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1.
CV Tomy D Pal SS Banerjee S Ramakrishnan AK Grover S Bhattacharya MJ Higgins G Balakrishnan McK Paul 《Pramana》2002,58(5-6):925-935
The weakly pinned single crystals of the hexagonal 2H-NbSe2 compound have emerged as prototypes for determining and characterizing the phase boundaries of the possible order-disorder
transformations in the vortex matter. We present here a status report based on the ac and dc magnetization measurements of
the peak effect phenomenon in three crystals of 2H-NbSe2, in which the critical current densities vary over two orders of magnitude. We sketch the generic vortex phase diagram of
a weakly pinned superconductor, which also utilizes theoretical proposals. We also establish the connection between the metastability
effects and pinning. 相似文献
2.
Optimization of synthesis procedure and structure characterization of manganese tungstate nanoplates
Mehdi Rahimi-Nasrabadi S. Mahdi Pourmortazavi Morteza Khalilian-Shalamzari S. Somayyeh Hajimirsadeghi M. Mahdi Zahedi 《Central European Journal of Chemistry》2013,11(8):1393-1401
A simple and fast chemical method was used for synthesis of manganese tungstate nanoplates in flower-like clusters; while Taguchi robust design was employed as statistical method for optimization of the experimental parameters for the procedure. Ultrafine manganese tungstate plates in flower-like clusters were synthesized via a direct precipitation method involving addition of manganese ion solution to the aqueous tungstate reagent. Effects of various reaction conditions such as manganese and tungstate concentrations, flow rate of reagent addition and reactor temperature on the thickness of the synthesized manganese tungstate plates were investigated experimentally. Analysis of variance (ANOVA) showed that manganese tungstate nanoplates could be effectively synthesized by tuning significant parameters of precipitation procedure. Meanwhile, optimum conditions for synthesis of MnWO4 nanoplates via this simple, fast, and cost effective method were proposed. The structure and composition of the prepared nanoplates under optimum conditions were characterized by EDX, X-ray diffraction (XRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM), FT-IR spectroscopy, and photoluminescence techniques. 相似文献
3.
In subnormal glow discharge under d.c. excitation at different pressure in a varying transverse magnetic field (0 to 30 G)
some measurements have been carried out for various initial average tube currents. The voltage across the discharge increases
and average tube current and residual current decreases in the magnetic field. With the help of Beckman’s expression [4] for
the axial field and the electron density distribution in a transverse magnetic field the observed variation of current and
voltage can be satisfactorily explained. The variation of axial electric field with transverse magnetic field can be represented
to a fair degree of accuracy by the derived equation. The behaviour of residual current with magnetic field has been observed
in these oscillations. 相似文献
4.
An integral equation formulation for buoyancy-driven convection problems is developed and illustrated. Buoyancy-driven convection in a bounded cylindrical geometry with a free surface is studied for a range of aspect ratios and Nusselt numbers. The critical Rayleigh number, the nature of the cellular motion, and the heat transfer enhancement are computed using linear theory. Green's functions are used to convert the linear problem into linear Fredholm integral equations. Theorems are proved which establish the properties of the eigenvalues and eigenfunctions of the linear integral operator which appears in these equations. 相似文献
5.
Seied M. Pourmortazavi Iraj Kohsari Seiedeh S. Hajimirsadeghi 《Central European Journal of Chemistry》2009,7(1):74-78
The present study concerns the electrochemical synthesis of basic copper carbonate nanoparticles by oxidation of metallic
copper on the anode in an aqueous bicarbonate solution. This simple and one-step preparation can be considered as green synthesis.
The scanning electron microscopy (SEM) analysis indicates that average particle size of the product is in the range of about
70 nm. On the other hand, basic copper carbonate micro-powder has been prepared, by mixing solutions of copper(II) sulphate
and sodiu bicarbonate. The SEM analysis showed that the size of particles prepared in the same way is in the range of about
1 μm. In another part of this study, the thermal decomposition of micro and nanoparticles of copper carbonate produced by
various methods was studied in air using TG-DTA techniques. The results of thermal study show that the decomposition of both
samples occurs in single step. Also, the TG-DTA analysis of the nanoparticles indicates that the main thermal degradation
occurs in the temperature range of 245–315°C. However, microparticles of Cu(OH)2 · CuCO3 decomposed endothermally in the temperature range of 230–330°C.
相似文献
6.
