The Resonance Phenomena Associated with the Time Asymmetry in Non-Hermitian Quantum Mechanics

Resonances are defined as the poles of the scattering matrix. The poles are associated with the complex eigenvalues of the Hamiltonian which are embedded in the lower half of the complex plane. The asymptotes of the corresponding eigenfunctions are exponentially diverged. Therefore, the resonance eigenfunctions are not embedded in the Hermitian domain of the Hamiltonian. The time asymmetric problem is discussed for these types of non-Hermitian Hamiltonians and several solutions of this problem are proposed.     

Fermi and Coulomb correlations in the 21 S state of the helium isoelectronic sequence

The Fermi and Coulomb holes of the 2¹ S state of the helium isoelectronic sequence are investigated. Several interesting differences between the results obtained and those which might be expected on the basis of the corresponding 2³ S state are pointed out and discussed.     

Improved asymptotic analysis of the average number of steps performed by the self-dual simplex algorithm

In this paper we analyze the average number of steps performed by the self-dual simplex algorithm for linear programming, under the probabilistic model of spherical symmetry. The model was proposed by Smale. Consider a problem ofn variables withm constraints. Smale established that for every number of constraintsm, there is a constantc(m) such that the number of pivot steps of the self-dual algorithm,(m, n), is less thanc(m)(lnn) ^m(m+1) . We improve upon this estimate by showing that(m, n) is bounded by a function ofm only. The symmetry of the function inm andn implies that(m, n) is in fact bounded by a function of the smaller ofm andn. Parts of this research were done while the author was visiting Stanford University, XEROX- PARC, Carnegie-Mellon University and Northwestern University and was supported in part by the National Science Foundation under Grants MCS-8300984, ECS-8218181 and ECS-8121741.     

Dynamical tunneling through a chaotic region

It is shown that a non-vibrating diatomic molecule (i.e. a rigid rotor) in the presence of a strong laser field changes its hindered rotational motion (which on the average is in resonance with the oscillating time dependent field) from anti-clockwise to clockwise (hindered) rotational motion. This transition is classically forbidden and is another example of a quantum mechanical tunneling phenomenon occurring due to the time-reversal symmetry of the Hamiltonian. Classically, the two stable rotational modes are separated by an extended chaotic region in phase space. The Husimi representation of the quasienergy states of the time-periodic quantum system enables us to localize wave packets inside the classical stability islands. The effect of the field and the molecular parameters on the perioid of this oscillation is obtained from the quasienergy splittings without the need to carry out long time dependent computations. An analytical analysis of the dynamical tunneling using an extended version of the (t,t) formalism recently developed (J. Chem. Phys.99, 4590 (1993)) is in remarkable agreement with the numerical results.Member of the Minerva center of non-linear physics of complex systems at the Technion     

Fused Fluorinated Bis-β-diketones and Luminescent-Spectral Properties of Their Complexes with Europium

Russian Journal of General Chemistry - Claisen condensation of diacetylated fused aromatic and heteroaromatic compounds (fluorene, dibenzofuran, dibenzothiophene, or carbazole) with...     

Perturbation approach to the complex-rotation method

Non-degenerate and almost degenerate perturbation theory is applied to the problem of calculating autoionizing resonances of the helium atom using the complex-rotation method. The radii of convergence of the series are often found to be too small to allow the perturbation method to have general utility.     

Electromagnetic realization of orders-of-magnitude tunneling enhancement in a double well system

We report on tunneling enhancement in a periodically perturbed double well system. The double well system was realized by a structure of two optical waveguides. The transfer of light power from one waveguide to the another as induced by the periodic variations of the waveguide geometry was investigated. Our experimental measurements show that, in the presence of periodic perturbation, this transfer of light power can be enhanced by more than 500 times. We use an analogy between electromagnetic wave optics and the quantum wave phenomena to provide an experimental support to the theoretical model of tunneling enhancement of a quantum particle, facilitated by its interaction with auxiliary quantum states.     

Interatomic coulombic decay in van der waals clusters and impact of nuclear motion

It is demonstrated that excited van der Waals systems can relax by electron emission via a novel interatomic mechanism. The process is analyzed by means of extensive ab initio calculations of potential energy surfaces and electronic decay rates. The electronic emission, taking place on the same time scale as the motion of the atomic nuclei, is accompanied by interesting dynamical effects amenable to experimental observations. These effects arise as a consequence of the weak chemical bond in van der Waals clusters and the Coulomb repulsion pattern originating from electron emission.     

Amplified analysis of DNA by the autonomous assembly of polymers consisting of DNAzyme wires

A systematic study of the amplified optical detection of DNA by Mg(2+)-dependent DNAzyme subunits is described. The use of two DNAzyme subunits and the respective fluorophore/quencher-modified substrate allows the detection of the target DNA with a sensitivity corresponding to 1 × 10(-9) M. The use of two functional hairpin structures that include the DNAzyme subunits in a caged, inactive configuration leads, in the presence of the target DNA, to the opening of one of the hairpins and to the activation of an autonomous cross-opening process of the two hairpins, which affords polymer DNA wires consisting of the Mg(2+)-dependent DNAzyme subunits. This amplification paradigm leads to the analysis of the target DNA with a sensitivity corresponding to 1 × 10(-14) M. The amplification mixture composed of the two hairpins can be implemented as a versatile sensing platform for analyzing any gene in the presence of the appropriate hairpin probe. This is exemplified with the detection of the BRCA1 oncogene.     

Tight bounds and 2-approximation algorithms for integer programs with two variables per inequality

The problem of integer programming in bounded variables, over constraints with no more than two variables in each constraint is NP-complete, even when all variables are binary. This paper deals with integer linear minimization problems inn variables subject tom linear constraints with at most two variables per inequality, and with all variables bounded between 0 andU. For such systems, a 2-approximation algorithm is presented that runs in time O(mnU ² log(Un ² m)), so it is polynomial in the input size if the upper boundU is polynomially bounded. The algorithm works by finding first a super-optimal feasible solution that consists of integer multiples of 1/2. That solution gives a tight bound on the value of the minimum. It furthermore has an identifiable subset of integer components that retain their value in an integer optimal solution of the problem. These properties are a generalization of the properties of the vertex cover problem. The algorithm described is, in particular, a 2-approximation algorithm for the problem of minimizing the total weight of true variables, among all truth assignments to the 2-satisfiability problem.This paper is dedicated to Phil Wolfe on the occasion of his 65th birthday.Research supported in part by ONR contracts N00014-88-K-0377 and N00014-91-J-1241.Research supported in part by ONR contract N00014-91-C-0026.Part of this work was done while the author was visiting the International Computer Science Institute in Berkeley, CA and DIMACS, Rutgers University, New Brunswick, NJ.