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排序方式: 共有122条查询结果,搜索用时 15 毫秒
1.
Novel synthesis of heterocyclic spirans by tandem cycloaddition to sulfur-containing heterocumulenes
Yoshiki Ohshiro Hitoshi Nanimoto Hiroyuki Tanaka Mitsuo Komatsu Toshio Agawa Noritake Yasuoka Yasushi Kai Nobutami Kasai 《Tetrahedron letters》1985,26(25):3015-3018
Novel Ni(C0)4-promoted tandem cycloadditions of diphenylcyclo- propenone to isothiocyanates and to CS2 were found to provide new heterocyclic spirans, pyrroline-2-one-5-spiro-5′-thiolene-4′-ones and a thiolene-2-one-5-spiro-5′-thiolene-4′-one, respectively, in moderate yields. 相似文献
2.
Ogata H Mizoguchi Y Mizuno N Miki K Adachi S Yasuoka N Yagi T Yamauchi O Hirota S Higuchi Y 《Journal of the American Chemical Society》2002,124(39):11628-11635
The carbon monoxide complex of [NiFe]hydrogenase from Desulfovibrio vulgaris Miyazaki F has been characterized by X-ray crystallography and absorption and resonance Raman spectroscopy. Nine crystal structures of the [NiFe]hydrogenase in the CO-bound and CO-liberated forms were determined at 1.2-1.4 A resolution. The exogenously added CO was assigned to be bound to the Ni atom at the Ni-Fe active site. The CO was not replaced with H(2) in the dark at 100 K, but was liberated by illumination with a strong white light. The Ni-C distances and Ni-C-O angles were about 1.77 A and 160 degrees, respectively, except for one case (1.72 A and 135 degrees ), in which an additional electron density peak between the CO and Sgamma(Cys546) was recognized. Distinct changes were observed in the electron density distribution of the Ni and Sgamma(Cys546) atoms between the CO-bound and CO-liberated structures for all the crystals tested. The novel structural features found near the Ni and Sgamma(Cys546) atoms suggest that these two atoms at the Ni-Fe active site play a role during the initial H(2)-binding process. Anaerobic addition of CO to dithionite-reduced [NiFe]hydrogenase led to a new absorption band at about 470 nm ( approximately 3000 M(-1)cm(-1)). Resonance Raman spectra (excitation at 476.5 nm) of the CO complex revealed CO-isotope-sensitive bands at 375/393 and 430 cm(-1) (368 and 413 cm(-1) for (13)C(18)O). The frequencies and relative intensities of the CO-related Raman bands indicated that the exogenous CO is bound to the Ni atom with a bent Ni-C-O structure in solution, in agreement with the refined structure determined by X-ray crystallography. 相似文献
3.
Kunio Miki Yasushi Kai Noritake Yasuoka Nobutami Kasai 《Journal of organometallic chemistry》1979,165(1):79-91
The precise molecular structure of [PdCl(CH2SCH3)(PPh3)2] has been determined from three-dimensional X-ray diffraction data collected at ?160°C. The CH2Cl2 solvated crystal ([PdCl(CH2SCH3)(PPh3)2 · CH2Cl2]) belongs to the monoclinic system, space group P21/n, with four formula units in a cell of dimensions: a 14.973(3), b 15.333(3), c 17.377(3) Å and β 115.77(1)° at ?160°C. The structure was solved by the conventional heavy atom method and refined by the least-squares procedure to R = 0.035 for observed reflections. The geometry around the palladium atom is square-planar. The phosphorus atoms of the two triphenylphosphine ligands are mutually trans. The CH2SCH3 group is bonded to the palladium atom only through the PdC σ-bond and the sulfur atom is not bonded to the metal atom (PdC(1) 2.061(3), SC(1) 1.796(3), SC(2) 1.817(5), Pd?S 2.973(1) Å, PdC(1)S 100.64(14)° and C(1)SC(2) 101.28(18)°). The structure is in contrast to that of [PdCl(CH2SCH3)(PPh3)], in which both the carbon and sulfur atoms of the CH2SCH3 group are bonded to the palladium atom. 相似文献
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More than 100 micros dissipative particle dynamics simulations were carried out to investigate the spontaneous formation process of threadlike micelles from the random configuration for surfactant molecules. Stable spherical micelles were formed during the earlier stage. These spherical micelles fused to each other and grew into rodlike and threadlike micelles during the later stage. The length and radius of a micelle were estimated by tracing the backbone positions and the distance between the head group particles and the backbone of the micelles, respectively. The ratio of the largest to the smallest principal moments of inertia for each micelle was calculated as the micelle shape. 相似文献
6.
Yukiko Yasuoka Yuichiro Izumi Takashi Fukuyama Haruki Omiya Truyen D. Pham Hideki Inoue Tomomi Oshima Taiga Yamazaki Takayuki Uematsu Noritada Kobayashi Yoshitaka Shimada Yasushi Nagaba Tetsuro Yamashita Masashi Mukoyama Yuichi Sato Susan M. Wall Jeff M. Sands Noriko Takahashi Katsumasa Kawahara Hiroshi Nonoguchi 《Molecules (Basel, Switzerland)》2022,27(3)
Anemia is a major complication of chronic renal failure. To treat this anemia, prolylhydroxylase domain enzyme (PHD) inhibitors as well as erythropoiesis-stimulating agents (ESAs) have been used. Although PHD inhibitors rapidly stimulate erythropoietin (Epo) production, the precise sites of Epo production following the administration of these drugs have not been identified. We developed a novel method for the detection of the Epo protein that employs deglycosylation-coupled Western blotting. With protein deglycosylation, tissue Epo contents can be quantified over an extremely wide range. Using this method, we examined the effects of the PHD inhibitor, Roxadustat (ROX), and severe hypoxia on Epo production in various tissues in rats. We observed that ROX increased Epo mRNA expression in both the kidneys and liver. However, Epo protein was detected in the kidneys but not in the liver. Epo protein was also detected in the salivary glands, spleen, epididymis and ovaries. However, both PHD inhibitors (ROX) and severe hypoxia increased the Epo protein abundance only in the kidneys. These data show that, while Epo is produced in many tissues, PHD inhibitors as well as severe hypoxia regulate Epo production only in the kidneys. 相似文献
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9.
S. Nasu T. Takano F. E. Fujita K. Takanashi H. Yasuoka H. Adachi 《Hyperfine Interactions》1986,28(1-4):1071-1074
The atomic arrangements in Fe-C martensite, especially the interstitial carbon positions have been discussed utilizing57Fe Mössbauer spectroscopy and13C and57Fe spin-echo NMR measurements. The experimental result is well explained by the model of two interstices occupancy of carbon in the bct martensite. Especially, the spin-echo spectra by13C nuclei showed that two main lines first appear and clear satellite lines gradually rise during the aging at 323K, suggesting the carbon jumps from the tetrahedral to the octahedral interstices and further movements to form a local ordered arrangement. 相似文献
10.
K. Yoshimura M. Takigawa Y. Takahashi H. Yasuoka M. Mekata Y. Nakamura 《Journal of magnetism and magnetic materials》1987,70(1-3):11-13
The nuclear spin-lattice relaxation rate, 1/T1, has been measured in weak itinerant ferromagnets Y(Co1−xAlx)2. The temperature and magnetic field dependence of 1/T1T has been found to be well described by the self-consistent renormalization (SCR) theory of spin fluctuations. The parameters characterizing spin fluctuations in this system were estimated from NMR and magnetic measurements. The temperature dependence of susceptibility calculated from these parameters well reproduces the experimental results. 相似文献