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JETP Letters - We have demonstrated that with increasing the exchange splitting of the conduction band of a ferromagnet and, respectively, of the degree of the spin polarization, the probability of... 相似文献
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Yu. M. Kargin E. I. Gritsenko V. V. Yanilkin V. V. Plemenkov L. K. Dubovik N. I. Maksimyuk B. M. Garifullin Sh. K. Letypov A. V. Il'yasov 《Russian Chemical Bulletin》1992,41(9):1572-1579
The electrochemical reduction of 1,1-dihalo-2-R-2-methylcyclopropanes was studied by polarography and preparative electrolysis. A mixture of stereoisomeric monoboro- and monochlorocyclopropanes was obtained with preparative yield of 60–70% in preparative electroreduction in methanol against a background of 0.1 M LiClO4. In the case of bromine derivatives of cyclopropanes (except when R = CN) an effect was found on the part of the current density on the ratio of cis and trans isomers, which was interpreted as a change, in dependence on current density, of the contributions of the reactions of reduction of the starting compounds (SN2 mechanism) and ionic pairs (SN1 mechanism). The effect of the solvent (CHCl3, DMF, DMSO, MeOH) and background salt (LiClO4, Et4NBr) on the ratio of stereoisomers is in agreement with this interpretation.A. E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Science Center, Russian Academy of Sciences, Kazan. Translated from Izvestiya Akademii Nauk, Seriya Khimicheskaya, No. 9, pp. 2023–2032, September, 1992. 相似文献
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Th. Mühge Yu. V. Goryunov K. Theis-Bröhl K. Westerholt H. Zabel I. A. Garifullin 《Applied magnetic resonance》1998,14(4):567-582
Magnetic and superconducting properties of Fe/Nb epitaxial bilayers have been studied. Single crystal Fe/Nb (110) bilayers with a Nb thicknessd Nb in the range from 250 to 650 Å and with a Fe thicknessd Fe in the range from 7 to 27 Å were prepared using molecular beam epitaxy techniques. Magnetization measurements showed the existence of a magnetically “dead” Fe-interface layer with a thicknessd NM varying strongly with minor modifications of the growth conditions. For bilayers with a small magnetic layer thicknessd M and a smalld NM the FMR measurements revealed an anomalous decrease of the effective magnetization 4πM eff of the ferromagnetic Fe layer below the superconducting transition temperatureT c. The absolute change of 4πM eff belowT c depends strongly on the actual values ofd M andd NM: upon decreasing bothd M andd NM the effect increases considerably. As a possible mechanism for the anomalous temperature dependence of 4πM eff belowT c we discuss a spatial modulation of ferromagnetic order due to a modification of the RKKY inter-action in the superconducting state. 相似文献
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V. V. Yanilkin N. I. Maksimyuk E. I. Strunskaya B. M. Garifullin Yu. M. Kargin 《Russian Chemical Bulletin》1993,42(8):1340-1343
The effect of the nature of organic electron transfer agents and of PtII, PdII, RhII, CoII, NiII, CuII, CrIII, MnII, TiIII, VIII, ZnII, and AgI metal ions on the kinetics of the homogeneous reduction ofgem-dichlorocyclopropanes has been studied. PtII, PdII, RhIII, CoII, and NiII ions accelerate this process, VIII and AgI ions exert practically no effect on the reduction rate, and the rest of the metal ions exhibit inhibitor properties.Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 8, pp. 1407–1410, August, 1993. 相似文献
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Andriy B. Zaborovskiy Ruslan E. Prystansky Vitaliy I. Timokhin 《Journal of organometallic chemistry》2004,689(18):2912-2919
The interaction of (Me3Si)3SiH with O2 is known to afford (Me3SiO)2Si(H)SiMe3 in which the two oxygen atoms arise from the same oxygen molecule. In order to investigate the mechanism of this unusual reaction, the oxidation rates were measured in the temperature range 30-70 °C by following oxygen uptake in the presence and absence of hydroquinone as inhibitor. The rate constant for the spontaneous reaction of (Me3Si)3SiH with O2 was determined at 70 °C to be ∼3.5 × 10−5 M−1 s−1. A sequence of the propagation steps is proposed by combining the previous and present experimental findings with some theoretical results obtained at the semiempirical level. These calculations showed that the silylperoxyl radical (Me3Si)3SiOO undergoes three consecutive unimolecular steps to give (Me3SiO)2Si()SiMe3. Evidence has been obtained that the rate determining step is the rearrangement of silylperoxyl radical to a dioxirand-like pentacoordinated silyl radical. Our findings are of considerable importance for the understanding of the oxidation of hydrogen-terminated silicon surfaces. 相似文献
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We review our recent work on the direct calculation of the interfacial free energy, gamma, of the crystal-melt interface via molecular dynamics computer simulation for a number of model systems. The value of gamma as a function of crystal orientation is determined using a thermodynamic integration technique employing moving cleaving walls [Phys. Rev. Lett. 2000, 85, 4751]. The calculation is sufficiently precise to resolve the small anisotropy in gamma, which is crucial in determining the kinetics and morphology of dendritic growth. We report values of gamma for the hard-sphere and Lennard-Jones systems, as well as recent results on the series of inverse-power potentials. For the inverse sixth-, seventh-, and eighth-power systems, we determine gamma for both fcc and bcc crystal structures. For these systems, the bcc-melt gamma is lower than that for fcc crystals by about 25%, consistent with recent experiments and computer simulations on fcc-forming systems that show preferential formation of bcc nuclei in the initial stages of crystallization. In addition, we show that our results give a molecular interpretation of Turnbull's rule, which is the empirical relationship between gamma and the enthalpy of fusion. 相似文献