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排序方式: 共有1294条查询结果,搜索用时 15 毫秒
1.
Dr. Nozomi Mihara Dr. Yasuyuki Yamada Dr. Hikaru Takaya Prof. Yasutaka Kitagawa Dr. Kazunobu Igawa Prof. Katsuhiko Tomooka Prof. Hiroshi Fujii Prof. Kentaro Tanaka 《Chemistry (Weinheim an der Bergstrasse, Germany)》2019,25(13):3369-3375
Development of supramolecular methods to further activate a highly reactive intermediate is a fascinating strategy to create novel potent catalysts for activation of inert chemicals. Herein, a supramolecular approach to enhance the oxidizing ability of a high-valent oxo species of a nitrido-bridged iron porphyrinoid dimer that is a known potent molecular catalyst for light alkane oxidation is reported. For this purpose, a nitrido-bridged dinuclear iron complex of porphyrin-phthalocyanine heterodimer 3 5+, which is connected through a fourfold rotaxane, was prepared. Heterodimer 3 5+ catalyzed ethane oxidation in the presence of H2O2 at a relatively low temperature. The site-selective complexation of 3 5+ with an additional anionic porphyrin (TPPS4−) through π–π stacking and electrostatic interactions afforded a stable 1:1 complex. It was demonstrated that the supramolecular post-synthetic modification of 3 5+ enhances its catalytic activity efficiently. Moreover, supramolecular conjugates achieved higher catalytic ethane oxidation activity than nitrido-bridged iron phthalocyanine dimer, which is the most potent iron-oxo-based molecular catalyst for light-alkane oxidation reported so far. Electrochemical measurements proved that the electronic perturbation from TPPS4− to 3 5+ enhanced the catalytic activity. 相似文献
2.
Three new cytotoxic polyacetylenes, PQ-1 (1), PQ-2 (2) and PQ-3 (3), have been isolated from Panax quinquefolium. The structures of these acetylenes were determined by analyses of their 1H-1H and 1H-13C COSY spectra. All these compounds exhibited strong cytotoxic activities against leukemia cells (L 1210) in tissue culture. 相似文献
3.
Takayuki Yaegashi Shinya Yodoya Masahiko Nakamura Hiroki Takeshita Katsuhiko Takenaka Tomoo Shiomi 《Journal of polymer science. Part A, Polymer chemistry》2004,42(4):999-1007
Free‐radical homo‐ and copolymerization behavior of N,N‐diethyl‐2‐methylene‐3‐butenamide (DEA) was investigated. When the monomer was heated in bulk at 60 °C for 25 h without initiator, rubbery, solid gel was formed by the thermal polymerization. No such reaction was observed when the polymerization was carried out in 2 mol/L of benzene solution with with 1 mol % of azobisisobutyronitrile (AIBN) as an initiator. The polymerization rate (Rp) equation was Rp ∝ [DEA]1.1[AIBN]0.51, and the overall activation energy of polymerization was calculated 84.1 kJ/mol. The microstructure of the resulting polymer was exclusively a 1,4‐structure where both 1,4‐E and 1,4‐Z structures were included. From the product analysis of the telomerization with tert‐butylmercaptan as a telogen, the modes of monomer addition were estimated to be both 1,4‐ and 4,1‐addition. The copolymerizations of this monomer with styrene and/or chloroprene as comonomers were also carried out in benzene solution at 60 °C. In the copolymerization with styrene, the monomer reactivity ratios obtained were r1 = 5.83 and r2 = 0.05, and the Q and e values were Q = 8.4 and e = 0.33, respectively. © 2004 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 42: 999–1007, 2004 相似文献
4.
