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1.
A. V. Ivanov M. Yu. Tsentalovich E. G. Kogan L. G. Tomilova N. S. Zefirov 《Russian Chemical Bulletin》2008,57(8):1676-1679
The chlorination of benzene, toluene, and o-xylene with molecular chlorine in the presence of the phthalocyanine complexes of different structures was studied. The transformations
of the catalysts during the reaction were investigated.
Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 8, pp. 1644–1647, August, 2008. 相似文献
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I. A. Belogorokhov M. N. Martyshov E. V. Tikhonov M. O. Breusova V. E. Pushkarev P. A. Forsh A. V. Zoteev L. G. Tomilova D. R. Khokhlov 《JETP Letters》2007,85(12):655-657
The Raman spectra have been obtained and the temperature dependence of the conductivity of organic semiconductor structures based on butyl-substituted erbium monophthalocyanine and erbium triphthalocyanine has been studied. It has been found experimentally that the activation energy decreases dramatically and the Raman spectra exhibits four new peaks in the region of large Raman shifts as the molecular structure of the samples becomes more complicated. 相似文献
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Using electron spectroscopy, X-ray photoelectron spectroscopy, and ESR spectroscopy, the blue forms of bisphthalocyanines of rare-earth elements were found to have structures of sandwich-type complexes with isoelectronic phthalocyanine ligands linked with tetravalent metal ions, [Pc2–Ln4+Pc2–]0. A comparative spectral and electrochemical study of the blue and green forms oftert-butyl-substituted bisphthalocyanines was carried out for almost the whole series of rare-earth metals. Lutetium octa(perfluoro-tert-butyl)- and perchlorobisphthalocyanines were synthesized for the first time.Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 3, pp. 425–430, March, 1995.This study was financially supported by the Russian Foundation for Basic Research (grant No. 94-03-08903). 相似文献
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A. V. Ivanov P. A. Svinareva I. V. Zhukov L. G. Tomilova N. S. Zefirov 《Russian Chemical Bulletin》2006,55(2):281-286
A series of the earlier unknown diphthalocyanine complexes of rare-earth metals based on 4,5-isopropylidenedioxyphthalonitrile
were prepared. Their compositions and yields depend on the radius of the complexing ion. The synthesized compounds were studied
by spectroscopy and electrochemical methods. The redox potentials of the complexes studied change nonlinearly with a decrease
in the lanthanide ion radius.
Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 2, pp. 274—279, February, 2006. 相似文献
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New alkyl-substituted phosphorus phthalocyanines and triazatetrabenzocorroles were synthesized. The structures of these complexes
were confirmed by 1H, 13C, and 31P NMR spectroscopy, mass spectrometry, and electronic absorption spectroscopy.
Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 7, pp. 1403–1407, July, 2007. 相似文献
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T. V. Magdesieva I. V. Zhukov L. G. Tomilova E. V. Chernykh K. P. Butin 《Russian Chemical Bulletin》1997,46(12):2036-2043
The electrochemical potentials of seven redox transitions for green forms and eight redox transitions for blue forms of neutral
octa-tert-butylsubstituted diphthalocyanine cornplexes of lanthanides Pct
2Ln (Ln=Pr, Sm, Dy, and Lu) in solutions were measured by cyclic voltammetry and rotating disc electrode techniques. The spectroelectrochemical
investigation of the products of two-electron oxidation and reduction of the green form of Pct
2Lu was performed. The frontier molecular orbitals, total charge densities, total spin densities, electrostatic potentials,
and heats of ion formation for (Pc2Y)
m+,n−
(m=0, 1, 2 and 3;n=1, 2, 3 and 4), which can model the products of the redox transitions of the diphthalocyanines under study, were calculated
using the semiempirical ZINDO/1 method. The calculations for (Pc2Y)
m+,n−
and absorption spectra show that the electron changes in all redox transitions of the green forms of Pct
2Ln are mainly localized on the ligands.
Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya No. 12, pp. 2149–2156, December, 1997. 相似文献
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Nanoaggregation of the thermally stable bis(2-hydroxy-9(10),16(17),23(24)-tri-tert-butylphthalocyanine) of J-type was observed by the field emission scanning electron microscopy (FE-SEM). Ordered phases, represented as threads composed of about 200 nm diameter circles were discovered, unlike the parent dimeric magnesium complex, in which similar circles combine together to give visually distinguishable zones with widths of about 600 nm and the same distance between them. 相似文献