全文获取类型
收费全文 | 485篇 |
免费 | 6篇 |
国内免费 | 5篇 |
专业分类
化学 | 363篇 |
晶体学 | 4篇 |
力学 | 5篇 |
数学 | 21篇 |
物理学 | 103篇 |
出版年
2022年 | 4篇 |
2021年 | 5篇 |
2020年 | 7篇 |
2019年 | 6篇 |
2016年 | 7篇 |
2015年 | 6篇 |
2014年 | 6篇 |
2013年 | 34篇 |
2012年 | 17篇 |
2011年 | 11篇 |
2010年 | 13篇 |
2009年 | 13篇 |
2008年 | 25篇 |
2007年 | 25篇 |
2006年 | 23篇 |
2005年 | 25篇 |
2004年 | 19篇 |
2003年 | 17篇 |
2002年 | 15篇 |
2001年 | 9篇 |
2000年 | 8篇 |
1999年 | 9篇 |
1998年 | 6篇 |
1997年 | 3篇 |
1996年 | 15篇 |
1995年 | 6篇 |
1994年 | 3篇 |
1993年 | 4篇 |
1992年 | 10篇 |
1991年 | 3篇 |
1990年 | 4篇 |
1989年 | 4篇 |
1987年 | 4篇 |
1986年 | 5篇 |
1985年 | 9篇 |
1984年 | 4篇 |
1982年 | 7篇 |
1981年 | 6篇 |
1980年 | 9篇 |
1979年 | 3篇 |
1978年 | 4篇 |
1977年 | 6篇 |
1976年 | 5篇 |
1975年 | 3篇 |
1974年 | 5篇 |
1970年 | 5篇 |
1969年 | 6篇 |
1968年 | 10篇 |
1967年 | 14篇 |
1966年 | 10篇 |
排序方式: 共有496条查询结果,搜索用时 59 毫秒
1.
2.
Kentaro Suzuya Tomoaki Kamiyama Takemi Yamamura Kiyohito Okamura Kenji Suzuki 《Journal of Non》1992,150(1-3):167-171
A small-angle X-ray scattering (SAXS) study was performed to reveal the nanometer scale hybrid structure of Si---Ti---C---O fibers prepared by the pyrolysis of polytitanocarbosilane. The SAXS profile for Si---Ti---C---O fibers is attributed to two different types of scattering entities: an anisotropic contribution from long filaments with diameters hundreds to thousands of Ångströms and an isotropic contribution from β-SiC fine clusters of about a nanometer in diameter. A drastic degradation in the tensile strength of the fibers is correlated to the characteristic variations in their long-and medium-range structure. 相似文献
3.
4.
V. P. Ladygin T. Uesaka T. Saito M. Hatano A. Yu. Isupov H. Kato N. B. Ladygina Y. Maeda A. I. Malakhov J. Nishikawa T. Ohnishi H. Okamura S. G. Reznikov H. Sakai N. Sakamoto S. Sakoda Y. Satou K. Sekiguchi K. Suda A. Tamii N. Uchigashima K. Yako 《Physics of Atomic Nuclei》2006,69(8):1271-1278
RIKEN Accelerator Research Facility data on the tensor analyzing power T 20 of the dd → 3Hen and dd → 3Hp reactions at zero angle for deuteron kinetic energies of 140, 200, and 270 MeV are reported. The observed positive sign of T 20 clearly demonstrates the sensitivity to the D/S-wave ratio in the 3He and 3H wave functions in the energy range of the experiment. Data on T 20 for the 3Hen channel are in agreement with those for the 3Hp channel within the experimental errors. 相似文献
5.
6.
Y Nishioka S Kyotani M Okamura M Miyazaki Y Sakamoto M Morita K Okazaki S Ohnishi Y Yamamoto K Ito 《Chemical & pharmaceutical bulletin》1992,40(1):267-268
Hepatic artery of dogs was embolized with cisplatin (CDDP) albumin microspheres containing chitin and chitosan to investigate the in vivo CDDP release kinetics from CDDP albumin microspheres, the CDDP cumulative characteristics in the liver, and the influence of microsphere administration on hepatic tissue. Results showed that changes in blood CDDP content were dependent on CDDP albumin microsphere type and that release kinetics were better sustained when chitin was added to the microspheres or when the microspheres were treated with chitosan. In particular, the administration of CDDP in the chitin-containing CDDP chitosan albumin microspheres showed a blood CDDP content of approximately 0.26 micrograms Pt/ml 14 d after administration. The administration of chitin-containing or chitosan treated CDDP microspheres showed a CDDP content in the hepatic tissue of 0.14 to 0.23 micrograms Pt/g 28 d after administration. They also showed better control of CDDP release than those without chitin or chitosan treatment. No CDDP influence on hepatic tissue was observed. We conclude that, even in vivo, chitin and chitosan are effective embolic materials. 相似文献
7.