Yukio Iida Masahiro Shibutani Katsuhiko Kobayashi Kazuhiko Ohnuma Yoichi Miyake Toru Noda 《Optical Review》2006,13(2):87-92
The double-pass method is thought to obtain the point spread function (PSF) in human eyes based on two techniques: the symmetric
double-pass method using the same pupil size and the asymmetric double-pass method using a different pupil size. The symmetric
double-pass method provides autocorrelation of the retinal PSF and, thus, the modulation transfer function. The asymmetric
double-pass method provides low-frequency partial-phase information and the partial phase-retrieval algorithm is applied to
obtain the complete-phase information, and to estimate the PSF. The partial phase-retrieval algorithm is based on the iteration
method proposed by Fineup and Kowalczyk and requires a lengthy computation. In this study, we propose a new high-speed phase-retrieval
algorithm based on the property that the real and imaginary parts of optical transfer functions (OTFs) continuously change
in value. 相似文献
5.
H. Sunaoshi Y. Fukashiro M. Furukawa M. Yamauchi S. Hayashibe T. Shinozuka M. Fujioka I. Satoh M. Wada S. Matsuki 《Hyperfine Interactions》1993,78(1-4):241-245
The ground state hyperfine splitting of87Sr+ was measured with a precision of 1×10–8. The experiments were performed with an RF ion trap connected to an ISOL (isotope separator on-line), where all the possible transitions between Zeeman sublevels were observed by a laser-microwave double resonance method. The magnetic dipole hyperfine constant was determined to beA=–1 000 473.673 (11) kHz. 相似文献
6.
Teruhisa Horita Katsuhiko Yamaji Natsuko Sakai Yueping Xiong Harumi Yokokawa Tatsuya Kawada 《Ionics》2002,8(1-2):108-117
The oxygen reduction active sites were visualized around the O2/SOFC cathode/electrolyte triple phase boundaries (TPB) by the16O/18O exchange techniques and secondary ion mass spectrometry (SIMS) analysis. The higher18O concentration is observed on the cathode top surfaces (La0.9Sr0.1MnO3-mesh, Au-mesh, and Ag-porous), which suggested the promotion of oxygen adsorption and oxygen surface exchange at the cathode.
The oxygen diffusion through the bulk of cathode occurred at the La0.9Sr0.1MnO3-mesh and the Ag-porous cathodes, not at the Au-mesh cathode. On the YSZ surfaces after removing the cathode, the active sites
for oxygen incorporation were analyzed by SIMS. The active sites for oxygen incorporation were at the La0.9Sr0.1MnO3/YSZ interface as well as the TPB. On the other hand, the active sites for oxygen incorporation are limited to the TPB in
the case of the Au-mesh removed YSZ surface. From the SIMS analysis, the expansion of the active sites for oxygen incorporation
is less than a few μm from the TPB lines.
Paper presented at the 8th EuroConference on Ionics, Carvoeiro, Algarve, Portugal, Sept. 16–22, 2001. 相似文献
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9.
Tomomi Kawasaki Miyuki Nagaoka Tomoko Satoh Ayako Okamoto Rie Ukon Atsuyo Ogawa 《Tetrahedron》2004,60(15):3493-3503
Claisen rearrangement triggered by enolization of 2-allyloxyindolin-3-ones with DBU was performed in order to prepare 3-allyl-3-hydroxyindolin-2-ones. Total synthesis of 3-hydroxyindolin-2-one alkaloids, (±)-donaxaridine, as well as (±)-convolutamydines A and E, was achieved by transformation of the allyl moiety of 3-allyl-3-hydroxyindolin-2-ones. 相似文献
10.
A new hydrophilic copolymer having three kinds of hydroxyl groups, i.e. primary OH on -hydroxy allyl alcohol component, secondary OH on cyclic hemiacetal component and tertiary OH on -hydroxy acrylate component, was prepared by reducing a ‘polylactone’, poly(1-oxa-2-oxobutane-1,4:3,3-tetrayl), with NaBH4 in mixed solvents containing an alcohol. The structural analyses were performed by the solution 1H NMR and the solid state 13C NMR spectroscopies of the reduced samples. The composition of the three components turned out to be variable to the alcohol species used for the mixed solvent. 相似文献