全文获取类型
收费全文 | 3017篇 |
免费 | 101篇 |
国内免费 | 10篇 |
专业分类
化学 | 2032篇 |
晶体学 | 16篇 |
力学 | 101篇 |
数学 | 318篇 |
物理学 | 661篇 |
出版年
2022年 | 15篇 |
2021年 | 22篇 |
2020年 | 39篇 |
2019年 | 34篇 |
2018年 | 22篇 |
2017年 | 19篇 |
2016年 | 44篇 |
2015年 | 52篇 |
2014年 | 65篇 |
2013年 | 132篇 |
2012年 | 154篇 |
2011年 | 214篇 |
2010年 | 75篇 |
2009年 | 72篇 |
2008年 | 202篇 |
2007年 | 194篇 |
2006年 | 168篇 |
2005年 | 182篇 |
2004年 | 149篇 |
2003年 | 130篇 |
2002年 | 114篇 |
2001年 | 52篇 |
2000年 | 32篇 |
1999年 | 28篇 |
1998年 | 34篇 |
1997年 | 34篇 |
1996年 | 44篇 |
1995年 | 36篇 |
1994年 | 45篇 |
1993年 | 29篇 |
1992年 | 39篇 |
1991年 | 36篇 |
1990年 | 34篇 |
1989年 | 34篇 |
1988年 | 25篇 |
1987年 | 20篇 |
1986年 | 30篇 |
1985年 | 31篇 |
1984年 | 28篇 |
1983年 | 30篇 |
1982年 | 32篇 |
1981年 | 39篇 |
1980年 | 21篇 |
1979年 | 27篇 |
1978年 | 30篇 |
1977年 | 28篇 |
1976年 | 20篇 |
1975年 | 19篇 |
1974年 | 24篇 |
1973年 | 23篇 |
排序方式: 共有3128条查询结果,搜索用时 15 毫秒
1.
Claudia Poloni Marc C. A. Stuart Pieter van der Meulen Wiktor Szymanski Ben L. Feringa 《Chemical science》2015,6(12):7311-7318
The external photocontrol over peptide folding, by the incorporation of molecular photoswitches into their structure, provides a powerful tool to study biological processes. However, it is limited so far to switches that exhibit only a rather limited geometrical change upon photoisomerization and that show thermal instability of the photoisomer. Here we describe the use of an overcrowded alkene photoswitch to control a model β-hairpin peptide. This photoresponsive unit undergoes a large conformational change and has two thermally stable isomers which has major influence on the secondary structure and the aggregation of the peptide, permitting the phototriggered formation of amyloid-like fibrils. 相似文献
2.
Padavattan Govindaswamy Patrick J. Carroll Yurij A. Mozharivskyj Mohan Rao Kollipara 《Journal of Chemical Sciences》2006,118(4):319-326
The reaction of [{(η5-C5Me5)M(μ-Cl)Cl}2] {where M = Rh (1), Ir (2)} with functionalized phosphine viz., diphenyl-2-pyridylphosphine (PPh2Py) in dichloromethane solvent yield neutral ϰ1-P-coordinated rhodium and iridium complexes [(η5-C5Me5)RhCl2(κ1-P-PPh2Py)]3 and [(η5-C5Me5) IrCl2(ϰ1-P-PPh2Py)]4. Reaction of complexes 1 and 2 with the ligand PPh2Py in methanol under reflux give bis-substituted complexes such as [(η5-C5Me5)RhCl(ϰ1-P-PPh2Py)2]+
5 and [(η5-C5Me5)IrCl(ϰ1-P-PPh2Py)2]+
6, whereas stirring in methanol at room temperature gives P-, N-chelating complexes of the type [(η5-C5Me5)RhCl(ϰ2-P-N-PPh2Py)]+ 7 and [(η5-C5Me5)IrCl(ϰ2-P-N-PPh2Py)]+
8. Neutral ϰ1-P-coordinated complexes [(η5-C5Me5)RhCl2(ϰ1-P-PPh2Py)]3 and [(η5-C5Me5)IrCl2(ϰ1-P-PPh2Py)]4 easily undergo conversion to the cationic P-, N-chelating complexes [(η5-C5Me5)RhCl(ϰ2-P-N-PPh2Py)]+
7 and [(η5-C5Me5) IrCl(ϰ2-P, N-PPh2Py)]+
8 on stirring in methanol at room temperature. These complexes are characterized by FT-IR and FT-NMR spectroscopy as well as
analytical methods. The molecular structures of the representative complexes [(η5-C5Me5)RhCl2(ϰ1-P-PPh2Py)]3, [(η5-C5Me5)IrCl2(ϰ1-P-PPh2Py)]4 and hexafluorophosphate salt of complex [(η5-C5Me5)IrCl(ϰ2-P-PPh2Py)2]+
6 are established by single-crystal X-ray diffraction methods 相似文献
3.
