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1.
Caesium carbonate supported on hydroxyapatite‐encapsulated Ni0.5Zn0.5Fe2O4 nanocrystallites as a novel magnetically basic catalyst for the one‐pot synthesis of pyrazolo[1,2‐b]phthalazine‐5,10‐diones
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Behrooz Maleki Samaneh Barat Nam Chalaki Samaneh Sedigh Ashrafi Esmail Rezaee Seresht Farid Moeinpour Amir Khojastehnezhad Reza Tayebee 《应用有机金属化学》2015,29(5):290-295
A novel nanomagnetic basic catalyst of caesium carbonate supported on hydroxyapatite‐coated Ni0.5Zn0.5Fe2O4 magnetic nanoparticles (Ni0.5Zn0.5Fe2O4@HAP‐Cs2CO3) was prepared. This new catalyst was fully characterized using Fourier transform infrared spectroscopy, transmission and scanning electron microscopy, X‐ray diffraction and vibrating sample magnetometry techniques, and then the catalytic activity of this catalyst was investigated in the synthesis of 1H‐pyrazolo[1,2‐b]phthalazine‐5,10‐dione derivatives. Also, Ni0.5Zn0.5Fe2O4@HAP‐Cs2CO3 could be reused at least five times without significant loss of activity and could be recovered easily by applying an external magnet. Thus, the developed nanomagnetic catalyst is potentially useful for the green and economic production of organic compounds. Copyright © 2015 John Wiley & Sons, Ltd. 相似文献
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K. Dasgupta P. Barat A. Sarkar P. Mukherjee D. Sathiyamoorthy 《Applied Physics A: Materials Science & Processing》2007,87(4):721-726
The use of graphite as a moderator in a low temperature thermal nuclear reactor is restricted due to accumulation of energy
caused by displacement of atoms by neutrons and high energetic particles. Thermal transients may lead to a release of stored
energy that may raise the temperature of the fuel clad above the design limit. Disordered carbon is thought to be an alternative
choice for this purpose. Two types of disordered carbon composites, namely, CB (made up of 15 wt. % carbon black dispersed
in carbonized phenolic resin) and PAN (made up of 20 vol. % chopped polyacrylonitrile carbon fibre dispersed in carbonized
phenolic resin matrix) have been irradiated with 145 MeV Ne6+ ions at three fluence levels of 1.0×1013, 5.0×1013 and 1.5×1014 Ne6+/cm2, respectively. The XRD patterns revealed that both the samples remained disordered even after irradiation. The maximum release
of stored energy for CB was 212 J/g and that of PAN was 906 J/g. For CB, the release of stored energy was a first order reaction
with activation energy of 2.79 eV and a frequency factor of 3.72×1028 per second. 13% of the defects got annealed by heating up to 700 °C. PAN showed a third-order release rate with activation
energy of 1.69 eV and a frequency factor of 1.77×1014 per second. 56% of the total defects got annealed by heating it up to 700 °C. CB seems to be the better choice than PAN as
it showed less energy release with a slower rate.
PACS 61.80.Jh; 61.80.-x; 61.43Er; 61.43.-j; 68.43.Vx 相似文献
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M. Barat J.C. Brenot H. Dunet J.A. Fayeton 《Zeitschrift für Physik D Atoms, Molecules and Clusters》1997,40(1):323-326
The basic mechanisms of collision induced fragmentation of small sodium cluster ions (Na n + n < 9) at keV collision energy are investigated by measuring the velocity vectors of the two fragments employing a new type of coincidence experiment. The results suggest that in most of the cases the lost of one Na atom can be interpreted as relevant of an impulsive mechanism. On the other hand, the lost of one Na+ ion seems to require transition to an electronically excited state of the cluster. 相似文献
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A. Chatterjee A. Sarkar Sourav Bhattacharya P. Mukherjee N. Gayathri P. Barat 《Physics letters. A》2008,372(22):4016-4020
Tensile tests were carried out by deforming polycrystalline samples of substitutional Al–2.5%Mg alloy at room temperature for a range of strain rates. The Portevin–Le Chatelier (PLC) effect was observed throughout the strain rate regime. The deformation bands in this region are found to be of type A in nature. From the analysis of the experimental stress time series data we could infer that the dynamics of type A dislocation band propagation is a Markov process. 相似文献
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García-Acosta B Comes M Bricks JL Kudinova MA Kurdyukov VV Tolmachev AI Descalzo AB Marcos MD Martínez-Máñez R Moreno A Sancenón F Soto J Villaescusa LA Rurack K Barat JM Escriche I Amorós P 《Chemical communications (Cambridge, England)》2006,(21):2239-2241
Pyrylium-containing mesoporous materials have been used for the chromo-fluorogenic sensing of biogenic amines in an aqueous environment. 相似文献
8.
Novel Helmholtz-based photoacoustic sensor for trace gas detection at ppm level using GaInAsSb/GaAlAsSb DFB lasers 总被引:2,自引:0,他引:2
Mattiello M Niklès M Schilt S Thévenaz L Salhi A Barat D Vicet A Rouillard Y Werner R Koeth J 《Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy》2006,63(5):952-958
A new and compact photoacoustic sensor for trace gas detection in the 2-2.5 microm atmospheric window is reported. Both the development of antimonide-based DFB lasers with singlemode emission in this spectral range and a novel design of photoacoustic cell adapted to the characteristics of these lasers are discussed. The laser fabrication was made in two steps. The structure was firstly grown by molecular beam epitaxy then a metallic DFB grating was processed. The photoacoustic cell is based on a Helmholtz resonator that was designed in order to fully benefit from the highly divergent emission of the antimonide laser. An optimized modulation scheme based on wavelength modulation of the laser source combined with second harmonic detection has been implemented for efficient suppression of wall noise. Using a 2211 nm laser, sub-ppm detection limit has been demonstrated for ammonia. 相似文献
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Flow cytometry is widely used for analyzing micro-particles such as cells and bacteria. Microfabricated flow cytometers promise reduced instrument size and cost with increased robustness and have application in medicine, life sciences and environmental metrology. Further miniaturisation and robustness can be achieved if integrated optics are used instead of traditional free space optics. We present designs simulation and experimental characterisation of integrated optics for a microfabricated cytometer made from SU-8 resin on a glass substrate. The optics constructed from combinations of optical fibres (positioned with microgrooves), waveguides, and microlenses enable analysis of scattered light and fluorescence from particles positioned near the centre of a microchannel using one dimensional sheath flow. Four different methods for directing the incident light onto the particles are examined and the optimum design discussed. 相似文献
10.
Sinyukov AM Liu Z Hor YL Su K Barat RB Gary DE Michalopoulou ZH Zorych I Federici JF Zimdars D 《Optics letters》2008,33(14):1593-1595
Rapid voltage-controlled phase modulation of cw terahertz (THz) radiation is demonstrated. By transmitting an infrared beam through a lithium niobate phase modulator the phase of the THz radiation, which is generated by the photomixing of two infrared beams, can be directly modulated through a 2pi phase shift. The 100 kHz modulation rate that is demonstrated with this technique is approximately 3 orders of magnitude faster than what can be achieved by mechanical scanning. 相似文献