials. Here, the first-principles calculations were carried out to explore the structural, electronic, and carrier mobility properties of Janus MoSSe/GaN heterostructures. This heterostructure exhibits a superior high carrier mobility of 281.28 cm²·V⁻¹·s⁻¹ for electron carrier and 3951.2 cm²·V⁻¹·s⁻¹ for hole carrier. Particularly, the magnitude of the carrier mobility can be further tuned by Janus structure and stacking modes of the heterostructure. It is revealed that the equivalent mass and elastic moduli strongly affect the carrier mobility of the heterostructure, while the deformation potential contributes to the different carrier mobility for electron and hole of the heterostructure. These results suggest that the Janus MoSSe/GaN heterostructures have many potential applications for the unique carrier mobility.     

Synthesis and primary biological evaluation of 188ReN-NEMPTDD

The recovery of uranium(VI) from chloride solution using a liquid emulsion membrane (LEM) technique was studied. The emulsion is constituted by the quaternary salt of benzyloctadecyldimethyl ammonium chloride (BODMAC, R₄NCl) as a carrier, kerosene as organic diluent, Span 80 as emulsifying agent and 0.5 mol/l Na₂CO₃ as stripping phase. The important variables affecting the LEM permeation process such as the concentrations of extractant, internal strip phase, types of organic diluent, and the presence of magnesium chloride or magnesium sulfate were investigated. It was found that, at a given condition, the maximum extraction rate of uranium(VI) reached 80%. The emulsion was stable at low pH in the presence of certain amounts of electrolytes such as NaCl and MgCl₂.     

Rossby solitary waves excited by the unstable topography in weak shear flow

A new forced KdV equation including topography is derived and the numerical solutions are given. The topographic variable should be related with the temporal and spatial function, which is called unstable topography. The physical features of the solitary waves about the mass and energy are discussed by theoretical analysis. In further studies, the pseudo-spectral numerical methods are used to discuss the evolution of solitary wave generated by the topography when meridional wave number \(m=1\); in a similar way, we analyze the solitary wave when meridional wave number \(m=2\). At last, we make the comparison for the characteristics of waves between \(m=1\) and \(m=2\), the wave of meridional number \(m=1\) plays a leading role.     

Excess electrons in reduced rutile and anatase TiO2

As a prototypical photocatalyst, TiO₂ is a material of scientific and technological interest. In photocatalysis and other applications, TiO₂ is often reduced, behaving as an n-type semiconductor with unique physico-chemical properties. In this review, we summarize recent advances in the understanding of the fundamental properties and applications of excess electrons in reduced, undoped TiO₂. We discuss the characteristics of excess electrons in the bulk and at the surface of rutile and anatase TiO₂ focusing on their localization, spatial distribution, energy levels, and dynamical properties. We examine specific features of the electronic states for photoexcited TiO₂, for intrinsic oxygen vacancy and Ti interstitial defects, and for surface hydroxyls. We discuss similarities and differences in the behaviors of excess electrons in the rutile and anatase phases. Finally, we consider the effect of excess electrons on the reactivity, focusing on the interaction between excess electrons and adsorbates.