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1.
Peralta Cecilia Mariana Acosta Gimena Henestrosa Cecilia Gil Raúl Andrés Fernández Liliana Patricia 《Journal of Analytical Chemistry》2022,77(3):308-317
Journal of Analytical Chemistry - The present development involved a flow injection strategy using a mini-column of multiwalled carbon nanotubes and fluorescent detection (λex of 283 nm,... 相似文献
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3.
Georges Alexits 《Commentarii Mathematici Helvetici》1940,13(1):1-5
Sans résumé 相似文献
4.
A new asymmetric synthesis of 2-substituted chiral chromanes has been achieved. The key step is the intramolecular conjugate addition of a phenolic nucleophile on a α,β-unsaturated ester catalyzed by Cinchona alkaloids. The high ee’s obtained with cinchonine and its derivatives have been rationalized by ab initio quantum chemistry calculations of transition state structures. 相似文献
5.
Jonathan L. Sessler Patricia J. Melfi Anne E.V. Gorden Doris K. Ford C. Drew Tait 《Tetrahedron》2004,60(49):11089-11097
Hexaphyrin(1.0.1.0.0.0) (isoamethyrin) undergoes a significant color change in the presence of UO22+, PuO22+, and NpO22+. The complexation of the first of these dioxo actinide cations was studied in semi-quantitative fashion in 1:1 MeOH-CH2Cl2. Under these conditions, the detection limit for UO22+ was found to be ca. 5.8 ppm by naked eye monitoring and <28 ppb by UV-vis spectroscopy. Isoamethyrin does not undergo a color change in the presence of most transition metals or when exposed to Gd(III). Isoamethyrin thus constitutes an attractive alternative to 2,2′(1,8-dihydroxy-3,6-disulfonaphthylene-2,7-bisazo)-bisbenzenarsonic acid (AzIII) and 2-(5-bromo-2-pyridylazo)-5-(diethylamino)phenol (BrPADAP), systems currently used as actinide cation sensors. 相似文献
6.
Patricia D. Morrell Camille Wainwright Lawrence Flick 《School science and mathematics》2004,104(5):199-213
The purposes of this study were to observe the teaching practices occurring in student teachers' science and mathematics K‐12 classrooms, compare the student teachers' perceptions of their teaching with what was actually occurring in their classrooms, and determine which college faculty members and courses these student teachers felt contributed to the teaching methods they used. Data on each student teacher were gathered via field notes of three classes, an observation protocol completed after each lesson, and an interview. Composites were written for each of the students. The total data set of all composites was examined to see if any patterns generalizable to the whole were evident. Differences between and among grade levels and content areas surfaced and are discussed. 相似文献
7.
We consider the divergence form elliptic operator A=??x,z·(c2(x,z) ?x,z) in the strip Ω=?× [0,H]. The velocity c(x,z) describes the multistratification of Ω: a horizontal stratification with a compact perturbation K, the velocity in K is a L∞(K) function. We suppose that the position of the perturbation is known and we prove uniqueness for identification of the perturbation from one generalized eigenfunction pattern in the neighbourhood of K. Copyright © 2004 John Wiley & Sons, Ltd. 相似文献
8.
Alain Estve Adeline Bail Georges Landa Ahmed Dkhissi Marie Brut Mehdi Djafari Rouhani Jan Sudor Anne-Marie Gu 《Chemical physics》2007,340(1-3):12-16
Possible collapsed forms of poly(N-isopropylacrylamide) molecules are reviewed on the basis of first principle calculations. Various configurations and associated conformations are detailed. The calculated optimized structures exhibit different possibilities of creating networks of intra-molecular bonds of the hydrogen type. We show that the most remarkable one is able to form a local, self-saturated and well ordered helix. We also indicate in which direction the synthesis of the molecule should be oriented to improve its global behavior in term of hydrophobic/hydrophilic behavior. 相似文献
9.
In this Note we propose a rigorous justification of the limit constitutive law of a periodic bi-anisotropic electromagnetic structure with memory. This study is based on the periodic unfolding method, introduced by D. Cioranescu, A. Damlamian and G. Griso, and is applied on the time domain and on the frequency domain. To cite this article: A. Bossavit et al., C. R. Acad. Sci. Paris, Ser. I 338 (2004). 相似文献
10.
Belting, a vocal technique typically cultivated in musical theatre singing, differs timbrally from operatic singing in many interesting respects. The underlying phonatory differences have not been previously investigated in detail. Yet, belting is frequently associated with disturbances of voice function. Articulatory and phonatory characteristics are investigated in a female subject who is a professional singer (co-author JL) trained in both the operatic and belting styles and in an intermediate vocal technique (“mixed”). This article presents data obtained from this subject by video-fiberoptic observation of the pharynx, inverse filtering of airflow, and measurement of subglottal pressure. The results reveal that belting was characterized by very high subglottal pressures and sound levels, and apparently also by a comparatively high degree of glottal adduction. Comparisons with other investigations of related aspects of belting and operatic singing support the assumption that the data obtained from our subject are representative for these vocal techniques. 相似文献