排序方式: 共有167条查询结果,搜索用时 375 毫秒
1.
The centrosymmetric title compound, [Cd2{CH3OC6H4P(OC5H9)S2}4], features an eight‐membered [? Cd? S? P? S? ]2 ring owing to the presence of bridging dithiolate ligands. Tetrahedral coordination geometries for cadmium are completed by chelating ligands. Copyright © 2004 John Wiley & Sons, Ltd. 相似文献
2.
In this study, a syringe was filled with silica gel loaded with 3-aminopropyltriethoxysilane, for the separation and preconcentration of copper, cadmium and chromium prior to their determination by graphite furnace atomic absorption spectrometry (GFAAS) in seawater. For this purpose, a syringe was filled with 0.5 g of modified silica gel and the sample solution was drawn into the syringe and ejected back again. The analyte elements were quantitatively retained at pH 5. Then, the elements sorbed by the silica gel were eluted with 2.0 M of HCl and determined by GFAAS. At optimum conditions, the recovery of Cu, Cd and Cr were 96-98%. Detection limits (3delta) were 6.6, 7.5 and 6.0 micro g L(-1) for Cu, Cd and Cr, respectively. The elements could be concentrated by drawing and discharging several portions of sample successively but eluting only once. Cu, Cd and Cr added to a seawater sample were quantitatively recovered (>95%) in the range of the 95% confidence level. The method proposed in this paper was compared with a column technique. Optimum experimental conditions, reproducibility, precision and recoveries of both techniques are the same, but the syringe technique is much faster, easier and more practical than the column technique. It is a portable system and allows one to make the sorption process in the source of sample. In addition, the risk of contamination is less than in the column technique. 相似文献
3.
Irem Dashan Melisa Elverici Demet Karaca Balta Binnur Aydogan Temel Gokhan Temel 《Journal of polymer science. Part A, Polymer chemistry》2019,57(12):1275-1282
Light‐responsive crosslinked structures were prepared by a straightforward quaternization strategy using chloride functional polystyrene copolymers and commercially available Michler's ketone with varying feed ratios. Resulting organogels demonstrated excellent solvent absorption and their swelling characteristics were altered by UV‐light irradiation. According to scanning electron microscope images, UV‐illuminated samples showed an obvious photodecomposition, which enhanced their solvent uptake capacity with increase of UV exposure. Additionally, release behavior of eosin Y as a model compound was determined by UV–vis and fluorescence spectrometers. Achieved photoactive gels were also employed as the reusable heterogeneous initiators for photoinduced free‐radical polymerization of methyl methacrylate. © 2019 Wiley Periodicals, Inc. J. Polym. Sci., Part A: Polym. Chem. 2019, 57, 1275–1282 相似文献
4.
The adsorption of two dyes, namely, Acid Red 57 (AR57) and Acid Blue 294 (AB294), onto acid-activated bentonite in aqueous solution was studied in a batch system with respect to contact time, pH, and temperature. Acidic pH was favorable for the adsorption of these dyes. The surface characterization of acid-activated bentonite was performed using the FTIR technique. The pseudo-first-order and pseudo-second-order kinetic models and the intraparticle diffusion model were used to describe the kinetic data and the rate constants were evaluated. The dynamic data fitted the pseudo-second-order kinetic model well and also followed the intraparticle diffusion model up to 90 min, but diffusion is not the only rate controlling step. The Langmuir and Freundlich adsorption models were applied to describe the equilibrium isotherms and the isotherm constants were determined. The Freundlich model agrees very well with experimental data. The activation energies of adsorption were also evaluated for the adsorption of AR57 and AB294 onto activated bentonite. 相似文献
5.
