全文获取类型
收费全文 | 492篇 |
免费 | 7篇 |
专业分类
化学 | 291篇 |
晶体学 | 5篇 |
力学 | 9篇 |
数学 | 49篇 |
物理学 | 145篇 |
出版年
2023年 | 4篇 |
2020年 | 7篇 |
2019年 | 3篇 |
2018年 | 4篇 |
2017年 | 5篇 |
2016年 | 4篇 |
2014年 | 10篇 |
2013年 | 11篇 |
2012年 | 4篇 |
2011年 | 13篇 |
2010年 | 9篇 |
2009年 | 12篇 |
2008年 | 13篇 |
2007年 | 13篇 |
2006年 | 18篇 |
2005年 | 22篇 |
2004年 | 21篇 |
2003年 | 23篇 |
2002年 | 18篇 |
2001年 | 17篇 |
2000年 | 16篇 |
1999年 | 11篇 |
1998年 | 11篇 |
1997年 | 12篇 |
1996年 | 7篇 |
1995年 | 11篇 |
1994年 | 14篇 |
1993年 | 16篇 |
1992年 | 22篇 |
1991年 | 14篇 |
1990年 | 8篇 |
1989年 | 9篇 |
1988年 | 13篇 |
1987年 | 8篇 |
1986年 | 9篇 |
1985年 | 7篇 |
1983年 | 2篇 |
1982年 | 3篇 |
1981年 | 6篇 |
1980年 | 9篇 |
1979年 | 10篇 |
1978年 | 4篇 |
1977年 | 7篇 |
1976年 | 5篇 |
1975年 | 6篇 |
1973年 | 6篇 |
1970年 | 5篇 |
1967年 | 2篇 |
1965年 | 3篇 |
1931年 | 2篇 |
排序方式: 共有499条查询结果,搜索用时 265 毫秒
1.
We obtain a solution of the DGLAP equation for the gluon at low x first by expanding the gluon in a Taylor series and then using the method of characteristics. We test its validity by comparing
it with that of Glück, Reya and Vogt. The convergence criteria of the approximation used are also discussed. We also calculate
εF
2(x,Q)2/ε In Q
2 using its approximate relations with the gluon distribution at low x. The predictions are then compared with the HERA data. 相似文献
2.
Suppose there exists a global solution u to the incompressible Navier–Stokes equations, such that . We prove that its norm goes to 0 at infinity. We next use this fact to control the norm of u, and finally we prove that such a solution is stable. To cite this article: I. Gallagher et al., C. R. Acad. Sci. Paris, Ser. I 334 (2002) 289–292. 相似文献
3.
4.
5.
6.
7.
Macrolide antibiotics such as erythromycin, oleandomycin, spiromycin, and tylosin are found to react with Fe(3+) in the presence of an acetic acid-sulfuric acid mixture to form a colored product having a useful absorption band at 592 nm. Troleandomycin forms only a weakly colored product upon reaction. The molar absorptivity is about 2900 1 mol(-1) cm(-1) for erythromycin and the detection limit is 5 mug ml(-1). This colorimetric method permits the analysis of fermentation broths containing either erythromycin or tylosin without a separation step. 相似文献
8.
9.
Gallagher LA Serron SA Wen X Hornstein BJ Dattelbaum DM Schoonover JR Meyer TJ 《Inorganic chemistry》2005,44(6):2089-2097
Photocurrent measurements have been made on nanocrystalline TiO2 surfaces derivatized by adsorption of a catalyst precursor, [Ru(tpy)(bpy(PO3H2)2)(OH2)]2+, or chromophore, [Ru(bpy)2 (bpy(PO3H2)2)]2+ (tpy is 2,2':6',2' '-terpyridine, bpy is 2,2'-bipyridine, and bpy(PO3H2)2 is 2,2'-bipyridyl-4,4'-diphosphonic acid), and on surfaces containing both complexes. This is an extension of earlier work on an adsorbed assembly containing both catalyst and chromophore. The experiments were carried out with the I3-/I- or quinone/hydroquinone (Q/H2Q) relays in propylene carbonate, propylene carbonate-water mixtures, and acetonitrile-water mixtures. Electrochemical measurements show that oxidation of surface-bound Ru(III)-OH2(3+) to Ru(IV)=O(2+) is catalyzed by the bpy complex. Addition of aqueous 0.1 M HClO4 greatly decreases photocurrent efficiencies for adsorbed [Ru(tpy)(bpy(PO3H2)2)(OH2)]2+ with the I3-/I- relay, but efficiencies are enhanced for the Q/H2Q relay in both propylene carbonate-HClO4 and acetonitrile-HClO4 mixtures. The dependence of the incident photon-to-current efficiency (IPCE) on added H2Q in 95% propylene carbonate and 5% 0.1 M HClO4 is complex and can be interpreted as changing from rate-limiting diffusion to the film at low H2Q to rate-limiting diffusion within the film at high H2Q. There is no evidence for photoelectrochemical cooperativity on mixed surfaces containing both complexes with the IPCE response reflecting the relative surface compositions of the two complexes. These results provide insight into the possible design of photoelectrochemical synthesis cells for the oxidation of organic substrates. 相似文献
10.
Thermomagnetic experiments are shown to be a useful and rapid technique for studying phase changes involving magnetic materials. Particular examples are chosen from Chromindur II (Fe28Cr10.5Co) alloys having different thermal histories. The Curie temperature of the single phase alloy is found to be ~650°C and the metastable spinodal decomposition boundary is at essentially the same temperature. The Cr-rich near equilibrium decomposition product is less magnetic and has a lower Tc, while the Cr-deficient product is more magnetic, with a Tc ? 720°C.Comparisons are made at different heating and cooling rates between temperatures measured using magnetic standards and those measured by a thermocouple in close proximity to the sample. 相似文献