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The consecutive reactions of (CH3)2Si(OC2H5)2 and CH3Si(OC2H5)3 with methoxide ions were investigated in methanol solutions. The reverse transesterification reactions with ethoxide ions could be neglected in both cases since the concentration of ethoxide in methanol solution was assumed to be low due to the fast equilibrium reaction C2H5O? + CH3OH ? C2H5OH + CH3O?. The progress of the reactions was followed by monitoring the formation of ethanol with a Fourier-transform infrared spectrometer. All rate constants were determined at 295 K. The reactions between the dialkoxydimethylsilanes and methoxide ions were assumed to consist of two consecutive steps that can be represented by the net reaction; (CH3)2Si(OC2H5)2 + 2CH3O? → (CH3)2Si(OCH3)2 + 2C2H5O?. The two consecutive rate constants were established as 1.93 ± 0.12M?1s?1 and 1.00 ± 0.12M?1s?1, respectively. The consecutive rate constants for the reactions between the trialkoxymethylsilanes and methoxide ions can be written according to the total reaction; CH3Si(OC2H5)3 + 3CH3O? → CH3Si(OCH3)3 + 3C2H5O?. The three rate constants corresponding to each consecutive step were established as 1.12 ± 0.09 M?1s?1, 0.82 ± 0.10 M?1s?1, and 0.51 ± 0.06 M?1s?1, respectively. © 1995 John Wiley & Sons, Inc. 相似文献
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K. -J. Berg A. Berger H. Hofmeister 《Zeitschrift für Physik D Atoms, Molecules and Clusters》1991,20(1):309-311
Small spherical silver particles in a surface layer of commercial flat glass were produced by means of sodium-silver ion exchange. In each volume element of the layer there is a Gaussian distribution of the particle diameters. The mean diameter increases with penetration depth. Within one individual sample it can vary from 4.5 nm immediately at the glass surface up to more than 50 nm at the end of the layer. Due to a special preparation technique the results were gained by microspectrophotometric measurements as well as by investigations carried out with the transmission electron microscope and the electron-probe microanalyzer on one and the same sample always as function of the penetration depth. 相似文献
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Ulf Pindur Ludwig Pfeuffer Manfred Eitel Martina Rogge Manfred Haber 《Monatshefte für Chemie / Chemical Monthly》1991,122(4):291-298
Summary Diels-Alder reactions of 2- and 3-vinylindoles with aryne, 1,4-benzo- and 1,4-naphtho-quinone lead to new six-ring annellated carbazoles. Molecular modeling studies predict that the compounds with coplanar framework are able to intercalate with the B-DNA. 相似文献
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Massively parallel computational paradigms can mitigate many issues associated with the analysis of large and complex remotely sensed data sets. Recently, the Beowulf cluster has emerged as the most attractive, massively parallel architecture due to its low cost and high performance. Whereas most Beowulf designs have emphasized numerical modeling applications, the Parallel Image Processing Environment (PIPE) specifically addresses the unique requirements of remote sensing applications. Automated, parallelization of user-defined analyses is fully supported. A neural network application, applied to Along Track Scanning Radiometer-2 (ATSR-2) data shows the advantages and performance characteristics of PIPE. 相似文献
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Mesophase behaviour of 2,5-dibenzoyloxy-p-benzoquinone derivatives and tetrahydrobenzene tetraesters
Sibylle Berg Volker Krone Helmut Ringsdorf Udo Quotschalla Helmut Paulus 《Liquid crystals》1991,9(2):151-163
The synthesis of 2,5-dibenzoyloxy-p-benzoquinone derivatives, their products after reduction and tetraesters from tetrahydroxybenzene prepared from those products is described. Their phase behaviour was investigated by differential scanning calorimetry and polarizing microscopy and is discussed in terms of their detailed structure. 相似文献