Binnur Aydogan Temel Julia Amici Marco Sangermano Yusuf Yagci 《Journal of polymer science. Part A, Polymer chemistry》2013,51(21):4601-4607
Three controlled/living polymerization processes, namely atom transfer radical polymerization (ATRP), ring‐opening polymerization (ROP) and iniferter polymerization, and photoinduced radical coupling reaction were combined for the preparation of ABCBD‐type H‐shaped complex copolymer. First, α‐benzophenone functional polystyrene (BP‐PS) and poly(methyl methacrylate) (BP‐PMMA) were prepared independently by ATRP. The resulting polymers were irradiated to form ketyl radicals by hydrogen abstraction of the excited benzophenone moieties present at each chain end. Coupling of these radicals resulted in the formation of polystyrene‐b‐poly(methyl methacrylate) (PS‐b‐PMMA) with benzpinacole structure at the junction point possessing both hydroxyl and iniferter functionalities. ROP of ε‐caprolactone (CL) by using PS‐b‐PMMA as bifunctional initiator, in the presence of stannous octoate yielded the corresponding tetrablock copolymer, PCL‐PS‐PMMA‐PCL. Finally, the polymerization of tert‐butyl acrylate (tBA) via iniferter process gave the targeted H‐shaped block copolymer. © 2013 Wiley Periodicals, Inc. J. Polym. Sci., Part A: Polym. Chem. 2013 , 51, 4601–4607 相似文献
6.
In situ PM‐IRRAS studies of organothiols and organosilane monolayers–ZnO interfaces at high water activities
下载免费PDF全文
![点击此处可从《Surface and interface analysis : SIA》网站下载免费的PDF全文](/ch/ext_images/free.gif)
Boray Torun Ignacio Giner Guido Grundmeier Ozlem Ozcan 《Surface and interface analysis : SIA》2017,49(1):71-74
In situ photoelastic‐modulated Fourier transform infrared reflection absorption spectroscopy has been applied for the investigation of interfacial stability of organothiol and organosilane monolayer films on nanocrystalline zinc oxide thin films. It has been shown that for octadecyltriethoxysilane films, exposure to high water activities results in physisorption of water in the cross‐linked film. This high water activity at the interface leads to a reversible wet de‐adhesion of the interfacial silanol groups from the ZnO surface. However, the organothiol seems to form a denser monolayer and a stable by S–Zn bond that is resistant to the competition with adsorbed water. The reversible attachment for cross‐linked organosilanol films has been demonstrated for the first time by means of an in situ spectroscopic method on model ZnO surfaces. Copyright © 2016 John Wiley & Sons, Ltd. 相似文献
7.
Ozcan Kocyigit Ersin Guler 《Journal of inclusion phenomena and macrocyclic chemistry》2010,67(1-2):29-37
This article describes synthesis of novel Schiff base and its complexation properties with Fe(III) and Cr(III). Firstly 1,3,5-tris (formylphenoxymethyl)benzene (1, TRIPOD) with tris aldehyde groups were synthesized using the 1,3,5-trisbromomethylbenzene and 4-hydroxybezaldehyde. The compound 1 was converted to the Schiff base derivative (2, TCPIM-TRIPOD) with p-aminobenzoic acid. The prepared TCPIM-TRIPOD were reacted with four new trinuclear Fe(III) and Cr(III) complexes involving tetradenta Schiff bases N,N-bis(salicylidene)ethylenediamine-(salenH2) or bis(salicylidene)-o-phenylenediamine-(salophenH2) and characterized by means of elemental analysis carrying out infrared spectroscopy (IR), thermogravimetric analysis (TG), nuclear magnetic resonance (1H-NMR), elemental analysis and magnetic susceptibility measurement. The complexes can also be characterized as low-spin distorted octahedral Fe(III) and Cr(III) bridged by carboxylic acids. The tricarboxylic acids play a role as bridges for weak antiferromagnetic intramolecular exchange. 相似文献
8.
