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排序方式: 共有186条查询结果,搜索用时 15 毫秒
1.
Petre Constantin 《Communications in Mathematical Physics》1986,104(2):311-326
One of the central problems in the mathematical theory of turbulence is that of breakdown of smooth (indefinitely differentiable) solutions to the equations of motion. In 1934 J. Leray advanced the idea that turbulence may be related to the spontaneous appearance of singularities in solutions of the 3—D incompressible Navier-Stokes equations. The problem is still open. We show in this report that breakdown of smooth solutions to the 3—D incompressible slightly viscous (i.e. corresponding to high Reynolds numbers, or highly turbulent) Navier-Stokes equations cannot occur without breakdown in the corresponding solution of the incompressible Euler (ideal fluid) equation. We prove then that solutions of distorted Euler equations, which are equations closely related to the Euler equations for short term intervals, do breakdown.Sponsored by the United States Army under Contract No. DAAG29-80-C-0041, and partially supported by the National Science Foundation under Grant No. MCS-82-01599 相似文献
2.
Gabriela Ionita Victor Sahini 《Journal of inclusion phenomena and macrocyclic chemistry》2004,50(3-4):183-186
The influence of certain thermal treatments on the reactivity of bovine serum albumin (denaturation followed by renaturation in three different cooling conditions) was studied monitoring the kinetics of oxidation of BSA with two water-soluble stable hydrazyl radicals. The results showed that the addition to the reaction mixture of -cyclodextrin and -cyclodextrin decreases the oxidation rate, probably due to the encapsulation of terminal amino acid rests by the cyclodextrins cavity. -Cyclodextrin protects more efficiently the albumin probes than -cyclodextrin. The denatured albumin probes are more reactive than natural albumin as a consequence of the reorienting of the hydrophobic rests of albumin molecule to their surface. 相似文献
3.
Petre BA Youhnovski N Lukkari J Weber R Przybylski M 《European journal of mass spectrometry (Chichester, England)》2005,11(5):513-518
Nitration of tyrosine residues in proteins may occur in cells upon oxidative stress and inflammation processes mediated through generation of reactive nitroxyl from peroxynitrite. Tyrosine nitration from oxidative pathways may generate cytotoxic species that cause protein dysfunction and pathogenesis. A number of protein nitrations in vivo have been reported and some specific Tyrosine nitration sites have been recently identified using mass spectrometric methods. High-resolution Fourier transform ion cyclotron resonance mass spectrometry (MALDI) FT-ICR-MS) is shown here to be a highly efficient method in the determination of protein nitrations. Following the identification of nitration of the catalytic site Tyr-430 residue of bovine prostacyclin synthase, we synthesised several model peptides containing both unmodified tyrosine and 3-nitro-tyrosine residues, using solid-phase peptide synthesis (SPPS). The structures of the nitrotyrosine peptides were characterised both by ESI- and by matrix-assisted laser desorption/ionisation (MALDI)-FT-ICR-MS, using a standard ultraviolet (UV) nitrogen nitrogen laser and a 2.97 microm Nd-YAG infrared laser. Using UV-MALDI-MS, 3-nitrotyrosyl-peptides were found to undergo extensive photochemical fragmentation at the nitrophenyl group, which may hamper or prevent the unequivocal identification of Tyr-nitrations in cellular proteins. In contrast, infrared-MALDI-FT-ICR-MS did not produce fragmentation of molecular ions of Tyr-nitrated peptides. 相似文献
4.
Harabor Novac Adrian Harabor Ana Rotaru Petre 《Plasma Chemistry and Plasma Processing》2017,37(1):305-323
Plasma Chemistry and Plasma Processing - A study is made on optical emission spectrum modification during X-ray exposure, in the case of a high-pressure mercury discharge lamp operated at several... 相似文献
5.
