二维平板光子晶体直波导的制备和光传输特性的测量

利用聚焦离子束刻蚀的方法在SOI(silicon on insulator)基片上制备了W3型二维光子晶体直波导.观察并测量了近红外激光通过光子晶体波导的散射图形和透过谱.实验结果说明，激光在有引入引出脊形波导的光子晶体直波导中具有很好的传输特性. 关键词： 光子晶体波导 光子带隙 脊型波导     

Scalable total synthesis of horsfiequinone A

Starting from two commercially available substrates, methoxyhydroquinone and piperonyl alcohol, a scalable four-step total synthesis of horsfiequinone A was developed. The notable feature of the synthesis is the application of two continuous sequential transformations. Namely, the key aldehyde 9 and horsfiequinone A were prepared via scalable Wittig/hydrolysis and Wittig/catalytic hydrogenation/oxidation sequences, respectively. Importantly, the synthetic route required only three recrystallizations and one column chromatography purification step.     

Two new lignans from Horsfieldia kingii

Two new dibenzylbutyrolactol lignans and three known dibenzylbutyrolactone lignans were isolated from the twigs and leaves of Horsfieldia kingii. Their structures were elucidated by spectroscopic analysis. Cytotoxicity evaluation of these compounds against five human tumour lines showed no inhibitory effects.     

部分空气桥式硅膜二维光子晶体

描述在Si基底上制备带隙在近红外波段部分空气桥式二维光子晶体（PC）.选用HF酸溶液作为腐蚀液，利用聚焦离子束刻蚀技术直接刻蚀出具有三角形空气洞结构的二维PC，并测出了二维PC完整的第一带隙透过谱的带隙范围为123—155μm.实验测得的透过谱与理论计算的空气桥式二维PC的计算结果一致.类TM0模的存在减小了带隙的宽度.由于部分SiO2支撑桥式平板，二维PC易于按所需尺寸进行制备.同时，通过改变平板下的支撑材料，可以制出有源的PC，利用这种机理可以把光从支撑材料中引出. 关键词： 二维光子晶体 带隙 平板波导     

Increased performance of an organic light-emitting diode by employing a zinc phthalocyanine based composite hole transport layer

We demonstrate that the electroluminescent performances of organic light-emitting diodes are significantly improved by employing a zinc phthalocyanine （ZnPc）-based composite hole transport layer （c-HTL）. The optimum ris-（8-hydroxyquinoline）aluminum （Alq3）-based organic light-emitting diode with a c-HTL exhibits a lower turn-on voltage of 2.8 V, a higher maximum current efficiency of 3.40 cd/A and a higher maximum power efficiency of 1.91 lm/W, which are superior to those of the conventional device （turn-on voltage of 3.8 V, maximum current efficiency of 2.60 cd/A, and maximum power efficiency of 1.21 lm/W）. We systematically studied the effects of different kinds of N’-diphenyl-N,N’-bis（1-naphthyl）（1,1’-biphenyl）-4,4’diamine （NPB）：ZnPc c-HTL. Meanwhile, we also investigate their mechanisms different from that in the case of using ZnPc as buffer layer. The specific analysis is based on the absorption spectra of the hole transporting material and current density–voltage characteristics of the corresponding hole-only devices.     

A new dimeric diarylpropane from Horsfieldia tetratepala

Five compounds, including a new dimeric diarylpropane, were isolated from the petroleum ether extract of the twigs and leaves of Horsfieldia tetratepala. The structures of these compounds were elucidated by spectroscopic analysis. Moreover, the antiproliferative activities of these compounds were tested on cancer cell lines, but none is active.     

基于连续性掺杂的高效全荧光白色有机电致发光器件的研究

利用荧光材料PT-01, PT-86, PT-05作为黄色荧光客体, 蓝色荧光客体以及荧光母体制备了一种基于连续性掺杂结构的全荧光白光有机电致发光器件. 其发光层为主体/客体薄层/主体/客体薄层···交替蒸镀的重复单元. 通过优化发光层中主体的厚度并检测发光层中单线态激子的分布, 将黄、蓝两种客体染料生长在发光层中适当的位置, 得到了高效且光谱稳定的全荧光白光器件. 其最大电流效率为11.2 cd/A, 亮度在159–20590 cd/m²范围内色坐标仅有(±0.004,±0.005)的改变. 基于这种连续性掺杂结构制备的器件, 其性能不但可以达到传统主-客体共掺结构所制备的器件的性能,而且具有较高的可重复性, 更适合产业化大批量生产. 关键词： 白色有机电致发光器件 连续性掺杂 能量转移 可重复性     

基于多源、多时相遥感影像的黄、东海绿潮影响区检测

利用不同空间分辨率、多时相卫星遥感数据,对2007-2010年间黄海、东海发生的绿潮(大型绿藻——浒苔)进行了监测与评估.江苏北部浅滩沿岸水体浑浊,浒苔在该海域中光谱混合现象严重,高空间分辨率的遥感影像有利于其检测;在水体极浑浊的射阳河口检测到的浒苔离岸最近距离为1 km左右.反演结果表明,浒苔在5月初会沿苏北沿岸流向...     

Optical Absorption Measurements on Nitrogen-doped 6H-SiC Single Crystals

6H-SiC bulk crystals have been prepared by sublimation method in an indu-ctively heated growth reactor. The effect of nitrogen doping on absorption for 6H-SiC was investigated. The absorption measurement based on optical method is a non-destructive and non-contact method. The band-gap narrowing with higher doping concentration was observed. For n-type doping below band-gap absorption band at 623 nm for 6H-SiC was observed. The peak intensity of the absorption band increased with increasing charge carrier concentration obtained from Hall measurements. It is also found that the nitrogen doping level decreased in the radial direction and it was the highest at the beginning of growth.     

基于少数层石墨烯可饱和吸收的锁模光纤激光器

本文利用化学气相沉积法高温分解甲烷在铜箔上制得单层石墨烯薄膜, 测量了石墨烯的拉曼光谱. 将石墨烯薄膜逐层转移到光纤跳线的氧化锆插芯端面上做成可饱和吸收材料, 实验研究了环形腔掺铒光纤脉冲激光器的输出特性, 获得了峰值波长为1560.1 nm, 3 dB带宽为0.27 nm, 重复频率为7.69 MHz, 脉冲宽度为58.8 ps 的锁模脉冲序列. 时间带宽积为1.98, 表明脉冲出现了啁啾. 最后, 通过改变两个光纤活动接头之间的空气腔的长度, 激光波长实现了4 nm的调谐. 关键词： 光纤激光器 石墨烯 锁模