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1.
Chemical modification of natural rubber (NR) has frequently been attempted to improve the performance in specific application.
30% poly (methyl metacrylate) grafted NR (MG 30) has been explored as a potential candidate for polymer electrolytes. The
complexation effect of LiCF3SO3, ethylene carbonate (EC) and Al2SiO5 in polymer host electrolytes has been investigated using FTIR ICP-OES spectrometry. Thermal studies of the systems have displayed
a stable trend of glass temperature transition at elevated salt concentration whereas incorporation of EC and filler into
the system results in the same pattern in their Tg values.
Paper presented at the International Conference on Functional Materials and Devices 2005, Kuala Lumpur, Malaysia, June 6 –
8, 2005. 相似文献
2.
Olive oil (OO) and its phenolic compounds are reported to possess many potential biological effects, which are ascribed to its powerful antioxidant property. In this study, we have assessed whether OO and its phenolic compound tyrosol (TY) could mitigate 2,3,7,8-tetrachlorodibenzo-p-dioxin (TCDD) induced oxidative damages in peripheral blood mononuclear cells (PBMC). The results showed that exposure of PBMC to 10 nM TCDD caused significant cell death and elevated cellular concentrations of reactive oxygen species and lipid peroxidation. Comet assay indicated that OO and TY protected DNA damage against dioxin toxicity. In addition, alterations in levels of antioxidant enzymes were substantially prevented by OO and TY. TCDD-induced CYP1A1 activity and loss of mitochondrial membrane potential were significantly reduced by the administration of OO and TY. The results suggested that dietary modifications incorporating diets rich in OO and associated phenolics could prove beneficial in protecting individuals against toxicity induced by dioxins. 相似文献
3.
Koteeswari R Ashokkumar P Malar EJ Ramakrishnan VT Ramamurthy P 《Chemical communications (Cambridge, England)》2011,47(27):7695-7697
Amidothiourea linked acridinedione derivatives selectively detect Hg(2+) in unbuffered aqueous solution under broad pH range with both single- and two-photon excitation. The observed linear fluorescence intensity change allows the quantitative detection of Hg(2+) in the concentration range of 22 nM-0.33 μM with the lower detection limit of 2 nM. 相似文献
4.
R. Kumaran T. Varalakshmi E. J. Padma Malar P. Ramamurthy 《Journal of fluorescence》2010,20(5):993-1002
Photophysical studies of photoinduced electron transfer (PET) and non-PET based acridinedione dyes with guanidine hydrochloride
(GuHCl) were carried out in water and methanol. Addition of GuHCl to photoinduced electron transfer (PET) based acridinedione
dye (ADR 1) results in a fluorescence enhancement, whereas a non-PET based dye (ADR 2) shows no significant change in the
fluorescence intensity and lifetime. Addition of GuHCl to ADR 1 dye in methanol results in single exponential decay behaviour,
on the contrary a biexponential decay pattern was observed on the addition of GuHCl in water. Absorption and emission spectral
studies of ADR 1 dye interaction with GuHCl reveals that the dye molecule is not in the protonated form in aqueous GuHCl solution,
and the dye is confined to two distinguishable microenvironment in the aqueous phase. A large variation in the microenvironment
around the dye molecule is created on the addition of GuHCl and this was ascertained by time-resolved area normalized emission
spectroscopy (TRANES) and time-resolved emission spectroscopy (TRES). The dye molecule prefers to reside in the hydrophobic
microenvironment, rather in the hydrophilic aqueous phase is well emphasized by time-resolved fluorescence lifetime studies.
The mechanism of fluorescence enhancement of ADR 1 dye by GuHCl is attributed to the suppression of the PET process occuring
through space. 相似文献
5.
Anthonysamy A Balasubramanian S Shanmugaiah V Mathivanan N 《Dalton transactions (Cambridge, England : 2003)》2008,(16):2136-2143
The synthesis and characterization of Ru(II) terpyridine complexes derived from 4'-functionalized 2,2':6',2'-terpyridine ligands by a multi step procedure have been described. The complexes are redox-active, showing both metal-centred (oxidation) and ligand-centred (reduction) processes. The antibacterial and antifungal activity of the synthesized ruthenium(II) complexes [Ru(attpy)2](PF6)2 (attpy = 4'-(4-acryloyloxymethylphenyl)-2,2':6',2'-terpyridine); [Ru(mttpy)2](PF6)2 (mttpy = 4'-(4-methacryloyloxymethylphenyl)-2,2':6',2'- terpyridine); [Ru(mttpy)(MeOPhttpy)](PF6)2 (MeOPhttpy = 4'-(4-methoxyphenyl)-2,2':6',2'-terpyridine); and [Ru(mttpy)(ttpy)](PF6)2 (ttpy = 4'-(4-methylphenyl)-2,2':6',2'-terpyridine) were tested against four human pathogens (Proteus vulgaris, Proteus mirabilis, Pseudomonas aeruginosa and Escherichia coli) and five plant pathogens (Curvularia lunata, Fusarium oxysporum, Fusarium udum, Macrophomina phaseolina and Rhizoctonia solani) by the well diffusion method and MIC values of the complexes are reported. A biological study of the complexes indicated that the complexes [Ru(mttpy)2](PF6)2 and [Ru(mttpy)(MeOPhttpy)](PF6)2 exhibit very good activity against most of the test pathogens and their activity is better than those of some of the commercially available antibiotics like tetracycline and the fungicide carbendazim. 相似文献
6.
