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2.
Development of Biosensor for Catechol Using Electrosynthesized Poly(3‐methylthiophene) and Incorporation of LAC Simultaneously
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Simultaneous electropolymerization of 3‐methylthiophene and incorporation of Laccase (LAC) was carried out in the presence of propylene carbonate as a medium by amperometric method. This enzyme modified electrode was used for the sensing of polyphenol. Catechol is taken as a model compound for the study. UV‐Vis spectral studies suggest no denaturation of LAC in presence of propylene carbonate. The SEM studies reveal the surface morphology and incorporation of LAC in P3MT with agglomerated flaky masses are observed in with and without enzyme micrographs. The cyclic voltammograms were recorded for 0.01 mM catechol on plain glassy carbon, polymer and enzyme incorporated electrodes at pH 6.0 and scan rate 50 mV s?1. The fabricated electrochemical biosensor was used for the determination of catechol in aqueous solution by Differential Pulse Voltammetry (DPV) technique. The concentration linear range of 8×10?8 to 1.4×10?5 M a value of Michealis? Menten constant Km=7.67 µmol dm?3 and activation energy is 32.75 kJ mol?1. It retains 83 % of the original activity after 60 days which is much higher than that of other biosensors. The developed biosensor was used to quantify catechol in the determination in real samples. 相似文献
3.
Twelve ruthenium(III) complexes bearing amine-bis(phenolate) tripodal ligands of general formula [Ru(L1–L3)(X)(EPh3)2] (where L1–L3 are dianionic tridentate chelator) have been synthesized by the reaction of ruthenium(III) precursors [RuX3(EPh3)3] (where E = P, X = Cl; E = As, X = Cl or Br) and [RuBr3(PPh3)2(CH3OH)] with the tripodal tridentate ligands H2L1, H2L2 and H2L3 in benzene in 1:1 molar ratio. The newly synthesized complexes have been characterized by analytical (elemental and magnetic susceptibility) and spectral methods. The complexes are one electron paramagnetic (low-spin, d5) in nature. The EPR spectra of the powdered samples at RT and the liquid samples at LNT shows the presence of three different ‘g’ values (gx ≠ gy ≠ gz) indicate a rhombic distortion around the ruthenium ion. The redox potentials indicate that all the complexes undergo one electron transfer process. The catalytic activity of one of the complexes [Ru(pcr-chx)Br(AsPh3)2] was examined in the transfer hydrogenation of ketones and was found to be efficient with conversion up to 99% in the presence of isopropanol/KOH. 相似文献
4.
V.A. Sethuraman M.J. Chon M. Shimshak N. Van Winkle P.R. Guduru 《Electrochemistry communications》2010,12(11):1614-1617
We report in situ measurement of biaxial moduli of a Si thin-film electrode as a function of its lithium concentration. During lithiation, biaxial compressive stress is induced in the Si film and it undergoes plastic flow. At any state-of-charge (SOC), a relatively small delithiation–relithiation sequence unloads and reloads the film elastically. From the stress and strain changes during a delithiation–relithiation cycle, the biaxial modulus of the film is calculated. Stress change is obtained by measuring the change in substrate curvature using a Multi-beam Optical Sensor; the elastic strain change is obtained from the change in SOC. By repeating these measurements at several different values of SOC, the biaxial modulus was seen to decrease from ca. 70 GPa for Li0.32Si to ca. 35 GPa for Li3.0Si. Such a significant reduction in elastic modulus has important implications for modeling stress evolution and mechanical degradation in Si-based anodes. 相似文献
5.
Chon MJ Sethuraman VA McCormick A Srinivasan V Guduru PR 《Physical review letters》2011,107(4):045503
Crystalline to amorphous phase transformation during initial lithiation in (100) Si wafers is studied in an electrochemical cell with Li metal as the counter and reference electrode. During initial lithiation, a moving phase boundary advances into the wafer starting from the surface facing the lithium electrode, transforming crystalline Si into amorphous Li(x)Si. The resulting biaxial compressive stress in the amorphous layer is measured in situ, and it was observed to be ca. 0.5 GPa. High-resolution TEM images reveal a very sharp crystalline-amorphous phase boundary, with a thickness of ~1 nm. Upon delithiation, the stress rapidly reverses and becomes tensile, and the amorphous layer begins to deform plastically at around 0.5 GPa. With continued delithiation, the yield stress increases in magnitude, culminating in a sudden fracture of the amorphous layer into microfragments, and the cracks extend into the underlying crystalline Si. 相似文献
6.
Transformation of hydrophobic surface into superhydrophobic surface by interfacial flower like silver films
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Namachivayam Karthik Mathur Gopalakrishnan Sethuraman 《Surface and interface analysis : SIA》2015,47(3):423-428
Fabrication of superhydrophobic surface was achieved by electroless deposition of silver film and subsequent immersion into a mixture of stearic acid and cysteamine. The resultant superhydrophobic surface with flower and fall‐leaves like structure showed lotus leaf effect with the water contact angle of about 154° making copper surface water repellant. Copyright © 2014 John Wiley & Sons, Ltd. 相似文献
7.
l-Proline-catalysed three-component domino reactions of ethyl 2-[(2-oxo-2-arylethyl)sulfanyl]acetate, aromatic aldehydes and ammonia provide a rapid and facile access to novel trans-6-aroyl-5-aryl-3-thiomorpholinones. This diastereoselective reaction presumably proceeds via a domino sequence comprising enamine formation, Mannich reaction and intramolecular amidation individual steps and resulting in the generation of one C-C and two C-N bonds in a one-pot operation. The reaction also creates two contiguous stereocenters with complete diastereoselectivity. 相似文献
8.
G. Aravamudan P. N. Venkatasubramanian P. R. Sethuraman N. Ramadass 《无机化学与普通化学杂志》1979,457(1):238-240
Telluride ion forms polynuclear soluble cationic complexes with excess Hg(II) in sulphuric acid media. Compounds Hg5TeCl8 and Hg4Te(SO4)3 were prepared and characterised. 相似文献
9.
The basic result of the paper states: Let F1, …, Fn, F1′,…, Fn′ have proportional hazard functions with λ1 ,…, λn , λ1′ ,…, λn′ as the constants of proportionality. Let X(1) ≤ … ≤ X(n) (X(1)′ ≤ … ≤ X(n)′) be the order statistics in a sample of size n from the heterogeneous populations {F1 ,…, Fn}({F1′ ,…, Fn′}). Then (λ1 ,…, λn) majorizes (λ1′ ,…, λn′) implies that (X(1) ,…, X(n)) is stochastically larger than (X(1)′ ,…, X(n)′). Earlier results stochastically comparing individual order statistics are shown to be special cases. Applications of the main result are made in the study of the robustness of standard estimates of the failure rate of the exponential distribution, when observations actually come from a set of heterogeneous exponential distributions. Further applications are made to the comparisons of linear combinations of Weibull random variables and of binomial random variables. 相似文献
10.