全文获取类型
收费全文 | 275篇 |
免费 | 9篇 |
专业分类
化学 | 189篇 |
晶体学 | 1篇 |
力学 | 35篇 |
数学 | 15篇 |
物理学 | 44篇 |
出版年
2023年 | 2篇 |
2022年 | 3篇 |
2021年 | 1篇 |
2020年 | 2篇 |
2019年 | 7篇 |
2018年 | 2篇 |
2017年 | 3篇 |
2016年 | 6篇 |
2015年 | 1篇 |
2014年 | 7篇 |
2013年 | 3篇 |
2012年 | 19篇 |
2011年 | 28篇 |
2010年 | 11篇 |
2009年 | 9篇 |
2008年 | 21篇 |
2007年 | 13篇 |
2006年 | 23篇 |
2005年 | 21篇 |
2004年 | 14篇 |
2003年 | 4篇 |
2002年 | 11篇 |
2001年 | 2篇 |
2000年 | 4篇 |
1999年 | 1篇 |
1996年 | 1篇 |
1995年 | 1篇 |
1994年 | 7篇 |
1993年 | 2篇 |
1992年 | 2篇 |
1991年 | 3篇 |
1990年 | 5篇 |
1989年 | 4篇 |
1988年 | 3篇 |
1987年 | 1篇 |
1985年 | 5篇 |
1984年 | 8篇 |
1983年 | 1篇 |
1982年 | 5篇 |
1981年 | 5篇 |
1979年 | 1篇 |
1977年 | 3篇 |
1976年 | 1篇 |
1975年 | 2篇 |
1974年 | 1篇 |
1973年 | 2篇 |
1972年 | 1篇 |
1957年 | 1篇 |
1956年 | 1篇 |
排序方式: 共有284条查询结果,搜索用时 21 毫秒
1.
Pál Sohár Gábor Bernáth Géza Stájer Angela E. Szabo 《Magnetic resonance in chemistry : MRC》1989,27(9):872-876
Pentacyclic isoxazolines were obtained by the cycloaddition of benzonitrile oxide to norbornene-azetidinone-fused 3,1-oxazines. The constitutions of two of the isomers obtained, and the configurations and conformations of all products, were determined by means of 1H and 13C NMR spectroscopy and DNOE experiments. 相似文献
2.
- The corresponding - and -methyl- and -benzyl-5,6- and 4,5-tetramethylenetetrahydro-l,3-oxazines were synthesized from - and -methyl and-benzyl-2- aminomethyl-1-cyclohexanols , from - and -methyl- and benzyl -2-hydroxymethyl-1-cyclohexylamines by reaction with formaldehyde. The aminoalcohols and were prepared in considerably higher yields than in earlier procedures. NMR spectroscopy showed that the isomers of the synthesized oxazines were conformationally homogeneous in solution, and their preferred conformation (inside or outside) depended on the steric requirement of the groups attached to the anellation points, whereas a bulky C-2 substituent had no influence on the predominant conformation. The structure of -benzyl--4,5-tetramethylenetetrahydro-1,3-oxaziniumpicrate . determined by X-ray diffraction analysis, was in agreement with the predominant N-outside conformation of the corresponding base, established by means of NMR spectroscopy. 相似文献
3.
S. K. Soh D. C. Sundberg 《Journal of polymer science. Part A, Polymer chemistry》1982,20(5):1299-1313
It is well known that the reaction rate and molecular weight of vinyl polymers can change markedly during the course of polymerization and that these changes are due to the influence of diffusion on the termination reaction. The chain length dependence of the termination rate constant has been considered in this work and has resulted in a general method of treating the polymerization kinetics and molecular weight distribution. This method is independent of the form of the chain length dependency and is capable of dealing with both disproportionation and recombination modes of termination. A specific model for the termination rate constant with chain length dependence is proposed and is based on free volume theory and entanglement coupling. Master curves for the characteristics of the reaction rate and molecular weight distribution are presented with the application of this model. 相似文献
4.
5.
6.
7.
Soh N Imato T Kawamura K Maeda M Katayama Y 《Chemical communications (Cambridge, England)》2002,(22):2650-2651
A novel fluorescent probe, which could be the first example of a ratiometric molecular probe for direct monitoring of NO production, has been developed using a 'spin-exchange' mechanism. 相似文献
8.
János Szabó Ágnes Katócs Gábor Bernáth Pál Sohár 《Monatshefte für Chemie / Chemical Monthly》1989,120(5):463-471
Summary (±)-4-Thiacarnegin (3) was synthesized by reaction of 6,7-dimethoxy-3-methyl-2H-1,3-benzothiazinium iodide (2) with methyl magnesium iodide, thereby opening a new synthetic route to 4-substituted dihydro-2H-1,3-benzothiazines. Compound3 was also obtained by reduction of 6,7-dimethoxy-3,4-dimethyl-2H-1,3-benzothiazinium iodide (5). In a similar way, reduction of the quaternary salts9 a–c afforded the (±)-4-thia analogues of cryptostilin-I, -II and -III (10 a–c). The isomers of the former compounds (12 a–c) were also synthesized by reduction of the 4H-1,3-benzothiazinium salts11 a–c.
Synthese von 4-Thiaanalogen von Alkaloiden mit Isochinolingerüst
Zusammenfassung Aus 6,7-Dimethoxy-3-methyl-2H-1,3-benzothiaziniumjodid (2) wurde mit Methylmagnesiumjodid (±)-Thiacarnegin (3) dargestellt. Diese Reaktion bietet ein neues Verfahren für die Synthese von 4-substituierten Dihydro-2H-1,3-benzothiazinen.3 wurde auch durch Reduktion von 6,7-Dimethoxy-3,4-dimethyl-2H-1,3-benzothiaziniumjodid (5) erhalten. Die Reduktion der quartären Ammoniumsalze9 a–c ergab ebenfalls die Cryptostillin I-, II-, III-(±)-4-thiaanalogen Verbindungen (10 a–c). Reduktion der 4H-1,3-Benzothiazinium-Salze11 a–c lieferte die entsprechenden Isomeren12 a–c der obengenannten Verbindungen.相似文献
9.
New tetracyclic derivatives (3a,, 5, 8) similar to protoberberines, but containing a lactam structural element and other hetero atoms besides the bridge-head nitrogen in rings B and C, were prepared by cycloaddition of 6,7-dimethoxy-2H-1,3-benzothiazine (1a) with -substituted aromatic carboxylic acid derivatives (2a,, 4) and from 4- methyl-6,7-dimethoxy-2-1,3-benzothiazine (1b) with 3.5-dinitrobenzoyl chloride. 相似文献
10.
József Reiter László Pongó Pál Sohár Péter Dvortsák 《Journal of heterocyclic chemistry》1988,25(1):173-176
The reaction of Schiff bases prepared from 1- and 2-substituted-5-amino-1,2,4-triazoles with phenoxyacetyl chlorides in the presence of triethylamine and a mixture of phosphorus oxychloride and dichloroacetic acid in dimethylformamide to yield β-lactam 4 , a dihydro-1,2,4-triazolo[4,3-a]pyrimidine-5(1H)-one 5, a 1,2,4-triazolo[1,5-a]pyrimidin-5(3H)-one 9 and the corresponding 1,2,4-triazolo[4,3-a]pyrimidine-5(1H)-one 10 derivatives was studied. 相似文献