Y. Ohsumi T. Higashimura S. Okamura 《Journal of polymer science. Part A, Polymer chemistry》1967,5(4):849-862
Methyl vinyl ether (MVE) was polymerized under various conditions by BF3·O(C2H5)2 and SnCl4·CCl3CO2H catalysts. The effect of polymerization conditions on the steric structure of poly(methyl vinyl ether) (PMVE) was studied by NMR spectra. It was found that the triad isotacticity of PMVE decreased and the syndiotacticity and heterotacticity increased with increasing polarity of the solvent and increasing polymerization temperature. This result coincided with the qualitative conclusion estimated from softening point and infrared spectra. However, the variation of tacticity by the change of the polarity of a solvent was not so large as expected. There was no large difference between the behavior of BF3·O(C2H5)2 and SnCl4·CCl3CO2H as catalysts. From the relation between the difference of free energy of monomer addition due to the steric structure of the polymer and the polymerization temperature, it was concluded that the penultimate effect really existed and was due to only the difference in enthalpy in the MVE–BF3. O(C2H5)2 or MVE–SnCl4·CCl3CO2H systems. The penultimate effect was not greatly changed by the polymerization conditions in these systems. 相似文献
8.
Bolm C Verrucci M Simic O Cozzi PG Raabe G Okamura H 《Chemical communications (Cambridge, England)》2003,(22):2826-2827
Quinoline-based C1-symmetric sulfoximines have been used as chiral ligands in copper-catalyzed asymmetric hetero Diels-Alder reactions leading to cycloadducts with up to 96% ee. 相似文献
9.
Okamura WH Zhu GD Hill DK Thomas RJ Ringe K Borchardt DB Norman AW Mueller LJ 《The Journal of organic chemistry》2002,67(5):1637-1650
Isotope-labeled drug molecules may be useful for probing by NMR spectroscopy the conformation of ligand associated with biological hosts such as membranes and proteins. Triple-labeled [7,9,19-(13)C(3)]-vitamin D(3) (56), its 25-hydroxylated and 1 alpha,25-dihydroxylated metabolites (58 and 68, respectively), and other labeled materials have been synthesized via coupling of [9-(13)C]-Grundmann's ketone 39 or its protected 25-hydroxy derivative 43 with labeled A ring enyne fragments 25 or 26. The labeled CD-ring fragment 39 was prepared by a sequence involving Grignard addition of [(13)C]-methylmagnesium iodide to Grundmann's enone 28, oxidative cleavage, functional group modifications leading to seco-iodide 38, and finally a kinetic enolate S(N)2 cycloalkylation. The C-7,19 double labeling of the A-ring enyne was achieved by the Corey-Fuchs/Wittig processes on keto aldehyde 11. By employing these labeled fragments in the Wilson-Mazur route, the C-7,9,19 triple-(13)C-labeled metabolites 56, 58, and 68 as well as other (13)C-labeled metabolites have been prepared. In an initial NMR investigation of one of the labeled metabolites prepared in this study, namely [7,9,19-(13)C(3)]-25-hydroxyvitamin D(3) (58), the three (13)C-labeled carbons of the otherwise water insoluble steroid could be clearly detected by (13)C NMR analysis at 0.1 mM in a mixture of CD(3)OD/D(2)O (60/40) or in aqueous dimethylcyclodextrin solution and at 2 mM in 20 mM sodium dodecyl sulfate (SDS) aqueous micellar solution. In the SDS micellar solution, a double half-filter NOESY experiment revealed that the distance between the H(19Z) and H(7) protons is significantly shorter than that of the corresponding distance calculated from the solid state (X-ray) structure of the free ligand. The NMR data in micelles reveals that 58 exists essentially completely in the alpha-conformer with the 3 beta-hydroxyl equatorially oriented, just as in the solid state. The shortened distance (H(19Z))-H(7)) in micellar solutions as compared to that in the solid state is most easily rationalized on the basis that the 5(10)-torsion angle in 58 is decreased in micellar solutions as compared to that in the solid state. 相似文献
10.
The nature of the complex europium carbonate ion in concentrated carbonate solution was studied polarographically. A polarographic method for the determination of micro amounts of europium ion in the presence of diverse ions (and especially lanthanides) was developed. 相似文献