全文获取类型
收费全文 | 783篇 |
免费 | 23篇 |
专业分类
化学 | 592篇 |
晶体学 | 12篇 |
力学 | 20篇 |
数学 | 112篇 |
物理学 | 70篇 |
出版年
2023年 | 4篇 |
2022年 | 23篇 |
2021年 | 28篇 |
2020年 | 14篇 |
2019年 | 13篇 |
2018年 | 15篇 |
2017年 | 12篇 |
2016年 | 29篇 |
2015年 | 17篇 |
2014年 | 19篇 |
2013年 | 37篇 |
2012年 | 42篇 |
2011年 | 41篇 |
2010年 | 29篇 |
2009年 | 41篇 |
2008年 | 48篇 |
2007年 | 45篇 |
2006年 | 51篇 |
2005年 | 44篇 |
2004年 | 36篇 |
2003年 | 38篇 |
2002年 | 29篇 |
2001年 | 11篇 |
2000年 | 7篇 |
1999年 | 8篇 |
1998年 | 13篇 |
1997年 | 5篇 |
1996年 | 16篇 |
1995年 | 7篇 |
1994年 | 7篇 |
1993年 | 5篇 |
1992年 | 3篇 |
1991年 | 5篇 |
1990年 | 4篇 |
1989年 | 8篇 |
1988年 | 7篇 |
1987年 | 4篇 |
1986年 | 6篇 |
1985年 | 3篇 |
1984年 | 7篇 |
1983年 | 5篇 |
1982年 | 2篇 |
1981年 | 3篇 |
1980年 | 4篇 |
1979年 | 3篇 |
1978年 | 2篇 |
1977年 | 1篇 |
1976年 | 4篇 |
1971年 | 1篇 |
排序方式: 共有806条查询结果,搜索用时 709 毫秒
1.
We report on the realization and characterization of electro-responsive and pressure sensitive polydimethylsiloxane (PDMS) conductive photonic structures combined with the reconfigurable properties of short pitch cholesteric liquid crystals (aligned in Grandjean configuration). By combining ion-implantation process and surface chemistry functionalization, we have overcome the insulating properties of PDMS and induced long range organization of cholesteric liquid crystals, thus controlling both diffraction and selective Bragg reflection of light by means of external perturbations (electric field, pressure). We have characterized our devices in terms of morphological, optical and electro-optical properties. 相似文献
2.
3.
Infinite dimensional duality and applications 总被引:2,自引:0,他引:2
Patrizia Daniele Sofia Giuffrè Giovanna Idone Antonino Maugeri 《Mathematische Annalen》2007,339(1):221-239
The usual duality theory cannot be applied to infinite dimensional problems because the underlying constraint set mostly has
an empty interior and the constraints are possibly nonlinear. In this paper we present an infinite dimensional nonlinear duality
theory obtained by using new separation theorems based on the notion of quasi-relative interior, which, in all the concrete
problems considered, is nonempty. We apply this theory to solve the until now unsolved problem of finding, in the infinite
dimensional case, the Lagrange multipliers associated to optimization problems or to variational inequalities. As an example,
we find the Lagrange multiplier associated to a general elastic–plastic torsion problem. 相似文献
4.
5.
Giovanni Cerioni Costantino Floris Giaime Marongiu Gabriele Navarra Francesca Sotgiu 《Journal of heterocyclic chemistry》1994,31(5):1151-1155
1-5-benzoxathiepine compounds are a novel class of heterocyclic rings that present interesting properties as central nervous system depressants. With the aim to contribute to the elucidation of the structure-activity relationship of this class of compounds we report a structural study of the 3-hydroxy-1,5-benzoxathiepine both in solution and in the solid state. Studies by dynamic 13C-nmr in solution show that three conformations are possible for the oxathiepin ring. A unique chair conformation characterizes the atoms in the oxathiepine ring of the crystallized molecule. The crystal structure was solved by direct methods. Values of bond distances and angles are within the expected range. 相似文献
6.
Giovanna Idone 《Journal of Mathematical Analysis and Applications》2004,290(1):147-170
Hölder regularity up to the boundary of the solutions to the Dirichlet problem for second order elliptic systems with nonlinearity q>2 and with controlled growth is proved when n?q+2. 相似文献
7.
This paper presents the preliminary results obtained using an Electron Paramagnetic Resonance imaging apparatus operating at 280 MHz. The acquisition technique and the procedure used to obtain the spin density spatial localization are presented and specimen images of extended samples are given. The accuracy of the images and the spatial resolution are also discussed. 相似文献
8.
Giovanna Citti 《Rendiconti del Circolo Matematico di Palermo》1986,35(3):364-375
In questa nota proviamo un teorema di esistenza di soluzioni positive su tuttoR n della equazionediv(|Du| p?2Du)+f(u)=0. 相似文献
9.
Marco Berettoni Giovanna De Chiara Tommaso Iacoangeli Paola Lo Surdo Rinaldo Marini Bettolo Lorenzo Montagnini Di Mirabello Luca Nicolini Rita Scarpelli 《Helvetica chimica acta》1996,79(7):2035-2041
A novel preparation of methyl (13S)-13-hydroxyisoatisiren-18-oate ( 4 ), a key-intermediate in a synthesis of (+)-methyl trachyloban-18-oate ((+)- 1 ), from (?)-abietic acid, is described. Since (?)- 1 has been previously converted into (?)-methyl 16-oxo-17-norkauran-18-oate ((?)- 16 ), our preparation of 4 constitutes also a formal total synthesis, from (?)-abietic acid, of (+)- 16 . Key steps in this approach were the allene photoaddition to podocarp-8(14)-en-13-one ( 5 ) and the conversion of the endo-toluene-4-sulfonate 11 into the exo-benzoate 12b . 相似文献
10.
Fabrizio Melani Lucia Cecchi Giovanna Palazzino Guido Filacchioni 《Journal of heterocyclic chemistry》1986,23(1):173-176
Following our reports on synthetic tricyclic analogues of antitumor anthramycin the synthesis of some isomers pyrazolo[4,5-d]- and pyrazolo[4,5-c][1]benzazepine derivatives is reported. 相似文献