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1.
Zusammenfassung Die dünnschichtchromatographische Trennung des Urans von Metallen der Ammoniumsulfidgruppe wurde beschrieben. Als Laufmittel dient ein Gemisch Aceton-Isobutanol-Salzsäure-Wasser. Nach Ablösung der Sorptionsschicht wird das Uran ausgewaschen und mit MDCM spektralphotometrisch bestimmt. pH- und Zeitabhängigkeit des Uran-MDCM-Komplexes werden untersucht und die Genauigkeit der Methode angegeben.
Summary The thin layer Chromatographic separation of uranium from metals of the ammonium sulfide group is described. The mobile phase is an acetoneisobutanol-hydrochloric acid-water mixture. After dissolving off the sorption layer, the uranium is washed out and determined spectrophotometrically with MDCM. The pH- and time relationship of the uranium-MDCM complex were studied and the precision of the method is given.
Résumé On décrit la séparation de l'uranium des métaux du groupe sulfure d'ammonium, par Chromatographie en couche mince. On utilise comme phase mobile un mélange acétone-isobutanol-acide chlorhydrique. Après lessivage de la couche de sorption, on élimine l'uranium par lavage et on le dose spectrophotométriquement par le MDCM. On étudie l'influence du pHet du temps sur le complexe uranium-MDCM et l'on indique la précision de la méthode.相似文献
2.
We have tested the limits of gaseous hydrogen fluoride as an agent for parallel detachment of organic molecules from the solid support. Peptides were chosen as relatively sensitive models for this reaction. Acid-catalyzed amide bond hydrolysis, side chain modification (tryptophan and other unnatural amino acids) by the protecting group residues as well as dehydration of serine and asparagine was followed. The technique of cleavage of side chain protection prior to the resin cleavage has given satisfactory results. Two-step deprotection and cleavage from benzhydrylamine resin by TFA and HF was compared to the deprotection and cleavage by TFA from Knorr resin. 相似文献
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Different approaches to transmission problems on graphs are studied on the basis of their reduction to problems for a single
equation on the graph. Methods for solving them are presented.
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Translated from Sovremennaya Matematika i Ee Prilozheniya (Contemporary Mathematics and Its Applications), Vol. 12, Partial
Differential Equations, 2004. 相似文献
6.
Flavin Adenine Dinucleotide and N5,N10‐Methenyltetrahydrofolate are the in planta Cofactors of Arabidopsis thaliana Cryptochrome 3
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Tanja Göbel Stefan Reisbacher Alfred Batschauer Richard Pokorny 《Photochemistry and photobiology》2017,93(1):355-362
Members of the cryptochrome/photolyase family (CPF) of proteins utilize noncovalently bound light‐absorbing cofactors for their biological function. Usually, the identity of these cofactors is determined after expression in heterologous systems leaving the question unanswered whether these cofactors are identical to the indigenous ones. Here, cryptochrome 3 from Arabidopsis thaliana was expressed as a fusion with the green fluorescent protein in Arabidopsis plants. Besides the confirmation of the earlier report of its localization in chloroplasts, our data indicate that fractions of the fusion protein are present in the stroma and associated with thylakoids, respectively. Furthermore, it is shown that the fusion protein expressed in planta contains the same cofactors as the His6‐tagged protein expressed in Escherichia coli, that is, flavin adenine dinucleotide and N5,N10‐methenyltetrahydrofolate. This demonstrates that the heterologously expressed cryptochrome 3, characterized in a number of previous studies, is a valid surrogate of the corresponding protein expressed in plants. To our knowledge, this is also a first conclusive analysis of cofactors bound to an Arabidopsis protein belonging to the CPF and purified from plant tissue. 相似文献
7.
Let $(L, h)\rightarrow (X, \omega )$ denote a polarized toric Kähler manifold. Fix a toric submanifold $Y$ and denote by $\hat{\rho }_{tk}:X\rightarrow \mathbb {R}$ the partial density function corresponding to the partial Bergman kernel projecting smooth sections of $L^k$ onto holomorphic sections of $L^k$ that vanish to order at least $tk$ along $Y$ , for fixed $t>0$ such that $tk\in \mathbb {N}$ . We prove the existence of a distributional expansion of $\hat{\rho }_{tk}$ as $k\rightarrow \infty $ , including the identification of the coefficient of $k^{n-1}$ as a distribution on $X$ . This expansion is used to give a direct proof that if $\omega $ has constant scalar curvature, then $(X, L)$ must be slope semi-stable with respect to $Y$ (cf. Ross and Thomas in J Differ Geom 72(3): 429–466, 2006). Similar results are also obtained for more general partial density functions. These results have analogous applications to the study of toric K-stability of toric varieties. 相似文献
8.
We consider the steady plane flow of certain classes of viscoelastic fluids in exterior domains with a non-zero velocity prescribed at infinity. We study existence as well as asymptotic behaviour of solutions near infinity and show that for sufficiently small data the solution decays near infinity as fast as the fundamental solution to the Oseen problem. 相似文献
9.
S. Pokorny 《Colloid and polymer science》1977,255(1):103
Ohne Zusammenfassung 相似文献
10.
Zusammenfassung Eine dünnschichtchromatographische Trennung der Halogenide und Pseudohalogenide wird beschrieben. Als Trägersubstanz dient Kieselgel. Systematische Untersuchungen ergaben drei Fließmittel, die für die Auftrennung gut geeignet sind. Die Identifizierung wird teils bei Tageslicht, teils im UV vorgenommen. Eine Auftrennung und Identifizierung dieser Anionen beansprucht etwa 3 bis 4 Stunden.
Summary A thin layer chromatographic separation of the halides and pseudohalides is described. Silica gel is used as carrier substance. Systematic studies revealed three liquids that are well suited for the separation. The identification was conducted partly in daylight and partly in XJV. A separation and identification of these anions requires about 3 to 4 hours.
Résumé On décrit un procédé de séparation des halogénures et des pseudohalogénures par chromatographie en couche mince. Du gel de silice sert de substance-support. Des essais systématiques montrent que trois éluants conviennent bien à la séparation. L'identification se fait soit à la lumière du jour soit dans l'UV. La séparation et l'identification de ces anions demandent environ 3 à 4 heures.相似文献