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A study has been made of the chemisorption of O2 from various gaseous media on divalent chromium ions in chromosilicate systems under dynamic conditions. After passing through the chemisorbent layer the residual O2 content of the gaseous mixtures is 10–6–10–7 vol. %. The adsorption capacity of the chemisorbents increases in proportion to their Cr(II) content and decreases as the moisture content increases in the gas mixture from which the oxygen is absorbed. The chemisorbents can be repeatedly regenerated by treating them with hydrogen.N. D. Zelinskii Institute of Organic Chemistry, Russian Academy of Sciences, 117913 Moscow. Translated fromIzvestiya Akademii Nauk, Seriya Khimicheskaya, No. 11, pp. 2500–2505, November, 1992. 相似文献
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M. A. Ryashentseva E. P. Belanova K. I. Slovetskaya E. G. Aleshin 《Russian Chemical Bulletin》1986,35(4):710-712
Conclusions In aluminum-chromium catalysts promoted by potassium and rare-earth oxides, used in the synthesis of 2-methylthiophene by heterocyclization of n-pentane with hydrogen sulfide, there are present low-valence cations of chromium and the rare-earth that enter into the active centers of the catalysts.Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 4, pp. 782–784, April, 1986. 相似文献
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K. I. Slovetskaya 《Russian Chemical Bulletin》2004,53(10):2168-2171
Stability of the Pd-, Co-, and Mn-zeolite catalysts supported on metal blocks was studied in high-temperature methane oxidation. The temperature regions were found in which the starting catalysts exhibit stable performance. The temperature was determined at which a partial deactivation is followed by stabilization of catalysts in reaction environment. In terms of specific activity, the partially deactivated Pd-zeolite catalyst is several times more active than conventional oxidation catalysts Pd/Al2O3, Pt/Al2O3, and the most active oxide CeO·6Al2O3.__________Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 10, pp. 2075–2078, October, 2004. 相似文献
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The high-temperature complete oxidation of methane over metallic monolith-supported zeolite catalysts containing isolated Mn, Co, and Pd ions was studied. The reaction involves heterogeneous and heterogeneous-homogeneous catalytic processes. The ratio between these processes depends on the temperature, feed rate, and the amount of catalyst charged in the reactor. In the heterogeneous catalytic process, the activity of the catalysts supported on the Fe—Cr—Al monolithic alloy decreases in the series Pd > Mn > Co > Fe—Cr—Al monolith and the reaction rate uniformly increases with increasing contact time. In the heterogeneous-homogeneous process, the reaction rate drastically increases and a 100% conversion of methane to CO2 can be achieved by minor variations of the contact time. In this case, methane oxidation depends not only on the catalyst chemical composition but also on its external surface area and the reaction volume. 相似文献
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