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排序方式: 共有1809条查询结果,搜索用时 11 毫秒
1.
João Marcos G. Barbosa Milenna K. Fernandes Rodrigues Lurian C. David Taynara C. e Silva Danielly A. Fortuna Lima Naiara Z. Pereira Emmanuel B. D'Alessandro Anselmo E. de Oliveira Paulo H. Jorge da Cunha Maria Clorinda S. Fioravanti Nelson R. Antoniosi Filho 《Biomedical chromatography : BMC》2020,34(11):e4935
An innovative volatolomic approach employs the detection of biomarkers present in cerumen (earwax) to identify cattle intoxication by Stryphnodendron rotundifolium Mart., Fabaceae (popularly known as barbatimão). S. rotundifolium is a poisonous plant with the toxic compound undefined and widely distributed throughout the Brazilian territory. Cerumen samples from cattle of two local Brazilian breeds (‘Curraleiro Pé-Duro’ and ‘Pantaneiro’) were collected during an experimental intoxication protocol and analyzed using headspace (HS)/GC–MS followed by multivariate analysis (genetic algorithm for a partial least squares, cluster analysis, and classification and regression trees). A total of 106 volatile organic metabolites were identified in the cerumen samples of bovines. The intoxication by S. rotundifolium influenced the cerumen volatolomic profile of the bovines throughout the intoxication protocol. In this way, it was possible to detect biomarkers for cattle intoxication. Among the biomarkers, 2-octyldecanol and 9-tetradecen-1-ol were able to discriminate all samples between intoxicated and nonintoxicated bovines. The cattle intoxication diagnosis by S. rotundifolium was accomplished by applying the cerumen analysis using HS/GC–MS, in an easy, accurate, and noninvasive way. Thus, the proposed bioanalytical chromatography protocol is a useful tool in veterinary applications to determine this kind of intoxication. 相似文献
2.
C. M. Silva R. S. Amaral A. Amaral J. A. Santos Júnior D. C. Santos L. E. Lima S. V. Silveira 《Journal of Radioanalytical and Nuclear Chemistry》2006,270(1):237-241
Summary Studies performed by the Brazilian Nuclear Corporation (NUCLEBRAS), in collaboration with the Geological Survey Company of
Brazil (CPRM), identified high levels of natural uranium in the districts of Pedra and Venturosa, in the rural region of the
state of Pernambuco (PE) - Brazil, where the maximum value found in rocks was 22,000 mg. 相似文献
3.
Ricardo Amorim 《Zeitschrift fur Physik C Particles and Fields》1995,67(4):695-700
We study the Hamiltonian path integral formulation for generic systems with first class and linear second class constraints.ift01001@ufrj 相似文献
4.
The fully frustrated planar rotator and fully frustrated XY models in two dimensions have two phase transitions: one of the Berezinskii–Kosterlitz–Thouless type and other in the Ising universality class. We use Monte Carlo simulation to study both models. We fix our attention in the Ising-like transition, which we show can be understood as a percolation transition. We obtain the critical temperature as well as the critical exponents of the mean cluster size, γ, and Fisher's exponent τ. The critical temperature agree very well with other calculations. We found that the critical exponents are smaller than in the pure two-dimensional percolation case. We interpret this as due to the long-range interaction between vortex and antivortex. 相似文献
5.
Emerson T da SilvaEdson L.S Lima 《Tetrahedron letters》2003,44(18):3621-3624
The ability of 1,3-dimethyl-5-acetyl-barbituric acid (DAB) to react with primary amines in a chemoselective fashion was applied to the synthesis of a selectively protected spermidine. 相似文献
6.
In this work we show that the energy associated to the linear three-dimensional magneto-elastic system decays polynomially to zero as time goes to infinity, provided the initial data is smooth enough. 相似文献
7.
A new class of expanding cosmological solutions is derived. The matter content of these models is a mixture of two interacting simple fluids: the first one, homogeneous and isotropic with equation of statep = (-1), the dynamics of which is given by the FRW equation and the second one an inhomogenous dust. The limiting case of two dusts corresponds to the Szekeres' universes of class II. A large subclass of the models evolve to a FRW phase for all physically meaningful values of the polytropic index and the curvature parameterk. A gauge condition, under which the metric is invariant, is shown to exist for k0. In particular, it explains why the parabolic model is a peculiar solution in the class found by Szekeres.On leave from Departamento de Fisica Teórica e Experimental Universidade Federal do Rio Grande do Norte, Natal, RN, Brazil. 相似文献
8.
L. Gomes de Lima M. Cariou H. Scordia R. Kergoat M. M. Kubicki J. E. Guerchais 《Journal of organometallic chemistry》1985,290(3):321-327
A new class of cyclic telluronium salts has been prepared. All the salts are stable in solution in CHCl3 or dimethylsulphoxide (DMSO). Conductivity measurements in DMSO and dimethylformamide (DMF) have shown that considerable ion pairing occurs in solution. Infrared, 1H, 13C, 125Te NMR, and mass spectra are reported and discussed. 相似文献
9.
D. S. Gouveia R. Rosenhaim M. A. M. A. de Maurera S. J. G. Lima C. A. Paskocimas E. Longo A. G. Souza I. M. G. Santos 《Journal of Thermal Analysis and Calorimetry》2004,75(2):453-460
With the aim of obtaining materials with applications in pigments, CoxZn7-xSb2O12 spinels were synthesized using the Pechini method. This method consists in the formation of a polymeric net, where the metallic
cations are homogeneously distributed. In this work, two types of alcohol (ethyl glycol and ethylene glycol) were used for
the synthesis of a zinc antimoniate spinel, CoxZn7-xSb2O12 (x=0-7). The materials were characterized by termogravimetry (TG) and differential thermal analysis (DTA). TG results indicated
a decrease in total mass loss when cobalt was added to the solution substituting zinc, for samples prepared using the two
different alcohols. Decomposition temperatures, obtained by TG and DTA, presented a decreasing behavior as cobalt was added
to the material. In relation to the alcohols, all results indicated a better polymerization of the resin when ethylene glycol
was used, being the most indicated one for cation immobilization. X-ray diffraction did not show differences between the two
alcohols - both presented the spinel phase (Co, Zn)2.33Sb0.67O4. Samples with higher quantity of cobalt also presented ilmenite phase (Co, Zn)Sb2O6.
This revised version was published online in August 2006 with corrections to the Cover Date. 相似文献
10.