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1.
Soluble complex-formation of mercury(II) thiocyanate has been studied oscillometrically. The titration of mercury(II) nitrate with thiocyanate gives one inflection corresponding to the formation of Hg(SCN)2, while in the reverse titration the formation of Hg(SCN)+ is also indecated. The method is useful for a rapid determination of very small quantities of mercury or thiocyanate in highly dilute solutions. The titrations can be effected in presence of nitric acid provided its total acidity in the system does not exceed about N. Further Work on the mercury(II) -halide and mercury(II)-cyanide reactions is in progress. 相似文献
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P. K. Mukherjee R. K. Moitra A. Mukherji 《International journal of quantum chemistry》1971,5(6):637-646
In this paper a fully coupled variation-perturbation theory has been introduced for handling open-shell atomic systems in the presence of static perturbations. The static dipolar and quadrupolar polarizabilities and shielding factors for Li, Be+, B2+, B, C+, Na and Al have been calculated and compared with available results. Important sources of discrepancies in previous calculations of shielding factors have been noticed and critically examined. The dipolar shielding factors calculated in this paper show satisfactory agreement with the theoretical N/Z ratio. In the absence of any theoretical test for the quadrupolar shielding factor, the accuracy of the calculations of γ∞, should be judged in the light of the accuracy of the corresponding β∞ values. 相似文献
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P. Strunz D. Mukherji G. Pigozzi R. Gilles T. Geue K. Pranzas 《Applied Physics A: Materials Science & Processing》2007,88(2):277-284
The Ni3Si-type nanoparticles dispersed in a mixture of H2O/D2O were characterised by SANS using the contrast variation method. The existence of a core-shell structure in the nanoparticles
with a Ni3Si(Al) core and amorphous SiOx shell is confirmed by the SANS measurements. The nanoparticles were produced by extracting precipitates from a bulk Ni-13.3Si-2Al
( at. %) alloy using electrochemical phase separation technique and were pre-characterised by X-ray diffraction and transmission
electron microscopy. By comparing the precipitate morphology in the Ni-Si-Al alloy with the extracted nanoparticles in the
SANS measurements, it is clearly established that the precipitates shape and size are unaffected by the extraction process
and that the amorphous shell forms on top of the particle core. However, the present measurement could not confirm or exclude
the presence of H atoms in the shell structure.
PACS 61.12.Ex; 61.12.-q; 61.46.Df; 61.82.Rx 相似文献
6.
We propose a new approximation scheme to obtain analytic expressions for the bond-state energies and eigenfunctions for any arbitrary bound nl-state of the Hulthén potential. The predicted energies Enl are in excellent agreement with the perturbative results of Lai and Lin. The scope for an extension of the method to the continuum states is also discussed. 相似文献
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Anil K. Mukherji 《Journal of separation science》1978,1(5):273-275
Systematic studies on operation variables affecting GPC separations using the semirigid Microstyragel (Waters Associates) and the rigid silica packings (DuPont) of about equivalent porosity are reported. The dependence of (a) flow rate, (b) injection volume, and (c) concentration on elution volume and theoretical plates are examined. 相似文献
10.
The formation of a coloured chelate, having λmax at 540 mμ, between cupric ions and ammonium aurintricarboxylate has been reported. It has been concluded that only one complex having metal : reagent ratio of 1:2 is formed in solution. The method adopted for investigation has been the continuous variation method, using spectrophotometric and electrical conductance measurements. It has been observed that there is an increase in acidity on mixing the reactants, which shows that hydrogen ions are liberated as a result of chelation It has been suggested that chelation occurs between the phenolic oxygen and the adjacent carboxylic oxygen.A method has been presented for the calculation of formation constant from spectrophotometric data and the value of K in the case of the chelate investigated has been calculated to be 6.45.108. The free energy of formation works out to be —14.6 kcal at 25°C. 相似文献