D. De Salvador A. Coati E. Napolitani M. Berti A.V. Drigo M.S. Carroll J.C. Sturm J. Stangl G. Bauer L. Lazzarini 《Applied Physics A: Materials Science & Processing》2002,75(6):667-672
In this work we investigate the diffusion and precipitation of supersaturated substitutional carbon in 200-nm-thick SiGeC
layers buried under a silicon cap layer of 40 nm. The samples were annealed in either inert (N2) or oxidizing (O2) ambient at 850 °C for times ranging from 2 to 10 h. The silicon self-interstitial (I) flux coming from the surface under
oxidation enhances the C diffusion with respect to the N2-annealed samples. In the early stages of the oxidation process, the loss of C from the SiGeC layer by diffusion across the
layer/cap interface dominates. This phenomenon saturates after an initial period (2–4 h), which depends on the C concentration.
This saturation is due to the formation and growth of C-containing precipitates that are promoted by the I injection and act
as a sink for mobile C atoms. The influence of carbon concentration on the competition between precipitation and diffusion
is discussed.
Received: 19 October 2001 / Accepted: 19 December 2001 / Published online: 20 March 2002 / Published online: 20 March 2002 相似文献
4.
Stuart S. Antman 《Journal of Elasticity》2003,70(1-3):55-64
The introduction of artificial viscosity into the partial differential equations of mechanics is often useful for both analytic and numerical studies. The traditional forms of artificial viscosity, originally designed to treat problems for fluids, when applied to problems for solids often lead to equations describing material properties that are not invariant under rigid motions. Consequently, for rapidly rotating bodies, artificial viscosity could produce serious errors. In this paper it is shown how to introduce artificial viscosity in a properly invariant way, and that the resulting systems have a rich and attractive structure, which beckons analysis. 相似文献
5.
Christopher E. Stuart Paul Abraham 《Journal of Mathematical Analysis and Applications》2004,300(2):224-361
Generalizations of the Nikodym boundedness and Vitali–Hahn–Saks theorems for scalar-valued measures on rings of sets that are in general not σ-rings are presented. As a consequence, the rings of subsets of N with density zero and uniform density zero are shown to have the Nikodym property. In addition, vector measure generalizations of the Vitali–Hahn–Saks theorem are given. 相似文献
6.
Stuart P. RomerilVictor Lee Jack E. Baldwin Timothy D.W. ClaridgeBarbara Odell 《Tetrahedron letters》2003,44(42):7757-7761
The absolute configuration of the marine sponge alkaloid pyrinodemin A is established by organic synthesis. 相似文献
7.
For a conformal manifold we introduce the notion of an ambient connection, an affine connection on an ambient manifold of
the conformal manifold, possibly with torsion, and with conditions relating it to the conformal structure. The purpose of
this construction is to realise the normal conformal Tractor holonomy as affine holonomy of such a connection. We give an
example of an ambient connection for which this is the case, and which is torsion free if we start the construction with a
C-space, and in addition Ricci-flat if we start with an Einstein manifold. Thus, for a C-space this example leads to an ambient metric in the weaker sense of Čap and Gover, and for an Einstein space to a Ricci-flat
ambient metric in the sense of Fefferman and Graham.
Current address for first author: Erwin Schr?dinger International Institute for Mathematical Physics (ESI), Boltzmanngasse
9, 1090 Vienna, Austria
Current address for second author: Department of Mathematics, University of Hamburg, Bundesstra?e 55, 20146 Hamburg, Germany 相似文献
8.
9.
R. Carroll 《Theoretical and Mathematical Physics》2007,152(1):904-914
Quantization using quantum potentials is described in terms of momentum fluctuations, and it is related to Fisher information
and entropy.
__________
Translated from Teoreticheskaya i Matematicheskaya Fizika, Vol. 152, No. 1, pp. 32–44, July, 2007. 相似文献
10.
Robert Carroll George Delic R. P. Gilbert 《Mathematical Methods in the Applied Sciences》1989,11(1):43-63
It is shown how Newton–Sabatier methods (arising in inverse scattering at fixed energy) can be related to spectral measures and typically when they correspond to regular potentials. A number of spectral formulae for various transmutation kernels are also given in terms of general Kontorovi?–Lebedev theory and connections to generating functions, generalized orthogonal polynomials, etc. are indicated. 相似文献