Erhan Temur İsmail Hakkı Boyacı Uğur Tamer Hande Unsal Nihal Aydogan 《Analytical and bioanalytical chemistry》2010,397(4):1595-1604
A very sensitive and highly specific heterogeneous immunoassay system, based on surface-enhanced Raman scattering (SERS) and
gold nanoparticles, was developed for the detection of bacteria and other pathogens. Two different types of gold nanoparticles
(citrate-stabilized gold nanosphere and hexadecyltrimethylammonium bromide (CTAB)-stabilized gold nanorod particles) were
examined and this immunoassay was applied for the detection of Escherichia coli. Raman labels were constructed by using these spherical and rod-shaped gold nanoparticles which were first coated with 5,5′-dithiobis(2-nitrobenzoic
acid) (DTNB) and subsequently with a molecular recognizer. The working curve was obtained by plotting the intensity of the
SERS signal of the symmetric NO2 stretching of DTNB at 1,333 cm−1 versus the concentration of the E. coli. The analytical performance of gold particles was evaluated via a sandwich immunoassay, and linear calibration graphs were
obtained in the E. coli concentration range of 101–105 cfu/mL with a 60-s accumulation time. The sensitivity of the Raman label fabricated with gold nanorods was more than three
times higher than spherical gold nanoparticles. The selectivity of the developed sensor was examined with Enterobacter aerogenes and Enterobacter dissolvens, which did not produce any significant response. The usefulness of the developed immunoassay to detect E. coli in real water samples was also demonstrated. 相似文献
9.
Yalcin S Gurler O Akar UT Incirci F Kaynak G Gundogdu O 《Isotopes in environmental and health studies》2011,47(4):438-445
Concentration of (222)Rn was determined in selected natural spring and tap water samples collected during spring and summer seasons from Kastamonu, Turkey. The aim of this work was to produce a map of the radon concentrations in water sources of the province and to determine any potential radiological risk for the local population. Radon measurements were performed by an AlphaGUARD radon gas analyser. The average radon concentrations were found to vary from 0.39±0.02 to 12.73±0.39?Bq?l(-1) for natural springs and from 0.36±0.04 to 9.29±0.45?Bq?l(-1) for tap water in spring, from 0.50±0.09 to 19.21±1.00?Bq?l(-1) for natural springs and from 0.31±0.03 to 13.14±0.38?Bq?l(-1) for tap water in summer. Furthermore, the results are compared with international recommendations and concentrations reported for other countries. Doses resulting from the consumption of these waters were calculated. The effective dose equivalents due to the intake of the (222)Rn present in these waters are expected to range from 0.93 to 32.54?μSv?y(-1) in summer and from 0.80 to 49.09?μSv?y(-1) in spring. 相似文献
10.
Hasan H. Ince F. Aylin Sungur Konuklar Ilke Ugur Ö. Alaz Ozcan Maryam Sayadi Michael Feig 《Molecular physics》2013,111(23):3839-3848
Deamidation plays an important role in biochemical phenomena such as aging. The role of the n + 1 residue on the deamidation of asparagine (asparagine being the nth residue) in three pentapeptide chains (GGNGG, GGNMG and GGNIG) has been analysed with hybrid computational tools. Potentials of mean force at 300 K were calculated from the MD/replica exchange simulations using weighted histogram analysis (WHAM) in explicit water. The snapshots were clustered taking into account the requirements of the plausible deamidation mechanisms, as such the tautomerisation of the asparagine side chain as initial step has been confirmed, based on the proximity of water to the deamidation site. The ultimate goal being to gain an insight on the peptide backbone N-H acidity, quantum mechanical calculations have been carried out. For this purpose, the distribution of Φ/Ψ, Φ2/Ψ and end-to-end distances deduced from the WHAM diagrams have been considered and a total of 110 structures have been sampled. These neutral pentapeptides as well as their corresponding anions have been optimised (B3LYP/6-31++G(d,p)) in implicit water in order to gain an insight on the peptide backbone N-H acidity. In this study, we have shown that the open conformations of the neutrals and the anions, which display a β sheet like structure are well populated and their pKas rank in the same order as the deamidating half-lives, that is the peptides that deaminate fastest can more readily access conformations that are more acidic. 相似文献