全文获取类型
收费全文 | 13386篇 |
免费 | 2234篇 |
国内免费 | 1453篇 |
专业分类
化学 | 9233篇 |
晶体学 | 123篇 |
力学 | 888篇 |
综合类 | 90篇 |
数学 | 1643篇 |
物理学 | 5096篇 |
出版年
2024年 | 48篇 |
2023年 | 287篇 |
2022年 | 487篇 |
2021年 | 524篇 |
2020年 | 545篇 |
2019年 | 482篇 |
2018年 | 469篇 |
2017年 | 409篇 |
2016年 | 589篇 |
2015年 | 643篇 |
2014年 | 744篇 |
2013年 | 989篇 |
2012年 | 1137篇 |
2011年 | 1154篇 |
2010年 | 800篇 |
2009年 | 738篇 |
2008年 | 827篇 |
2007年 | 770篇 |
2006年 | 693篇 |
2005年 | 568篇 |
2004年 | 422篇 |
2003年 | 351篇 |
2002年 | 327篇 |
2001年 | 284篇 |
2000年 | 240篇 |
1999年 | 287篇 |
1998年 | 274篇 |
1997年 | 197篇 |
1996年 | 218篇 |
1995年 | 213篇 |
1994年 | 184篇 |
1993年 | 161篇 |
1992年 | 130篇 |
1991年 | 143篇 |
1990年 | 145篇 |
1989年 | 111篇 |
1988年 | 92篇 |
1987年 | 79篇 |
1986年 | 59篇 |
1985年 | 62篇 |
1984年 | 28篇 |
1983年 | 35篇 |
1982年 | 26篇 |
1981年 | 20篇 |
1980年 | 13篇 |
1979年 | 10篇 |
1978年 | 8篇 |
1977年 | 10篇 |
1974年 | 6篇 |
1973年 | 9篇 |
排序方式: 共有10000条查询结果,搜索用时 15 毫秒
1.
Mass concentration and isotopic values δ13C and 14C are presented for the water-insoluble refractory carbon(WIRC) component of total suspended particulates(TSP),collected weekly during 2003,as well as from October 2005 to May 2006 at the WMO-GAW Mt.Waliguan(WLG) site.The overall average WIRC mass concentration was(1183±120)ng/m3(n = 79),while seasonal averages were 2081 ±1707(spring),454±205(summer),650±411(autumn),and 1019±703(winter) ng/m3.Seasonal variations in WIRC mass concentrations were consistent with black carbon measurements from an aethalometer,although WIRC concentrations were typically higher,especially in winter and spring.The δ13C PDB value(-25.3 ± 0.8)%.determined for WIRC suggests that its sources are C3 biomass or fossil fuel combustion.No seasonal change in δ13C PDB was evident.The average percent Modern Carbon(pMC) for 14C in WIRC for winter and spring was(67.2 ± 7.7)%(n = 29).Lower pMC values were associated with air masses transported from the area east of WLG,while higher pMC values were associated with air masses from the Tibetan Plateau,southwest of WLG.Elevated pMC values with abnormally high mass concentrations of TSP and WIRC were measured during a dust storm event. 相似文献
2.
Simultaneous quantitative determination of 20 active components in the traditional Chinese medicine formula Zhi‐Zi‐Da‐Huang decoction by liquid chromatography coupled with mass spectrometry: application to study the chemical composition variations in different combinations 下载免费PDF全文
Zheng Tang Ran Yin Kaishun Bi Heyun Zhu Fei Han Kelin Chen Fenrong Wang 《Biomedical chromatography : BMC》2015,29(9):1406-1414
3.
4.
5.
The γcmc values of CTAB-SDS decrease from 63.67 mN/m at 10‡C to 36.38 mN/m at 90‡C, slightly lower than those of either CTAB or SDS.
