排序方式: 共有75条查询结果,搜索用时 31 毫秒
1.
Alexander V. Stepakov Jörg Magull Galina L. Starova Rafael R. Kostikov 《Tetrahedron》2006,62(15):3610-3618
Treatment of substituted 1,3-dithiolanes and 1,3-oxathiolanes with methyl diazoacetate in the presence of Rh2(OAc)4 effects ring expansion to the corresponding substituted 1,4-dithiane-2-carboxylates and 1,4-oxathiane-3-carboxylates. The sulfur ylides initially generated in these reactions undergo Stevens rearrangement in competition with both [2,3]-C-C-sigmatropic rearrangement and intramolecular fragmentation. In the case of 2-styryl-substituted 1,3-oxathiolane and 1,3-dithiolane, ring expansion on one-, three- and four-carbons subsequently takes place. 相似文献
2.
I. A. Gluzdikov M. S. Egorov S. I. Selivanov G. L. Starova A. G. Shavva 《Russian Journal of Organic Chemistry》2006,42(11):1675-1682
Stereoselectivity of reaction with Raney nickel of D-homoestra-1,3,5(10),8,14-pentaenes containing one or two methyl groups in position 16 was investigated. The reaction direction is governed by the orientation of the substituent at C17a. The signals in the 1H and 13C NMR spectra of four synthesized compounds were completely assigned. Criteria for evaluation of the character of rings junction in analogs of D-homoequilenine were suggested. 16,16-Dimethyl-3-methoxy-D-homo-13α-estra-1,3,5(10),6,8-pentaen-17a-one was subjected to X-ray diffraction analysis. 相似文献
3.
A. P. Molchanov T. Q. Tran A. V. Stepakov G. L. Starova R. R. Kostikov 《Russian Journal of Organic Chemistry》2014,50(1):78-82
N-Aryl-C-(arylcarbamoyl)nitrones regioselectively add to methyl 2-(2-phenylcyclopropylidene)-acetate and methyl 2-methylidene-3-phenylcyclopropanecarboxylate to give in each case two diastereoisomeric 5-oxa-6-azaspiro[2.4]heptane-4-carboxylates. 相似文献
4.
Katkova S. A. Eliseev I. I. Mikherdov A. S. Sokolova E. V. Starova G. L. Kinzhalov M. A. 《Russian Journal of General Chemistry》2021,91(3):393-400
Russian Journal of General Chemistry - A series of cyclometalated platinum(II) complexes with nitrile and isocyanide ligands (RCN and RNC; R = t-Bu, Bn, Ph) have been synthesized in 60–80%... 相似文献
5.
R. V. Rodik V. Yu. Malytskyi V. S. Starova T. V. Yegorova A. I. Kysil O. A. Zaporozhets Z. V. Voitenko V. I. Kalchenko 《Journal of inclusion phenomena and macrocyclic chemistry》2013,77(1-4):343-350
New derivatives of calix[4]arenes, containing two isoindole fragments in distal positions of the macrocycle upper rim were synthesized. According to NMR and molecular modeling data, the obtained calixarenes exist in “flattened cone” conformation with inclination angles of benzene rings to the macrocycle plane equal to 133–140° and 92–100°. Fluorometric studies showed the presence of self-aggregation of isoindolenylcalixarenes in acetone solutions starting from micromolar concentrations. 相似文献
6.
A. G. Shavva G. L. Starova S. I. Selivanov S. N. Morozkina 《Chemistry of Heterocyclic Compounds》2008,44(2):148-152
By X-ray crystallographic analysis and NMR spectroscopy it was demonstrated that the conformations of several D-homo-6-oxa-8α
analogs of steroidal estrogens are similar in the crystal and in solution. The distances between the hydrogen atoms in these
molecules, calculated by the ab initio and MM+ methods, correspond to the experimental data.
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Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 2, pp. 202–207, February, 2008. 相似文献
7.
Sergey Miltsov Vladimir Karavan Alexandr Misharev Galina Starova Julian Alonso-Chamarro Mar Puyol 《Tetrahedron letters》2017,58(34):3353-3357
meso-Bromosubstituted indodicarbocyanine dyes produce dimeric molecules, together with the debrominated species, under acid catalysis. The relationship between the dimerization and hydrodebromination routes depends on the aryl substitution of the dyes. A possible reaction mechanism is also proposed. 相似文献
8.
G. L. Starova M. Yu. Skripkin I. M. Gusev 《Russian Journal of General Chemistry》2010,80(7):1236-1241
The crystalline structures of four tetraethylammonium salts, [Et4N]CdBrP3, [Et4N]Cd2Br5, [Et4N]2CoBr4, and [Et4N]2CuBr4 were determined by X-ray analysis of their single crystals. The CdBr
x
2 − x
anions in the examined salts are linked to polymeric chains, and the coordination number of cadmium ion is 5 or 6. The d-metal ion in the copper and cobalt complexes has tetrahedral configuration, and the corresponding anions are discrete. 相似文献
9.
Alexander V. Stepakov Ekatherine A. Popova Liubov V. Stepakova Vitaly M. Boitsov Galina L. Starova Elena V. Grinenko 《Tetrahedron》2010,66(27-28):5262-5269
Imides of arylmaleic acids in the presence of 3,5-dimethyl-1H-pyrazole underwent (4+2) dimerization under heating in chlorobenzene within 24 h to afford 1,2,3,3a,3b,4,5,6,6a,10b-decahydrobenzo[e]pyrrolo[3,4-g]isoindole-1,3,4,6-tetraones in good yields. It was established that during the heating of imides of arylmaleic acid in 2,6-lutidine at 100 °C the (4+2) dimerization products containing a lutidine fragment are obtained. 相似文献
10.
Alexander V. Stepakov Michail A. KinzhalovVitaly M. Boitsov Liubov V. StepakovaGalina L. Starova Sergey Yu. VyazminElena V. Grinenko 《Tetrahedron letters》2011,52(24):3146-3149
Reaction of N-aryl substituted maleimides with aliphatic ketazines leads to the formation of 4,5-dihydropyridazin-3(2H)-ones in moderate yields. The reaction proceeds through 1,4-addition of an azine to the maleimide double bond, as confirmed by separation of the corresponding adducts in some cases, which are then converted into 4,5-dihydropyridazin-3(2H)-ones. In addition, the solid-state synthesis of 4,5-dihydropyridazin-3(2H)-ones is demonstrated for the first time. 相似文献