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Shengzong Liang Ricardo A. Angnes Chinmay S. Potnis Gerald B. Hammond 《Tetrahedron letters》2019,60(45):151230
A visible light mediated deformylative alkynylation of aldehydes is presented. Under photo irradiation, 1,4-dihydropyridine (DHP), derived from an aldehyde, generated a C(sp3)- radical which couples with an alkynylbenziodoxolone to generate an alkyl substituted alkyne coupling product. This strategy is mild and easy to operate, a wide range of functional groups were tolerated, and 16 examples of products with 35–86% yields were obtained. 相似文献
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本文介绍了新近在中国工程物理研究院建成的一台直线感应加速器。这台加速器由六个250kV的加速组元构成。其中四个用于构成电子源,另外两个用作后加速。输出电子束能量为1.5MeV,束流2—3kA,束脉冲宽度90ns,束的非归—化均方根发射度70mrad-cm。 相似文献
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