Correspondingly, the CMC of CTAB-SDS decreases almost by half. The increase of surface activity of CTAB-SDS can be attributed
to the relatively weak electrostatic interaction at high temperature, which is supported by the increase of solubility of
CTAB-SDS with rise in temperature. Catalytic effect on oxidation of toluene derivatives with potassium permanganate follows
the order CTAB-SDS > SDS > CTAB. This is not caused by the dissociative effect of CTAB-SDS with low surface activity at low
temperature, as seen from the fact that almost all oxidative products can be retrieved for different toluene derivatives and
surfactants by mimicking the conditions of reaction. In the emulsifications of toluene derivatives at 90‡C, the time that
turbid water layers of surfactant solutions take to become clear is the same as that of the catalytic effect on oxidation
of toluene derivatives. Thus, it can be inferred that surfactants can improve the oxidation yields of toluene derivatives
by increasing the contact between two reacting phases. 相似文献
6.
HIRFL–CSR加速器中束流与真空中剩余气体的碰撞损失 总被引:1,自引:1,他引:0
研究了重离子加速器中束流与真空中剩余气体的碰撞损失过程和碰撞截面,在依据大量实验数据的基础上,提出了一组计算离子一原子的电荷交换截面的经验公式.以兰州重离子加速器HDRFL及冷却储存环CSR为例,给出了依据碰撞截面的公式计算束流在加速器真空中的传输效率的方法,并计算了在不同真空度下HIRFL的ECR源轴向注入束运线、注入器SFC、前束运线、主加速器SSC和后束运线等不同加速阶段及CSR的传输效率,并提出合理的真空度要求.HIRFL的真空分布测量和束流的损失测量证明了该计算方法的可靠性. 相似文献
7.
Solitary waves and their bifurcations of KdV like equation with higher order nonlinearity 总被引:3,自引:1,他引:2
We investigate the KdV like equation with higher order nonlinearity ut + a(1 +bun)unux + uxxx = 0with n ≥ 1, a, b ∈ R and α≠ 0. The bifurcations and explicit expressions of solitary wave solutions for theequation are discussed by using the bifurcation method and qualitative theory of dynamical systems. Thebifurcation diagrams, existence and number of the solitary waves are given. 相似文献
8.
Syntheses, structures, and properties of novel molybdenum and tungsten complexes of fullerenes 总被引:1,自引:0,他引:1
The synthesis and characterization of several fullerene-based organometallic complexes containing Mo and W is reported. 相似文献
9.
Hongwei Hao Minsheng Wu Yifang Chen Jiaowen Tang Qingyu Wu 《Colloids and surfaces. B, Biointerfaces》2004,33(3-4):151-156
To prevent cyanobacterial bloom in eutrophic water by ultrasonic method, ultrasonic irradiations with different parameters were tested to inhibit Spirulina platensis from growth. The experimental result based on cyanobacterial growth, chlorophyll a and photosynthetic activity showed that, the ultrasonic irradiation inhibited cyanobacterial proliferation effectively, furthermore the inhibition effectiveness increased in the order: 200 kHz>1.7 MHz>20 kHz and became saturated with the increased power. The inhibition mechanism can be mainly attributed to the mechanical damage to the cell structures caused by ultrasonic cavitation, which was confirmed by light microscopy and differential interference microscopy. The optimal frequency of 200 kHz in cavition and sonochemistry was also most effective in cyanobacterial growth inhibition. The higher frequency of 1.7 MHz is weaker than 20 kHz in cavitation, but has more effective inhibition because it is nearer to the resonance frequency of gas vesicle. The inhibition saturation with ultrasonic power was due to the ultrasonic attenuation induced by the acoustic shielding of bubbles enclosing the radiate surface of transducer. 相似文献
10.
LI Shufeng LI Qian YANG Xinlin HUANG Wenqiang** State Key Laboratory of Functional Polymer Materials for Adsorption Separation Institute of Polymer Chemistry Nankai University Tianjin China 《Chinese Journal of Reactive Polymers》2004,(Z1)
1. INTRODUCTION The development of efficient polymer-supported catalysts has attracted much attention [1]. For obtaining polymeric catalysts, catalytically active groups were introduced onto polymers mostly by copolymerization of the appropriate monomers bearing the desired catalyticfunctionalities (e.g. imidazole, OH, and COOH) or by modification of preformed polymers.Another possibility involves the attachment of side chains, containing the desired arrangement of functional groups, o… 相似文献