全文获取类型
收费全文 | 18734篇 |
免费 | 3539篇 |
国内免费 | 2686篇 |
专业分类
化学 | 13683篇 |
晶体学 | 236篇 |
力学 | 1203篇 |
综合类 | 178篇 |
数学 | 1835篇 |
物理学 | 7824篇 |
出版年
2024年 | 67篇 |
2023年 | 388篇 |
2022年 | 658篇 |
2021年 | 771篇 |
2020年 | 845篇 |
2019年 | 754篇 |
2018年 | 679篇 |
2017年 | 631篇 |
2016年 | 952篇 |
2015年 | 939篇 |
2014年 | 1171篇 |
2013年 | 1519篇 |
2012年 | 1682篇 |
2011年 | 1738篇 |
2010年 | 1263篇 |
2009年 | 1206篇 |
2008年 | 1366篇 |
2007年 | 1232篇 |
2006年 | 1087篇 |
2005年 | 910篇 |
2004年 | 698篇 |
2003年 | 588篇 |
2002年 | 533篇 |
2001年 | 463篇 |
2000年 | 377篇 |
1999年 | 381篇 |
1998年 | 290篇 |
1997年 | 273篇 |
1996年 | 281篇 |
1995年 | 228篇 |
1994年 | 175篇 |
1993年 | 163篇 |
1992年 | 123篇 |
1991年 | 98篇 |
1990年 | 105篇 |
1989年 | 68篇 |
1988年 | 57篇 |
1987年 | 56篇 |
1986年 | 38篇 |
1985年 | 39篇 |
1984年 | 18篇 |
1983年 | 12篇 |
1982年 | 15篇 |
1981年 | 8篇 |
1980年 | 5篇 |
1979年 | 4篇 |
1971年 | 1篇 |
1957年 | 3篇 |
1936年 | 1篇 |
排序方式: 共有10000条查询结果,搜索用时 62 毫秒
1.
Liu Wenbin Huang Yiwei Huang Guolin Fan Lijiao Xie Yuming Shi Jeffery 《Journal of Radioanalytical and Nuclear Chemistry》2022,331(5):2055-2068
Journal of Radioanalytical and Nuclear Chemistry - Eco-friendly and low-cost composite, amidoxime-functionalized microcrystalline cellulose/mesoporous silica (MCC/MS-AO), were synthesized by... 相似文献
2.
Zhang Bing Yang Jie-qin Liu Ying Hu Bin Yang Yang Zhao Li Lu Qiang 《Cellulose (London, England)》2022,29(12):6565-6578
Cellulose - Heating is essential in various biomass pre-treatments and thermal conversion processes. It is of practical significance to study the characteristics of cellulose-lignin and... 相似文献
3.
Dr. Yong-Sheng Wei Dr. Liming Sun Miao Wang Dr. Jinhua Hong Dr. Lianli Zou Hongwen Liu Dr. Yu Wang Dr. Mei Zhang Dr. Zheng Liu Prof. Yinwei Li Prof. Satoshi Horike Prof. Kazu Suenaga Prof. Qiang Xu 《Angewandte Chemie (Weinheim an der Bergstrasse, Germany)》2020,132(37):16147-16156
Understanding the thermal aggregation behavior of metal atoms is important for the synthesis of supported metal clusters. Here, derived from a metal–organic framework encapsulating a trinuclear FeIII2FeII complex (denoted as Fe3) within the channels, a well-defined nitrogen-doped carbon layer is fabricated as an ideal support for stabilizing the generated iron nanoclusters. Atomic replacement of FeII by other metal(II) ions (e.g., ZnII/CoII) via synthesizing isostructural trinuclear-complex precursors (Fe2Zn/Fe2Co), namely the “heteroatom modulator approach”, is inhibiting the aggregation of Fe atoms toward nanoclusters with formation of a stable iron dimer in an optimal metal–nitrogen moiety, clearly identified by direct transmission electron microscopy and X-ray absorption fine structure analysis. The supported iron dimer, serving as cooperative metal–metal site, acts as efficient oxygen evolution catalyst. Our findings offer an atomic insight to guide the future design of ultrasmall metal clusters bearing outstanding catalytic capabilities. 相似文献
4.
Simultaneous determination of cinnamaldehyde and its metabolite in rat tissues by gas chromatography–mass spectrometry 下载免费PDF全文
Hang Zhao Qian Yang Yanhua Xie Jiyuan Sun Honghai Tu Wei Cao Siwang Wang 《Biomedical chromatography : BMC》2015,29(2):182-187
Cinnamaldehyde (CA), an active ingredient isolated from the traditional Chinese medicine Cortex Cinnamomi, has a wide range of bioactivities. To clarify the distribution characteristics of CA, a selective and sensitive method utilizing gas chromatography–mass spetrometry was initially developed for simultaneously determining the concentration of CA and its metabolite cinnamyl alcohol in rat tissues. Selected ion masses of m/z 131, 105 and 92 were chosen, and separation of the analytes was performed on a DB‐5 ms (30 m × 0.25 mm, 0.25 µm, thickness) capillary column by gas chromatography–mass spectrometry. The calibration curves demonstrated good linearity and reproducibility over the range of 20–2000 and 20–4000 ng/mL for various tissue samples. Recoveries ranged from 86.8 to 107.5%, while intra‐ and interday relative standard deviations were all <11.3%. The analysis method was successfully applied in tissue distribution studies for CA and cinnamyl alcohol. As CA and cinnamyl alcohol may inter‐convert to one another, simultaneous determination of both analytes provides a comparative and accurate data for tissue study. The concentrations of CA and cinnamyl alcohol remaining in spleen were the highest among the main organs, including heart, liver, spleen, lung, kidney and brain. In addition, there was no long‐term accumulation of CA in rat tissues. Copyright © 2014 John Wiley & Sons, Ltd. 相似文献
5.
6.
7.
8.
9.
We propose a system of time-division multiplexing(TDM) and spatial frequency-division multiplexing(SFDM). Extrinsic Fabry–Perot interferometric sensors are applied to detect weak acoustic signals. The broadband source is employed, the light from it is modulated by a pulse signal sequence and is efficiently amplified by semiconductor optical amplifiers. Experimental results show that the equivalent noise pressure spectrum level is-97.2 d B re 1 rad/√Hz below 1250 Hz, and the cross talk between two sensors in one TDM channel is-32.7 d B with a cavity length difference of 60 μm. The number of sensors in this multiplexing system can theoretically reach 160. 相似文献
10.
Chao Liu Liying Wang Lin Yang Famei Wang Chunhong Xu Jingwei Lv Guanglai Fu Xianli Li Qiang Liu Haiwei Mu Tao Sun Paul K. Chu 《Physics letters. A》2019,383(25):3200-3206
A single-polarization filter comprising a gold-coated photonic crystal fiber based on surface plasmon resonance is designed and investigated. The pattern matching and coupled polarization characteristics analyzed by the full-vector finite element method (FEM) and losses at 1,540 nm are achieved to 1,016.01739 dB/cm (x-pol core mode) and 33.81917 dB/cm (y-pol core mode). The crosstalk (CT) value of the 1,540 nm band is ?853.12653 dB for fiber length and the bandwidth is 850 nm. The working wavelength of the filter ranges from 1,280 nm to 1,540 nm by varying the diameter of outer air holes (), the diameter of inner air holes (), the metal film thickness (t), as well as the liquid refractive index (n). 相似文献