排序方式: 共有7条查询结果,搜索用时 0 毫秒
1
1.
The kinetics of the reaction between organocobaloximes, RCo(DH)2H2O, and iodine have been investigated. They reveal the participation of an RCo(DH)2H2O · I2 intermediate which undergoes intramolecular transalkylation and acts as an electrophile towards a second organocobaloxime molecule. The trend in reactivity as the R group is varied is discussed. 相似文献
2.
Mason K Chang J Garlatti E Prescimone A Yoshii S Nojiri H Schnack J Tasker PA Carretta S Brechin EK 《Chemical communications (Cambridge, England)》2011,47(21):6018-6020
The use of "double-headed" phenolic oximes produces a trigonal antiprismatic [Fe(III)(3)](2) cluster with an "internal cavity" filled with an additional Fe(3+) ion. Magnetic measurements reveal that the competition between different exchange interactions leads to a low-spin ground multiplet weakly separated in energy from a complex pattern of low-lying excited levels. 相似文献
3.
Simone Chicco Alessandro Chiesa Giuseppe Allodi Elena Garlatti Matteo Atzori Lorenzo Sorace Roberto De Renzi Roberta Sessoli Stefano Carretta 《Chemical science》2021,12(36):12046
We show that [VO(TPP)] (vanadyl tetraphenylporphyrinate) is a promising system to implement quantum computation algorithms based on encoding information in multi-level (qudit) units. Indeed, it embeds a nuclear spin 7/2 coupled to an electronic spin 1/2 by hyperfine interaction. This qubit–qudit unit can be exploited to implement quantum error correction and quantum simulation algorithms. Through a combined theoretical and broadband nuclear magnetic resonance study, we demonstrate that the elementary operations of such algorithms can be efficiently implemented on the nuclear spin qudit. Manipulation of the nuclear qudit can be achieved by resonant radio-frequency pulses, thanks to the remarkably long coherence times and the effective quadrupolar coupling induced by the strong hyperfine interaction. This approach may open new perspectives for developing new molecular qubit–qudit systems.By a combined theoretical and broadband nuclear magnetic resonance study, we show that [VOTPP] is a coupled electronic qubit-nuclear qudit system suitable to implement qudit-based quantum error correction and quantum simulation algorithms. 相似文献
4.
CM Casadei L Bordonali Y Furukawa F Borsa E Garlatti A Lascialfari S Carretta S Sanna G Timco R Winpenny 《J Phys Condens Matter》2012,24(40):406002
We present (53)Cr-NMR spectra collected at low temperature in a single crystal of the heterometallic antiferromagnetic (AF) ring Cr(7)Ni in the S?=?1/2 ground state with the aim of establishing the distribution of the local electronic moment in the ring. Due to the poor S/N we observed only one signal which is ascribed to three almost equivalent (53)Cr nuclei in the ring. The calculated spin density in Cr(7)Ni in the ground state, with the applied magnetic field both parallel and perpendicular to the plane of the ring, turns out to be AF staggered with the greatest component of the local spin ?s? for the Cr(3+) ions next to the Ni(2+) ion. The (53)Cr-NMR frequency was found to be in good agreement with the local spin density calculated theoretically by assuming a core polarization field of H(cp)?=-?11?T/μ(B) for both orientations, close to the value found previously in Cr(7)Cd. The observed orientation dependence of the local spin moments is well reproduced by the theoretical calculation and evidences the importance of single-ion and dipolar anisotropies. 相似文献
5.
Garlatti E Carretta S Affronte M Sa?udo EC Amoretti G Santini P 《J Phys Condens Matter》2012,24(10):104006
The Ni? nanomagnet represents an ideal model system for investigating the effects of geometrical frustration in magnetic interactions. The Ni ions in the magnetic core are arranged on two corner-sharing tetrahedra and interact through antiferromagnetic exchange couplings. We show that the high degree of frustration leads to a magnetic energy spectrum with large degeneracies which result in unusual static and dynamical magnetic properties. In particular, the relaxation dynamics of the magnetization is characterized by several distinct characteristic times. We also discuss the possible interest of Ni? for magnetocaloric refrigeration. 相似文献
6.
The mechanism of the reaction between the organocobaloximes RCo(DH)2H2O (DH = dimethylglyoximate) and iodine in methanol has been studied and a comparison made with the corresponding reaction in chloroform. The effect of the solvent on the reaction mechanism and the role of nucleophilic assistance are discussed. 相似文献
7.
Mason K Chang J Prescimone A Garlatti E Carretta S Tasker PA Brechin EK 《Dalton transactions (Cambridge, England : 2003)》2012,41(29):8777-8785
Strapping two salicylaldoxime units together with aliphatic α,Ω-aminomethyl links in the 3-position gives ligands which allow the assembly of the polynuclear complexes [Fe(7)O(2)(OH)(6)(H(2)L1)(3)(py)(6)](BF(4))(5)·6H(2)O·14MeOH (1·6H(2)O·14MeOH), [Fe(6)O(OH)(7)(H(2)L2)(3)](BF(4))(3)·4H(2)O·9MeOH (2·4H(2)O·9MeOH) and [Mn(6)O(2)(OH)(2)(H(2)L1)(3)(py)(4)(MeCN)(2)](BF(4))(5)(NO(3))·3MeCN·H(2)O·5py (3·3MeCN·H(2)O·5py). In each case the metallic skeleton of the cluster is based on a trigonal prism in which two [M(III)(3)O] triangles are tethered together via three helically twisted double-headed oximes. The latter are present as H(2)L(2-) in which the oximic and phenolic O-atoms are deprotonated and the amino N-atoms protonated, with the oxime moieties bridging across the edges of the metal triangles. Both the identity of the metal ion and the length of the straps connecting the salicylaldoxime units have a major impact on the nuclearity and topology of the resultant cluster, with, perhaps counter-intuitively, the longer straps producing the "smallest" molecules. 相似文献
1