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M. Gopalakrishnan P. Sureshkumar V. Kanagarajan J. Thanusu Shanmugam Govindan Mahesh Reddy Ghanta 《合成通讯》2013,43(13):1923-1926
The p‐toluenesulphonic acid–catalyzed reaction between appropriate cresols and N‐methyl‐3‐phenyl‐3‐hydroxypropylamine in refluxing toluene resulted in the formation of o‐substituted phenol derivatives by an aromatic nucleophilic substitution reaction. 相似文献
2.
A series of novel ethyl 7,9-diaryl-1,4-diazaspiro[4.5]dec-9-ene-6-carboxylates was synthesized by the reaction of ethyl 4,6-diaryl-2-oxocyclohex-3-ene-1-carboxylates
with ethylenediamine in the presence of p-toluenesulfonic acid without a solvent under focused microwave irradiation. The
title compounds were screened for their antimicrobial activities against a spectrum of clinically isolated microorganisms. 相似文献
3.
M. Gopalakrishnan P. Sureshkumar V. Kanagarajan J. Thanusu 《Research on Chemical Intermediates》2007,33(6):541-548
Condensation of structurally diverse aldehydes including heterocyclic aldehydes, like furfural, with various amines in the
presence of calcium oxide affording the corresponding imines in solvent-free conditions in good to excellent yields under
microwave irradiation is described. A comparative study has been done under thermal conditions. The synergy between dry media
and microwave irradiation in this reaction is evaluated by condensing less electrophilic aldehydes with poorly nucleophilic
amines. The main advantages of this environmentally friendly protocol are the use of the non-toxic and inexpensive reagent
calcium oxide and the considerable rate enhancement in comparison with a thermal reaction. 相似文献
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V. Kanagarajan J. Thanusu M. R. Ezhilarasi M. Gopalakrishnan 《Chemistry of Heterocyclic Compounds》2011,47(1):60-66
A novel approach towards the synthesis of spiropiperidinyl 1,2,4-triazolidine-3-thiones was proposed, exploiting microwave
activation coupled with solvent-free reaction conditions. In search for new leads towards potent antimicrobial agents, we
tested all the synthesized compounds for their in vitro antibacterial activity against Bacillus subtilis and Micrococcus luteus
and antifungal activity against Aspergillus niger, Candida albicans, Candida-6, and Candida-51. Two of the compounds exerted
strong in vitro antibacterial activity against B. subtilis and M. luteus, and all the synthesized compounds were potent against
the tested fungal strains. 相似文献
6.
J. Thanusu V. Kanagarajan M. Gopalakrishnan 《Research on Chemical Intermediates》2010,36(9):1073-1084
Abstract
A series of bis heterocycles comprising both piperidine and thiohydantoin nuclei namely 3-(3-alkyl-2,6-diarylpiperin-4-ylidene)-2-thioxoimidazolidin-4-ones is synthesized and characterized by melting point, elemental analysis, MS, FT–IR, one-dimensional NMR (1H, D2O exchanged 1H and 13C), two-dimensional HOMOCOSY, and NOESY spectroscopic data. 相似文献7.
A novel class of 4,6-diaryl-4,5-dihydro-2H-indazol-3-ols and 4,6-diaryl-2-phenyl-4,5-dihydro-2H-indazol-3-ols is synthesized
and characterized by melting point, elemental analysis, MS, FT-IR, 1H and 13C NMR, D2O exchanged 1H NMR, and two-dimensional HSQC spectra.
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Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 8, pp. 1183–1188, August, 2008. 相似文献
8.
Kanagarajan V. Sureshkumar P. Thanusu J. Gopalakrishnan M. 《Russian Journal of Organic Chemistry》2009,45(11):1707-1713
One-pot condensation of thiourea (urea), diverse aromatic aldehydes, and ammonium acetate in the presence of repeatedly usable
heterogeneous catalyst NaHSO4-SiO2 in the absence of solvent under the microwave irradiation proceeds faster and with better yields of 6-aryl-1,2,4,5-tetrazinane-3-thiones(ones)
that under common heating. Compounds synthesized exist as a rule as two isomers distinguished by the position of the phenyl
ring: It is located in the major isomer nearly in the equatorial position, in the minor one, close to axial position. 相似文献
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