全文获取类型
收费全文 | 385篇 |
免费 | 19篇 |
专业分类
化学 | 311篇 |
晶体学 | 1篇 |
力学 | 8篇 |
数学 | 9篇 |
物理学 | 75篇 |
出版年
2024年 | 4篇 |
2023年 | 4篇 |
2022年 | 8篇 |
2021年 | 9篇 |
2020年 | 8篇 |
2019年 | 8篇 |
2018年 | 12篇 |
2017年 | 10篇 |
2016年 | 10篇 |
2015年 | 15篇 |
2014年 | 13篇 |
2013年 | 46篇 |
2012年 | 26篇 |
2011年 | 24篇 |
2010年 | 15篇 |
2009年 | 13篇 |
2008年 | 15篇 |
2007年 | 13篇 |
2006年 | 9篇 |
2005年 | 10篇 |
2004年 | 9篇 |
2003年 | 7篇 |
2002年 | 3篇 |
2000年 | 6篇 |
1999年 | 6篇 |
1998年 | 8篇 |
1997年 | 8篇 |
1996年 | 7篇 |
1995年 | 5篇 |
1994年 | 3篇 |
1993年 | 2篇 |
1992年 | 3篇 |
1988年 | 2篇 |
1987年 | 2篇 |
1986年 | 1篇 |
1985年 | 5篇 |
1984年 | 1篇 |
1983年 | 2篇 |
1982年 | 6篇 |
1981年 | 5篇 |
1980年 | 9篇 |
1979年 | 5篇 |
1978年 | 14篇 |
1977年 | 2篇 |
1976年 | 1篇 |
1975年 | 2篇 |
1974年 | 2篇 |
1973年 | 1篇 |
1970年 | 1篇 |
1936年 | 2篇 |
排序方式: 共有404条查询结果,搜索用时 46 毫秒
1.
2.
Krishna Raman Surendra S. Parmar Shiva P. Singh 《Journal of heterocyclic chemistry》1980,17(5):1137-1139
A series of 1-(5-phenyl-2H-tetrazol-2-ylacetyl)-4-substituted thiosemicarbazids were prepared as possible antiinflammatory agents. Their antiproteolytic activity was reported. 相似文献
3.
S. P. Singh S. S. Parmar V. I. Stenberg S. A. Farnum 《Journal of heterocyclic chemistry》1978,15(1):13-16
The 13C nmr chemical shifts of phenylbutazone, oxyphenbutazone, indomethacin and indole-3-acetic acid are reported. The assignments of various carbon resonances are made on the basis of the substitution effects on benzene shifts, multiplicities generated in SFORD spectra, nuclear overhauser enhancement for protonated carbons, and the comparison with analogous compounds. 相似文献
4.
5.
Sarjit S. Sandhu Miss Sukhvinder Baweja Swarn S. Parmar 《Transition Metal Chemistry》1980,5(1):299-302
Summary Ten complexes of nickel(II) and cobalt(II) witho-phenylenebis(diphenylarsine), (pdpa) ando-phenylenebis(di-p-tolylarsine), (pdta) have been synthesised. The stoichiometry of complexes is markedly dependent upon the reaction temperature, thus reaction atca. 0° gives the M(A-A)2X2 chelates, [M = Ni, X = Br, (A-A) = pdpa; M = Ni, X = I, (A-A) = pdpa, pdta; M = Co, X = CNS, (A-A) = pdpa] whereas at higher temperatures the M(A-A)X2 chelates [M = Ni, X = Br, I, (A-A) = pdpa, pdta; M = Co, X = CNS, (A-A) = pdpa or pdta] are obtained. The Ni(A-A)2I2 compounds can be converted into Ni(A-A)I2 by boiling under reflux in n-BuOH; the conversion can be reversed by cooling a CH2Cl2 solution of the latter at or below 0°. Stereochemical assignments of all the new complexes have been made on the basis of room temperature eff values, molar conductance, i.r. and u.v. data. 相似文献
6.
Bhagwan R. Pandey Sushil Kumar Shiva P. Singh Surendra S. Parmar 《Journal of heterocyclic chemistry》1980,17(5):1119-1120
Several 4-(arylaminothiocarbonyl)-1-(1-o-methoxyphenylcarbamido)-ethylpiperazines were synthesized and evaluated for their anticonvulsant activity against pentylenetetrazol-induced seizures in mice. The ability of substituted piperazines to inhibit in vitro respiratory activity of rat brain homogenates was also determined to study their structure-activity relationship. 相似文献
7.
Paresh J. Kothari Shiva P. Singh Surendra S. Parmar Virgil I. Stenberg 《Journal of heterocyclic chemistry》1980,17(7):1393-1398
Several 1-(5-aryl-2H-tetrazol-2-ylacetyl)-4-substituted thiosemicarbazides and 5-(5-aryl-2H-tetrazol-2-yl-methyl)-4-substituted-s-triazole-3-thiols were synthesized as possible antiinflammatory agents. These compounds were characterized by their elemental, infrared and nuclear magnetic resonance analysis. 相似文献
8.
9.
Anil M. Shelke Varun Rawat Gurunath Suryavanshi Arumugam Sudalai 《Tetrahedron: Asymmetry》2012,23(22-23):1534-1541
A new enantioselective synthesis of two important fungal metabolites, (+)-stagonolide C and (?)-aspinolide A, has been described from readily available raw materials. Proline catalyzed asymmetric α-aminooxylation and Jorgensen’s epoxidation of aldehydes are the key reactions employed in the introduction of chirality. The formation of the 10-membered lactone core structure was finally accomplished via Steglich esterification and ring closing metathesis reactions. 相似文献
10.
Polymeric UV absorbers have been prepared by free-radical solution copolymerization at 75°C of methyl methacrylate and 2-hydroxy-4-methacryloyloxybenzophenone monomers at low conversion (around 10%). The composition of the copolymers was determined by UV, IR, and NMR studies. The molecular weight was estimated by GPC. The reactivity ratios were determined by several methods. Viscosity was used to study the effect of copolymer composition and solvents. The copolymers were also analyzed by TGA and DSC, and DSC was used to study the effect of copolymer composition on Tg. 相似文献