Anca Mazare Mirela Dilea Daniela Ionita Ioana Demetrescu 《Surface and interface analysis : SIA》2014,46(3):186-192
The present study is focused on tailoring the morphology of TiO2 nanotubes obtained on Ti6Al7Nb alloy and evaluating their electrochemical behavior in simulated body fluid. The presence of the α and β phases on the Ti6Al7Nb alloy leads to a two‐scale organization of the nanotubes on the samples – which in turn affects the electrochemical stability. Furthermore, five different types of TiO2 nanotubes were obtained in various electrolytes (e.g. Generation I, a mixture of Generation II and Generation III, Generation III). Electrochemical behavior analysis of all obtained nanotubes morphologies was composed of Tafel plots, cyclic voltammetry and electrochemical impedance spectroscopy and was correlated with morphology data obtained from SEM (nanotubes diameters from top‐view and nanotube length from cross‐section view). The electrochemical results showed that morphological modifications of the Ti6Al7Nb alloy's surface by electrochemical anodizing have induced changes to the electrochemical behavior of the material, evident in the corrosion rates. Copyright © 2014 John Wiley & Sons, Ltd. 相似文献
6.
We give sufficient conditions for the rigid body in the presence of an axisymmetric force field and a gyroscopic torque to admit a Hamilton-Poisson formulation. Even if by adding a gyroscopic torque we initially lose one of the conserved Casimirs, we recover another conservation law as a Casimir function for a modified Poisson structure. We apply this frame to several well-known results in the literature. 相似文献
7.
Fast and efficient separation of cytokinins from auxin and abscisic acid and their purification using mixed-mode solid-phase extraction 总被引:17,自引:0,他引:17
A method for separation of cytokinins from auxin and abscisic acid, which allows further separation of cytokinin ribotides from cytokinin bases, ribosides and glucosides and their purification on a single Oasis MCX column was developed. Due to the mixed reversed-phase and cation-exchange mode of the Oasis MCX sorbent the cationic cytokinin bases, ribosides and glucosides as well as the anionic auxin, abscisic acid and cytokinin ribotides are retained and can be sequentially eluted by solvents containing different concentrations of methanol and ammonium hydroxide. Characteristics of the method are high recoveries of analyzed phytohormones and their sufficient purity for quantification by HPLC–ELISA (RIA) or HPLC–MS. 相似文献
8.
Gabriela Ionita Petre Ionita Victor EM. Sahini Constantin Luca 《Journal of inclusion phenomena and macrocyclic chemistry》2001,39(3-4):269-271
The kinetics of oxidation of amino acids (Arg, His, Lys, Phe, Thr and Tyr), a dipeptide (Gly-His), and BSA (bovine serum albumin) by two persistent water soluble free radicals of the hydrazyl type has been studied.The rate decreases in the order Arg>Lys>Tyr>Thr>HisBSAPheGly-His with bothfree radicals. Addition to the reaction mixture of - and -cyclodextrin decreases the oxidation rate, probably due to amino acidencapsulation in the cyclodextrin cavity. -Cyclodextrin protects more efficiently against oxidation than -cyclodextrin. 相似文献
9.
10.
Mariana Cristea Daniela Gheorghiu Ionita Maria Bruma B. C. Simionescu 《Journal of Thermal Analysis and Calorimetry》2008,93(1):63-68
Two aromatic polyimides and the corresponding poly(amic acid)s, with oxadiazole and para/meta phenoxyphenylene rings in the backbone, were synthesized and the structure — thermal properties correlation was followed
by dynamic mechanical analysis. Concerning the poly(amic acid)s, the glass transition domain was emphasized only for the compound
with meta-oriented rings because the process of imidization takes place with increasing temperature. A multiplex experiment was performed
to calculate the activation energy of the transition localized under 200°C. Consecutive heating-cooling-heating cycles were
accomplished. All phenomena are discussed by cross-examination of the storage modulus (E′), loss modulus (E″) and loss factor tanδ variation with temperature. 相似文献