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1.
2.
Infrared difference spectroscopy has been used to study the association of p-nitrophenol (NP) with butyl acetate (BA) in CCl4 and in undiluted BA. It has been shown that in CCl4, an associate is formed, [NP·BA] ·BA (Ia), in which one molecule of BA is linked to the NP by a hydrogen bond, and the second BA molecule is linked to the H-complex NP·BA by outer-sphere (dipole-dipole) interaction. In undiluted BA with low concentrations of NP, (Ia) is formed; with high concentrations of NP, an associate [(NP)2BA] ·mBA is formed, in which two molecules of NP are bonded successively to each other and with a BA molecule; and the number of outer-sphere BA molecules may depend on the concentration of free BA molecules in the solutions.Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 3, pp. 593–599, March, 1991. 相似文献
3.
Stefan Wörner Boryana Racheva-Iotova Stoyan Stoyanov 《Mathematical Methods of Operations Research》2002,55(2):247-263
Applying real options thinking to company valuation seems theoretically and intuitively appealing. However, the real option
analogy of a single European option as well as the compound option proxy perform poorly when applied to company valuation.
We therefore suggest to rework the building blocks of real option applications to corporate valuation.
We introduce a framework to delineate the distribution of the underlying asset in the risk neutral world, which is important
in order to value any derivative. This is achieved by an algorithm to calibrate a basket option model using real world data
of observed share prices. The fitting takes account of the class of stable distributions. The index of stability of asymmetric
α stable distribution serves as an over-all parameter to characterise the specific distribution. 相似文献
4.
B.J. Stoyanov R.A. Farrell J.F. Bird 《Journal of Computational and Applied Mathematics》1994,50(1-3):533-543
Asymptotic expansions of certain finite and infinite integrals involving products of two Bessel functions of the first kind are obtained by using the generalized hypergeometric and Meijer functions. The Bessel functions involved are of arbitrary (generally different) orders, but of the same argument containing a parameter which tends to infinity. These types of integrals arise in various contexts, including wave scattering and crystallography, and are of general mathematical interest being related to the Riemann—Liouville and Hankel integrals. The results complete the asymptotic expansions derived previously by two different methods — a straightforward approach and the Mellin-transform technique. These asymptotic expansions supply practical algorithms for computing the integrals. The leading terms explicitly provide valuable analytical insight into the high-frequency behavior of the solutions to the wave-scattering problems. 相似文献
5.
In 1965 Knuth (J. Algebra 2 (1965) 182) noticed that a finite semifield was determined by a 3-cube array (aijk) and that any permutation of the indices would give another semifield. In this article we explain the geometrical significance of these permutations. It is known that a pair of functions (f,g) where f and g are functions from GF(q) to GF(q) with the property that f and g are linear over some subfield and g(x)2+4xf(x) is a non-square for all x∈GF(q)∗, q odd, give rise to certain semifields, one of which is commutative of rank 2 over its middle nucleus, one of which arises from a semifield flock of the quadratic cone, and another that comes from a translation ovoid of Q(4,q). We show that there are in fact six non-isotopic semifields that can be constructed from such a pair of functions, which will give rise to six non-isomorphic semifield planes, unless (f,g) are of linear type or of Dickson-Kantor-Knuth type. These six semifields fall into two sets of three semifields related by Knuth operations. 相似文献
6.
L. Stoyanov 《Mathematische Annalen》2002,324(4):743-771
In this paper we consider properties of obstacles satisfying some non-degeneracy conditions that can be recovered from the
scattering length spectrum (SLS). Clearly the latter tells us whether the obstacle K is trapping or non-trapping. If the set of trapped points is relatively small, then the SLS also determines the volume of
the obstacle, the number of its connected components, and whether its boundary is convex everywhere or it has non-trivial
concavities. Under the additional assumption that the curvature of the obstacle does not vanish of infinite order, it is proved
that from the SLS one can recover certain information about the number of reflection points of any simply reflecting ray in
the exterior of the obstacle. Finally, for some special classes of obstacles (e.g. star-shaped ones), it is shown that the
SLS completely determines the obstacle.
Received: 2 March 1999 / Revised version: 16 January 2001 / Published online: 5 September 2002 相似文献
7.
S. Stoyanov 《Applied Physics A: Materials Science & Processing》1990,50(3):349-352
A quantitative treatment of the crystallization kinetics in MBE growth of vicinal surfaces results the relation l
2=2D
sK between the surface diffusion coefficient D
s, the time for a monolayer deposition and the interstep distance l at which the RHEED intensity oscillations disappear. The correction factor K depends on the size and the energy of the two-dimensional critical nucleus and it is estimated to be smaller than 10–2. The currently used interpretation of the RHEED intensity oscillations ignores the correction factor K and, therefore, the calculated values of D
s are several orders of magnitude smaller than its real values. The surface transport during the time of growth interruption is discussed in connection with the tendency to three dimensional growth at every second interface (where a deposition of the material with strong intermolecular bonds starts) of a small period superlattice. 相似文献
8.
IR spectroscopy was used to study the structure and composition of Eu(III) and Sr(II) complexes formed by cation-exchange extraction of these metals from their aqueous nitrate solutions with dichlorethane solutions of mixtures of chlorinated cobalt(III) dicarbollide (CCD) as a superacid with diphenyldiphosphine dioxides containing a methyl (Me-DPDO), ethyl (Et-DPDO), or polyoxyethylene bridge between two phosphorus atoms of phosphine oxide groups. At molar ratios DPDO/CCD ≤ 1, [Eu(H2O)nL4]3+ complexes are formed in organic phases, whereas with an excess of DPDO relative to CCD, Eu(NO3)L 4 2+ complexes are formed, where L = Me-or Et-DPDO. Polyoxyethylenediphosphine dioxide forms anhydrous complexes of composition Eu:L = 1:1 and 1:2 with Eu(III) and outer-spheric complexes of composition Sr:L = 1:1 and 1:2 with Sr(II), where the organic ligand molecules envelop the hydrated Sr(H2O) n 2+ cation. The peculiarities of extraction of the complexes are explained based on data about their composition and structure. 相似文献
9.
Vladislav?Tomi?i?Email author Vjekoslav?Butorac Jadranka?Viher Vladimir?Simeon 《Journal of solution chemistry》2005,34(6):613-616
The effect of temperature on the π∗←π transition band in the UV absorption spectrum of NO3−(aq) centered at ≈200 nm was studied in the temperature range 10–70 ∘C. The observed temperature independence of this band was in contrast to the significant influence of temperature on the nitrate π∗←n transition reported recently by us. However, taking into account the electronic states involved in both the transitions, it was concluded that this finding was in accordance with our previous assumption that interconversion between spectrally distinct (with respect to π∗←n band) nitrate species included the rupture/formation of hydrogen bond(s) in the hydration shell of the nitrate ion. 相似文献
10.
By an appropriate choice of cation, three of the four possible aldols from the reactions of the chiral α-silyloxy ketone 1 with aldehydes may be obtained. The , lithium enolate provides 6, the , boron enolate gives 7, and the magnesium enolate affords 8. 相似文献