FTIR studies of PVC/PMMA blend based polymer electrolytes 总被引:1,自引:0,他引:1
Ramesh S Leen KH Kumutha K Arof AK 《Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy》2007,66(4-5):1237-1242
The polymer electrolytes composing of the blend of polyvinyl chloride-polymethyl methacrylate (PVC/PMMA) with lithium triflate (LiCF3SO3) as salt, ethylene carbonate (EC) and dibutyl phthalate (DBP) as plasticizers and silica (SiO2) as the composite filler were prepared. FTIR studies confirm the complexation between PVC/PMMA blends. The CCl stretching mode at 834 cm-1 for pure PVC is shifted to 847 cm-1 in PVC-PMMA-LiCF3SO3 system. This suggests that there is interaction between Cl in PVC with Li+ ion from LiCF3SO3. The band due to OCH3 at 1150 cm-1 for PVC-PMMA blend is shifted to 1168 cm-1 in PVC-PMMA-LiCF3SO3 system. This shift is expected to be due to the interaction between Li+ ion and the oxygen atom in PMMA. The symmetric vibration band and the asymmetric vibration band of LiCF3SO3 at 1033 and 1256 cm-1 shifted to 1075 and 1286 cm-1 in the DBP-EC plasticized PVC-PMMA-LiCF3SO3 complexes. The interaction between Li+ ions and SiO2 will lead to an increase in the number of free plasticizers (which does not interact with Li+ ions). When the silica content increases from 2% to 5%, the intensity of the peak at 896 cm-1 (due to the ring breathing vibration of free EC) increases in PVC-PMMA-LiCF3SO3-DBP-EC system. 相似文献
7.
Muthian Shanmugasundaram Srinivasarao Arulananda Babu Raghavachary Raghunathan Ezekiel J. Padma Malar 《Heteroatom Chemistry》1999,10(4):331-336
Synthesis of a series of novel 1,3‐diphe nyl‐4‐arylspiropyrazolines[5.21]‐11‐tetralones has been accomplished in good yield by regioselective 1,3‐dipolar cycloaddition of diphenylnitrilimine with (E)‐2‐arylidene‐1‐tetralones. X‐ray crystal structure analysis of one of the products 4b confirms the structure and the regiochemistry of cycloaddition. © 1999 John Wiley & Sons, Inc. Heteroatom Chem 10: 331–336, 1999 相似文献
8.
Torres DA Azagarsamy MA Thayumanavan S 《Journal of the American Chemical Society》2012,134(17):7235-7237
We report a new approach for the rapid screening of analyte binding affinities for a target protein. We demonstrate that a molecular probe, with a pro-fluorophore substrate and ligand moieties, can be hindered from enzymatic access when bound to the target protein. When analytes displace the probe from the protein's binding pocket, a fluorescence profile is generated. This profile is used to discriminate analytes based on their relative binding affinities. 相似文献
9.
N Selvakumar B.Yadi ReddyA.Malar Azhagan Manoj Kumar KheraJ.Moses Babu Javed Iqbal 《Tetrahedron letters》2003,44(37):7065-7069
A short and efficient route to 1-methoxyindoles via a novel rearrangement is disclosed. This route involves only three steps from commercially available nitro compounds. The methodology is also generalized with a variety of examples to afford a series of 2-substituted-1-methoxyindoles possessing an electron-withdrawing group at position 3. In addition, a 1-methoxyindole compound 10 was converted to the corresponding indole 11 under mild conditions thereby constituting a new synthesis of substituted indoles. 相似文献
10.
N. Selvakumar Manoj Kumar KheraB.Yadi Reddy D. SrinivasA.Malar Azhagan Javed Iqbal 《Tetrahedron letters》2003,44(37):7071-7074
A direct synthesis of naturally occurring 9-methoxycarbazole-3-carbaldehyde 1, based on our methodology for the synthesis of 1-methoxyindoles, is reported. A novel benzannulation strategy was employed using ring closing metathesis as the key step in this total synthesis. The synthesis of the natural product 1 has been achieved in seven steps in 14% overall yield from commercial materials and in only four steps from a methoxyindole compound obtained using the new methodology. 相似文献