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排序方式: 共有1875条查询结果,搜索用时 46 毫秒
1.
Svetlakova A. V. Mendez M. Sanchez Tuchin E. S. Khodan A. N. Traore M. Azouani R. Kanaev A. Tuchin V. V. 《Optics and Spectroscopy》2021,129(8):846-850
Optics and Spectroscopy - We study the photocatalytic activity of nanocomposites based on θ-phase alumina (Al2O3) with different TiO2 concentrations for heterogeneous photocatalysis and... 相似文献
2.
We investigate the dynamics of the Λ system driven by two resonant laser fields in presence of dissipation for coupling strengths where the rotating‐wave approximation starts to break down. This regime is characterised by Rabi frequencies being approximately equal or smaller than the field frequencies. A systematic procedure to obtain an expansion for the solution of the Bloch evolution equations of the system is presented. The lowest contribution results to be the well‐known rotating‐wave approximation. The method is based on a semi‐classical treatment of the problem, and its predictions are interpreted fully quantum mechanically. The theory is illustrated by a detailed study of the disappearance of coherent population trapping as the intensities of the fields increase. 相似文献
3.
Antonio Guirado Enrique LópezSánchez Raquel Andreu Andrés Zapata 《Tetrahedron letters》2004,45(10):2075-2076
The first method for the synthesis of the title compounds has been established involving a stereoselective electrochemical diacylation process. The cathodic reductions of monothiobenzils in an aprotic medium, under constant potential, in the presence of twofold molecular amounts of aroyl chlorides provide previously unknown (Z)-α-benzoyloxy-β-benzoythiostilbenes in high to quantitative yields. 相似文献
4.
J. Saunier F. Alloin J. Y. Sanchez B. Barrire 《Journal of Polymer Science.Polymer Physics》2004,42(3):544-552
Some microporous poly(vinylidene fluoride) (PVdF) separators for lithium‐ion batteries, used in liquid organic electrolytes based on a mixture of carbonate solvents and lithium salt LiPF6, were characterized by the study of the swelling phenomena on dense PVdF membranes. Various aspects of the kinetics of the carbonate solvents and the solvent mixture sorption in dense PVdF slabs were studied at different temperatures. Non‐Fickian behavior, characterized by S‐shaped sorption curves, was highlighted, and a salt effect, which resulted in two‐stage sorption, was studied. Diffusion coefficients and activation energies were calculated for the Fickian portions of the sorption curves, that is, at short times and low swelling ratios. A strong influence of the different interaction parameters was shown for the swelling kinetics. This study proved that the swelling of microporous PVdF membranes could be considered instantaneous. © 2003 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 42: 544–552, 2004 相似文献
5.
J. Saunier F. Alloin J. Y. Sanchez L. Maniguet 《Journal of Polymer Science.Polymer Physics》2004,42(12):2308-2317
Microporous poly(vinylidene fluoride) (PVdF) separators for lithium-ion batteries, used in liquid organic electrolytes, have been characterized with respect to the swelling phenomena on dense PVdF membranes (obtained through hot pressing). In the first and second parts of this study, we have described the swelling equilibria and swelling kinetics of dense PVdF. Here the thermal properties of PVdF gels and their irreversible modifications induced by swelling are characterized. Particular attention is paid to crystallinity modifications, polymer plasticization, and membrane degradation. © 2004 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 42: 2308–2317, 2004 相似文献
6.
A sequential injection methodology for the spectrophotometric determination of calcium, magnesium and alkalinity in water samples is proposed. A single manifold is used for the determination of the three analytes, and the same protocol sequence allows the sequential determination of calcium and magnesium (the sum corresponds to the water hardness). The determination of both metals is based on their reaction with cresolphtalein complexone; mutual interference is minimized by using 8-hydroxyquinoline for the determination of calcium and ethylene glycol-bis(beta-aminoethyl ether)-N,N,N',N'-tetraacetic acid (EGTA) for the determination of magnesium. Alkalinity determination is based on a reaction with acetic acid, and corresponding color change of Bromcresol Green. Working ranges of 0.5 - 5 mg dm(-3) for Ca, 0.5 - 10 mg dm(-3) for Mg, and 10 - 100 mg HCO3- dm(-3), for alkalinity have been achieved. The results for water samples were comparable to those of the reference methods and to a certified reference water sample. RSDs lower than 5% were obtained, a low reagent consumption and a reduced volume of effluent have been accomplished. The determination rate for calcium and magnesium is 80 h(-1), corresponding to 40 h(-1) per element, while 65 determinations of alkalinity per hour could be carried out. 相似文献
7.
Alejandro Balbs Raquel Balbs Silvia Mayoral 《Mathematical and Computer Modelling》2007,45(11-12):1308-1318
The first Fundamental Theorem of Asset Pricing establishes the equivalence between the absence of arbitrage in financial markets and the existence of Equivalent Martingale Measures, if appropriate conditions hold. Since the theorem may fail when dealing with infinitely many trading dates, this paper draws on the A.A. Lyapunov Theorem in order to retrieve the equivalence for complete markets such that the Sharpe Ratio is adequately bounded. 相似文献
8.
Push-pull dithiafulvenes with reduced bond length alternation (BLA) and high optical nonlinearities have been prepared. The interplay between the proaromaticity of the donor and the structural and optical properties of these merocyanines is discussed. The donor ability of dithiafulvenes can reach that of ferrocene or dialkylaminophenyl groups. 相似文献
9.
P. Bonville M. Rams K. Królas J.-P. Sanchez P. C. Canfield O. Trovarelli C. Geibel 《The European Physical Journal B - Condensed Matter and Complex Systems》2007,55(1):77-84
We have examined the magnetic properties of the heavy electron compounds
YbAgGe and YbPtIn by 170Yb M?ssbauer spectroscopy down to 0.1 K, and
the crystal field properties of YbAgGe by Perturbed Angular Correlations
(PAC) measurements up to 900 K. In YbAgGe, we show that each of the two
magnetically ordered phases below 0.8 K involves a specific incommensurate
modulation of the Yb moment. An analysis of existing low temperature specific
heat data suggests the
persistence of fluctuations of the correlated Yb spins down to 0.1 K.
The PAC data allow to discriminate among proposed Yb3+ crystal field
level schemes. In YbPtIn, we show that the low temperature magnetic order
phase has an antiferro-para structure, where zero moment Yb ions coexist with
large moment ones, and that a 90° moment reorientation occurs at
1.4 K. 相似文献
10.