Seied Mahdi Pourmortazavi Mehdi Rahimi-Nasrabadi Iraj Kohsari Seiedeh Somayyeh Hajimirsadeghi 《Journal of Thermal Analysis and Calorimetry》2012,110(2):857-863
Thermal stability and decomposition kinetics for two energetic materials, potassium nitroform (KNF) and 5-Nitro-2,4-dihydro-3H-1,2,4-triazol-3-one (NTO), were investigated to obtain information on their safety for handling, storage, and use. Differential scanning calorimetry (DSC) and simultaneous thermogravimetry-differential thermal analysis (TG-DTA) techniques have been used to study thermal behavior of these energetic compounds. The results of TG analysis revealed that the main thermal degradation for the KNF occurs during two temperature ranges of 270?C330 and 360?C430?°C. Meanwhile, NTO decomposes completely in temperature range of 250?C300 °C. TG-DTA analysis of KNF indicates that this energetic compound dehydrated (at about 108?°C) before its decomposition. However, NTO is thermally stable until its decomposition. The decomposition kinetic of energetic materials was studied by non-isothermal DSC under various heating rates. Kinetic parameters such as activation energy and frequency factor for thermal decomposition of energetic compounds were obtained via the methods proposed by ASTM E696 and Starink. Also, thermodynamic parameters correspond to the activation of thermal decomposition and critical ignition temperatures of the compounds were obtained. 相似文献
7.
WANG Er-Kang ZHOU Wei-HongLaboratory of Electroanalytical Chemistry Changchun Institute of Applied Chemistry Chinese Academy of Sciences Changchun Jilin SS China 《中国化学》1996,14(2):131-137
Capillary electrpphoresis (CE)/electrochemical detection (EC) for the simultane-ous determination of hydrazine and isoniazid has been developed.The electrochemical method uses a novel modified electrode dispersed with ultrafine platinum particles on the surface of a 30μm carbon fiber microelectrode.The unique characteristic of the Pt-particles modified carbon fiber microelectrode is its excellent stability.The current measurement for hydrazine is more sensitive than that of isoniazid.Selective determination of trace amount of free hydrazine in isoniazid and its formulation can be achieved at applied potential of 0.5V. 相似文献
8.
A Soibel SS Banerjee Y Myasoedov ML Rapparort E Zeldov S Ooi T Tamegai 《Pramana》2002,58(5-6):893-898
Using a novel differential magneto-optical imaging technique we investigate the phenomenon of vortex lattice melting in crystals
of Bi2Sr2CaCu2O8 (BSCCO). The images of melting reveal complex patterns in the formation and evolution of the vortex solid-liquid interface
with varying field (H)/temperature (T). We believe that the complex melting patterns are due to a random distribution of material disorder/inhomogeneities across
the sample, which create fluctuations in the local melting temperature or field value. To study the fluctuations in the local
melting temperature/field, we have constructed maps of the melting landscape T
m(H, r), viz., the melting temperature (T
m) at a given location (r) in the sample at a given field (H). A study of these melting landscapes reveals an unexpected feature: the melting landscape is not fixed, but changes rather
dramatically with varying field and temperature along the melting line. It is concluded that the changes in both the scale
and shape of the landscape result from the competing contributions of different types of quenched disorder which have opposite
effects on the local melting transition. 相似文献
9.
The use of supercritical fluids, especially carbon dioxide, in the extraction of plant volatile components has increased during two last decades due to the expected advantages of the supercritical extraction process. Supercritical fluid extraction (SFE) is a rapid, selective and convenient method for sample preparation prior to the analysis of compounds in the volatile product of plant matrices. Also, SFE is a simple, inexpensive, fast, effective and virtually solvent-free sample pretreatment technique. This review provides a detailed and updated discussion of the developments, modes and applications of SFE in the isolation of essential oils from plant matrices. SFE is usually performed with pure or modified carbon dioxide, which facilitates off-line collection of extracts and on-line coupling with other analytical methods such as gas, liquid and supercritical fluid chromatography. In this review, we showed that a number of factors influence extraction yields, these being solubility of the solute in the fluid, diffusion through the matrix and collection process. Finally, SFE has been compared with conventional extraction methods in terms of selectivity, rapidity, cleanliness and possibility of manipulating the composition of the extract. 相似文献
10.
Rednikov AY; Zhao Hong; Sadhal SS; Trinh EH 《The Quarterly Journal of Mechanics and Applied Mathematics》2006,59(3):377-397
The steady (acoustic) streaming associated with a sphericaldrop displaced from the velocity antinode of a standing waveis studied. The ratio of the particle size to the acoustic wavelengthis treated as small but non-zero, and the solution is developedin the form of a two-term expansion in terms of the correspondingsmallness parameter. The drop viscosity is assumed to be muchhigher than that of the surrounding fluid, which is the casefor a drop in a gas medium. There are essentially three distinctregions where the steady streaming flow is analysed: insidethe drop (internal circulation), in the Stokes shear-wave layerat the surface on the gas side, and the gas outside the Stokeslayer (the outer streaming region). Solutions for the internalcirculation and the outer streaming are obtained in the limitof small Reynolds number. Despite the gas-to-liquid viscosity ratio being small, the outerstreaming may be dramatically affected by the fact that thesphere is liquid as opposed to solid. The parameter that measuresthe effect of liquidity is essentially the viscosity ratio dividedby the relative (to the particle size) thickness of the Stokeslayer. The case of a solid sphere is recovered by letting thisparameter go to zero. 相似文献